Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究)

Study of enantioseparation of the herbicide fluazifop-P-butyl and its intermediate(稳杀得除草剂及其中间体的对映体分离研究)

稳杀得(吡氟禾草灵)除草剂具有旋光性,其中S异构体没有除草活性.利用Pirkle型(S,S)-Whelk-O1手性固定相,在高效液相色谱上首次对稳杀得及其中间体进行了对映体分离,由相应的R-异构体标样确定R型先洗脱出;同时对流动相条件进行优化实验,考察了醇类添加剂体积分数和种类、酸性添加剂体积分数对其对映体分离的影响....

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Bibliographic Details
Main Authors: CAIXiao-jun(蔡小军), XUXiu-zhu(徐秀珠), PANChun-xiu(潘春秀), HEHong-mei(何红梅)
Format: Article
Language:zho
Published: Zhejiang University Press 2004-01-01
Series:Zhejiang Daxue xuebao. Lixue ban
Subjects:
稳杀得
对映体分离
高效液相色谱
(s,s)-whelk-o1
Online Access:https://doi.org/zjup/1008-9497.2004.31.1.70-73

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