Achieve High Dielectric and Energy-Storage Density Properties by Employing Cyanoethyl Cellulose as Fillers in PVDF-Based Polymer Composites

Fluoropolymer/inorganic nanofiller composites are considered to be ideal polymer dielectrics for energy storage applications because of their high dielectric constant and high breakdown strength. However, these advantages are a trade-off with the unavoidable aggregation of the inorganic nanofillers,...

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Bibliographic Details
Main Authors: Deqi Wu, Mingxuan Luo, Rui Yang, Xin Hu, Chunhua Lu
Format: Article
Language:English
Published: MDPI AG 2023-06-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/16/12/4201
Description
Summary:Fluoropolymer/inorganic nanofiller composites are considered to be ideal polymer dielectrics for energy storage applications because of their high dielectric constant and high breakdown strength. However, these advantages are a trade-off with the unavoidable aggregation of the inorganic nanofillers, which result in a reduced discharge of the energy storage density. To address this problem, we developed polyvinylidene fluoride (PVDF) graft copolymer/cellulose-derivative composites to achieve high-dielectric and energy-storage density properties. An enhanced dielectric constant and improved energy density were achieved with this structure. The optimal composites exhibited a high discharge energy density of 8.40 J/cm<sup>3</sup> at 300 MV/m. This work provides new insight into the development of all-organic composites with bio-based nanofillers.
ISSN:1996-1944