Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究)
稳杀得(吡氟禾草灵)除草剂具有旋光性,其中S异构体没有除草活性.利用Pirkle型(S,S)-Whelk-O1手性固定相,在高效液相色谱上首次对稳杀得及其中间体进行了对映体分离,由相应的R-异构体标样确定R型先洗脱出;同时对流动相条件进行优化实验,考察了醇类添加剂体积分数和种类、酸性添加剂体积分数对其对映体分离的影响....
| Main Authors: | , , , |
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| Format: | Article |
| Language: | zho |
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Zhejiang University Press
2004-01-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/zjup/1008-9497.2004.31.1.70-73 |
| _version_ | 1797236428727386112 |
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| author | CAIXiao-jun(蔡小军) XUXiu-zhu(徐秀珠) PANChun-xiu(潘春秀) HEHong-mei(何红梅) |
| author_facet | CAIXiao-jun(蔡小军) XUXiu-zhu(徐秀珠) PANChun-xiu(潘春秀) HEHong-mei(何红梅) |
| author_sort | CAIXiao-jun(蔡小军) |
| collection | DOAJ |
| description | 稳杀得(吡氟禾草灵)除草剂具有旋光性,其中S异构体没有除草活性.利用Pirkle型(S,S)-Whelk-O1手性固定相,在高效液相色谱上首次对稳杀得及其中间体进行了对映体分离,由相应的R-异构体标样确定R型先洗脱出;同时对流动相条件进行优化实验,考察了醇类添加剂体积分数和种类、酸性添加剂体积分数对其对映体分离的影响. |
| first_indexed | 2024-04-24T17:03:42Z |
| format | Article |
| id | doaj.art-f893ef8967f441748f97aad03e2b3af9 |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T17:03:42Z |
| publishDate | 2004-01-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-f893ef8967f441748f97aad03e2b3af92024-03-29T01:58:21ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94972004-01-013117073zjup/1008-9497.2004.31.1.70-73Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究)CAIXiao-jun(蔡小军)0XUXiu-zhu(徐秀珠)1PANChun-xiu(潘春秀)2HEHong-mei(何红梅)3Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系, 浙江 杭州 310027)Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系, 浙江 杭州 310027)Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系, 浙江 杭州 310027)Department of Chemistry, Zhejiang University, Hangzhou 310027, China(浙江大学化学系, 浙江 杭州 310027)稳杀得(吡氟禾草灵)除草剂具有旋光性,其中S异构体没有除草活性.利用Pirkle型(S,S)-Whelk-O1手性固定相,在高效液相色谱上首次对稳杀得及其中间体进行了对映体分离,由相应的R-异构体标样确定R型先洗脱出;同时对流动相条件进行优化实验,考察了醇类添加剂体积分数和种类、酸性添加剂体积分数对其对映体分离的影响.https://doi.org/zjup/1008-9497.2004.31.1.70-73稳杀得对映体分离高效液相色谱(s,s)-whelk-o1 |
| spellingShingle | CAIXiao-jun(蔡小军) XUXiu-zhu(徐秀珠) PANChun-xiu(潘春秀) HEHong-mei(何红梅) Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究) Zhejiang Daxue xuebao. Lixue ban 稳杀得 对映体分离 高效液相色谱 (s,s)-whelk-o1 |
| title | Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究) |
| title_full | Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究) |
| title_fullStr | Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究) |
| title_full_unstemmed | Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究) |
| title_short | Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究) |
| title_sort | study of enantioseparation of the herbicide fluazifop p butyl and its intermediate 稳杀得除草剂及其中间体的对映体分离研究 |
| topic | 稳杀得 对映体分离 高效液相色谱 (s,s)-whelk-o1 |
| url | https://doi.org/zjup/1008-9497.2004.31.1.70-73 |
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