Catalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theory
Tailored reaction of Schiff base ligands with palladium(II) chloride and imidazole afford three complexes of formula [Pd(II)(L)(imdz)2]Cl, which are L = 2-((E)-(p-lylimino)methyl)-6-methoxyphenol (complex 1), 2-methoxy- -6-((E)-(phenylimine)methyl)phenol (complex 2) and 2-((E)-(4-chlorophenylimino)...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2021-01-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2021/0352-51392000075S.pdf |
| _version_ | 1818889485900840960 |
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| author | Shukla Satyendra N. Gaur Pratiksha Bagri Sanjay S. Mehrotra Ripul Chaurasia Bhaskar |
| author_facet | Shukla Satyendra N. Gaur Pratiksha Bagri Sanjay S. Mehrotra Ripul Chaurasia Bhaskar |
| author_sort | Shukla Satyendra N. |
| collection | DOAJ |
| description | Tailored reaction of Schiff base ligands with palladium(II) chloride and imidazole afford three complexes of formula [Pd(II)(L)(imdz)2]Cl, which are L = 2-((E)-(p-lylimino)methyl)-6-methoxyphenol (complex 1), 2-methoxy- -6-((E)-(phenylimine)methyl)phenol (complex 2) and 2-((E)-(4-chlorophenylimino) methyl)-6-methoxyphenol (complex 3). Compounds were characterized with elemental analysis, molar conductance, electronic spectroscopy, ESI-MS, FT-IR, TGA, 1H-NMR and 13C-NMR. Molecular structure and different quantum chemical parameters were calculated using the B3LYP basis set of density functional theory with the standard 6-311+G (d, 2p) level. The catalytic potential of 1-3 was examined over Heck-Mizoroki reaction and found in order of 1 > 2 > 3. |
| first_indexed | 2024-12-19T17:09:47Z |
| format | Article |
| id | doaj.art-f8cad86f2a1c4b9ea51c32b209d74ce5 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 1820-7421 |
| language | English |
| last_indexed | 2024-12-19T17:09:47Z |
| publishDate | 2021-01-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-f8cad86f2a1c4b9ea51c32b209d74ce52022-12-21T20:13:04ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212021-01-0186326928210.2298/JSC200902075S0352-51392000075SCatalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theoryShukla Satyendra N.0Gaur Pratiksha1Bagri Sanjay S.2Mehrotra Ripul3Chaurasia Bhaskar4Coordination Chemistry Research Lab, Department of Chemistry, Government Science College, Jabalpur (M.P.), IndiaCoordination Chemistry Research Lab, Department of Chemistry, Government Science College, Jabalpur (M.P.), IndiaCoordination Chemistry Research Lab, Department of Chemistry, Government Science College, Jabalpur (M.P.), IndiaInstituto de Quimica Rosario Area Inorganica Facultad de Cs. Bioquimicas y Farmaceuticas Universidad Nacional de Rosario Suipacha SLRK Rosario, ArgentinaCoordination Chemistry Research Lab, Department of Chemistry, Government Science College, Jabalpur (M.P.), IndiaTailored reaction of Schiff base ligands with palladium(II) chloride and imidazole afford three complexes of formula [Pd(II)(L)(imdz)2]Cl, which are L = 2-((E)-(p-lylimino)methyl)-6-methoxyphenol (complex 1), 2-methoxy- -6-((E)-(phenylimine)methyl)phenol (complex 2) and 2-((E)-(4-chlorophenylimino) methyl)-6-methoxyphenol (complex 3). Compounds were characterized with elemental analysis, molar conductance, electronic spectroscopy, ESI-MS, FT-IR, TGA, 1H-NMR and 13C-NMR. Molecular structure and different quantum chemical parameters were calculated using the B3LYP basis set of density functional theory with the standard 6-311+G (d, 2p) level. The catalytic potential of 1-3 was examined over Heck-Mizoroki reaction and found in order of 1 > 2 > 3.http://www.doiserbia.nb.rs/img/doi/0352-5139/2021/0352-51392000075S.pdfschiff base pd(ii) derivativespectroscopic characterizationmolecular modelingthermogravimetric analysiscross-coupling reaction |
| spellingShingle | Shukla Satyendra N. Gaur Pratiksha Bagri Sanjay S. Mehrotra Ripul Chaurasia Bhaskar Catalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theory Journal of the Serbian Chemical Society schiff base pd(ii) derivative spectroscopic characterization molecular modeling thermogravimetric analysis cross-coupling reaction |
| title | Catalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theory |
| title_full | Catalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theory |
| title_fullStr | Catalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theory |
| title_full_unstemmed | Catalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theory |
| title_short | Catalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theory |
| title_sort | catalytic investigation of pd ii complexes over heck mizoroki reaction tailored synthesis characterization and density functional theory |
| topic | schiff base pd(ii) derivative spectroscopic characterization molecular modeling thermogravimetric analysis cross-coupling reaction |
| url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2021/0352-51392000075S.pdf |
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