2-{(E)-[(4-Anilinophenyl)imino]methyl}-4-[(E)-(4-methoxyphenyl)diazenyl]phenol
In the title Schiff base compound, C26H22N4O2, the hydroxy group forms a intramolecular hydrogen bond to the imine N atom and generates an S(6) ring motif. The conformation about the C=N and N=N bonds is E. The 4-methoxybenzene ring and the p-phenylenediamine ring are inclined to the phenol ring by...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2017-04-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461700548X |
| _version_ | 1818990023843774464 |
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| author | Md. Serajul Haque Faizi Necmi Dege Kateryna Goleva |
| author_facet | Md. Serajul Haque Faizi Necmi Dege Kateryna Goleva |
| author_sort | Md. Serajul Haque Faizi |
| collection | DOAJ |
| description | In the title Schiff base compound, C26H22N4O2, the hydroxy group forms a intramolecular hydrogen bond to the imine N atom and generates an S(6) ring motif. The conformation about the C=N and N=N bonds is E. The 4-methoxybenzene ring and the p-phenylenediamine ring are inclined to the phenol ring by 11.61 (17) and 46.04 (17)°, respectively. The terminal N-phenyl ring is inclined to the p-phenylenediamine ring by 50.72 (17)°. In the crystal, adjacent molecules are linked by C—H...O hydrogen bonds, involving the p-phenylenediamine ring and the phenol ring, forming chains along [001]. The chains are linked by a number of C—H...π interactions, forming slabs propagating parallel to (100). |
| first_indexed | 2024-12-20T19:47:47Z |
| format | Article |
| id | doaj.art-f8ccc68864c3405aa3fde7d89338b2d4 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-20T19:47:47Z |
| publishDate | 2017-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-f8ccc68864c3405aa3fde7d89338b2d42022-12-21T19:28:23ZengInternational Union of CrystallographyIUCrData2414-31462017-04-0124x17054810.1107/S241431461700548Xsu41342-{(E)-[(4-Anilinophenyl)imino]methyl}-4-[(E)-(4-methoxyphenyl)diazenyl]phenolMd. Serajul Haque Faizi0Necmi Dege1Kateryna Goleva2Department of Chemistry, College of Science, Sultan Qaboos University, PO Box 36 Al-Khod 123, Muscat, Sultanate of OmanOndokuz Mayıs University, Arts and Sciences Faculty, Department of Physics, 55139 Samsun, TurkeyDepartment of Chemistry, Taras Shevchenko National University of Kyiv, 64, Vladimirska Str., Kiev 01601, UkraineIn the title Schiff base compound, C26H22N4O2, the hydroxy group forms a intramolecular hydrogen bond to the imine N atom and generates an S(6) ring motif. The conformation about the C=N and N=N bonds is E. The 4-methoxybenzene ring and the p-phenylenediamine ring are inclined to the phenol ring by 11.61 (17) and 46.04 (17)°, respectively. The terminal N-phenyl ring is inclined to the p-phenylenediamine ring by 50.72 (17)°. In the crystal, adjacent molecules are linked by C—H...O hydrogen bonds, involving the p-phenylenediamine ring and the phenol ring, forming chains along [001]. The chains are linked by a number of C—H...π interactions, forming slabs propagating parallel to (100).http://scripts.iucr.org/cgi-bin/paper?S241431461700548Xcrystal structureazo compoundsdiazenylphenylaminoiminoSchiff basehydrogen bondingC—H...π interactions |
| spellingShingle | Md. Serajul Haque Faizi Necmi Dege Kateryna Goleva 2-{(E)-[(4-Anilinophenyl)imino]methyl}-4-[(E)-(4-methoxyphenyl)diazenyl]phenol IUCrData crystal structure azo compounds diazenyl phenylamino imino Schiff base hydrogen bonding C—H...π interactions |
| title | 2-{(E)-[(4-Anilinophenyl)imino]methyl}-4-[(E)-(4-methoxyphenyl)diazenyl]phenol |
| title_full | 2-{(E)-[(4-Anilinophenyl)imino]methyl}-4-[(E)-(4-methoxyphenyl)diazenyl]phenol |
| title_fullStr | 2-{(E)-[(4-Anilinophenyl)imino]methyl}-4-[(E)-(4-methoxyphenyl)diazenyl]phenol |
| title_full_unstemmed | 2-{(E)-[(4-Anilinophenyl)imino]methyl}-4-[(E)-(4-methoxyphenyl)diazenyl]phenol |
| title_short | 2-{(E)-[(4-Anilinophenyl)imino]methyl}-4-[(E)-(4-methoxyphenyl)diazenyl]phenol |
| title_sort | 2 e 4 anilinophenyl imino methyl 4 e 4 methoxyphenyl diazenyl phenol |
| topic | crystal structure azo compounds diazenyl phenylamino imino Schiff base hydrogen bonding C—H...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461700548X |
| work_keys_str_mv | AT mdserajulhaquefaizi 2e4anilinophenyliminomethyl4e4methoxyphenyldiazenylphenol AT necmidege 2e4anilinophenyliminomethyl4e4methoxyphenyldiazenylphenol AT katerynagoleva 2e4anilinophenyliminomethyl4e4methoxyphenyldiazenylphenol |