Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(acetato-κ2O,O′)lead(II)]
Both independent PbII atoms in the title compound, [Pb2(C10H8NO)2(C2H3O2)2], are chelated by acetate and substituted quinolin-8-olate anions; the O atoms of the quinolin-8-olates also bridge to confer a five-coordinate status to each metal center. The geometry approximates a distorted Ψ...
| Format: | Article |
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| Language: | English |
| Published: |
International Union of Crystallography
2009-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809003560 |
| _version_ | 1818282858429546496 |
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| collection | DOAJ |
| description | Both independent PbII atoms in the title compound, [Pb2(C10H8NO)2(C2H3O2)2], are chelated by acetate and substituted quinolin-8-olate anions; the O atoms of the quinolin-8-olates also bridge to confer a five-coordinate status to each metal center. The geometry approximates a distorted Ψ-fac octahedron in which one of the sites is occupied by a stereochemically active lone pair. |
| first_indexed | 2024-12-13T00:27:42Z |
| format | Article |
| id | doaj.art-f8847e493f0f42d68ff4b87951ec6bc2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T00:27:42Z |
| publishDate | 2009-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f8847e493f0f42d68ff4b87951ec6bc22022-12-22T00:05:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653m260m26010.1107/S1600536809003560Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(acetato-κ2O,O′)lead(II)]Both independent PbII atoms in the title compound, [Pb2(C10H8NO)2(C2H3O2)2], are chelated by acetate and substituted quinolin-8-olate anions; the O atoms of the quinolin-8-olates also bridge to confer a five-coordinate status to each metal center. The geometry approximates a distorted Ψ-fac octahedron in which one of the sites is occupied by a stereochemically active lone pair.http://scripts.iucr.org/cgi-bin/paper?S1600536809003560 |
| spellingShingle | Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(acetato-κ2O,O′)lead(II)] Acta Crystallographica Section E |
| title | Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(acetato-κ2O,O′)lead(II)] |
| title_full | Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(acetato-κ2O,O′)lead(II)] |
| title_fullStr | Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(acetato-κ2O,O′)lead(II)] |
| title_full_unstemmed | Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(acetato-κ2O,O′)lead(II)] |
| title_short | Bis(μ-2-methylquinolin-8-olato)-κ3N,O:O;κ3O:N,O-bis[(acetato-κ2O,O′)lead(II)] |
| title_sort | bis amp 956 2 methylquinolin 8 olato amp 954 3n o o amp 954 3o n o bis acetato amp 954 2o o amp 8242 lead ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809003560 |