Investigation of lead-free BiFeO3–BaTiO3 piezoelectric ceramics through precise composition control
BiFeO3–BaTiO3 is a promising lead-free piezoelectric ceramic, exhibiting high Curie temperature and superior electrochemical characteristics. In this work, [Formula: see text]BiFeO3–xBaTiO3 (BF–xBT, [Formula: see text], 0.28, 0.30, 0.32, 0.34, 0.36) ceramics were fabricated using the conventional so...
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Format: | Article |
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World Scientific Publishing
2023-12-01
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Series: | Journal of Advanced Dielectrics |
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Online Access: | https://www.worldscientific.com/doi/10.1142/S2010135X23500182 |
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author | Hailan Qin Jianwei Zhao Xiaoxin Chen Hongtian Li Shenghao Wang Yuxiao Du Peifeng Li Huanfu Zhou Dawei Wang |
author_facet | Hailan Qin Jianwei Zhao Xiaoxin Chen Hongtian Li Shenghao Wang Yuxiao Du Peifeng Li Huanfu Zhou Dawei Wang |
author_sort | Hailan Qin |
collection | DOAJ |
description | BiFeO3–BaTiO3 is a promising lead-free piezoelectric ceramic, exhibiting high Curie temperature and superior electrochemical characteristics. In this work, [Formula: see text]BiFeO3–xBaTiO3 (BF–xBT, [Formula: see text], 0.28, 0.30, 0.32, 0.34, 0.36) ceramics were fabricated using the conventional solid-state reaction method through precise composition control. Multiple characterization techniques, including X-ray powder diffraction (XRD), scanning electron microscope (SEM), and electrical property testing systems, were applied to systematically examine the crystallographic structure, microstructure, as well as the dielectric, ferroelectric and piezoelectric properties of the BF–xBT ceramics. The XRD results confirm that all compositions exhibit a typical perovskite structure, transitioning from a single rhombohedral phase to a rhombohedral–cubic phase mixture as the BT content increases. SEM shows apparent core–shell microstructures in the ceramics. Notably, the results demonstrated that the BF–0.30BT ceramic exhibits the maximum piezoelectric constant ([Formula: see text]) [Formula: see text][Formula: see text]pC/N, while the BF–0.34BT ceramic displays the maximum converse piezoelectric constant [Formula: see text][Formula: see text]pm/V, which highlights the suitability of BF–BT ceramics for high-performance piezoelectric applications. |
first_indexed | 2024-03-08T16:04:03Z |
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institution | Directory Open Access Journal |
issn | 2010-135X 2010-1368 |
language | English |
last_indexed | 2024-03-08T16:04:03Z |
publishDate | 2023-12-01 |
publisher | World Scientific Publishing |
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series | Journal of Advanced Dielectrics |
spelling | doaj.art-f9137438ebf242809dc87ac7def3a2d62024-01-08T09:02:46ZengWorld Scientific PublishingJournal of Advanced Dielectrics2010-135X2010-13682023-12-01130610.1142/S2010135X23500182Investigation of lead-free BiFeO3–BaTiO3 piezoelectric ceramics through precise composition controlHailan Qin0Jianwei Zhao1Xiaoxin Chen2Hongtian Li3Shenghao Wang4Yuxiao Du5Peifeng Li6Huanfu Zhou7Dawei Wang8Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, P. R. ChinaShenzhen Institute of Advanced Electronic Materials, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, P. R. ChinaKey Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, P. R. ChinaKey Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, P. R. ChinaShenzhen Institute of Advanced Electronic Materials, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, P. R. ChinaShenzhen Institute of Advanced Electronic Materials, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, P. R. ChinaShenzhen Institute of Advanced Electronic Materials, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, P. R. ChinaKey Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, P. R. ChinaFunctional Materials and Acousto-Optic Instruments Institute, School of Instrumentation Science and Engineering, Harbin Institute of Technology, Harbin 150080, P. R. ChinaBiFeO3–BaTiO3 is a promising lead-free piezoelectric ceramic, exhibiting high Curie temperature and superior electrochemical characteristics. In this work, [Formula: see text]BiFeO3–xBaTiO3 (BF–xBT, [Formula: see text], 0.28, 0.30, 0.32, 0.34, 0.36) ceramics were fabricated using the conventional solid-state reaction method through precise composition control. Multiple characterization techniques, including X-ray powder diffraction (XRD), scanning electron microscope (SEM), and electrical property testing systems, were applied to systematically examine the crystallographic structure, microstructure, as well as the dielectric, ferroelectric and piezoelectric properties of the BF–xBT ceramics. The XRD results confirm that all compositions exhibit a typical perovskite structure, transitioning from a single rhombohedral phase to a rhombohedral–cubic phase mixture as the BT content increases. SEM shows apparent core–shell microstructures in the ceramics. Notably, the results demonstrated that the BF–0.30BT ceramic exhibits the maximum piezoelectric constant ([Formula: see text]) [Formula: see text][Formula: see text]pC/N, while the BF–0.34BT ceramic displays the maximum converse piezoelectric constant [Formula: see text][Formula: see text]pm/V, which highlights the suitability of BF–BT ceramics for high-performance piezoelectric applications.https://www.worldscientific.com/doi/10.1142/S2010135X23500182BiFeO3–BaTiO3morphotropic phase boundarycore–shell microstructurepiezoelectricity |
spellingShingle | Hailan Qin Jianwei Zhao Xiaoxin Chen Hongtian Li Shenghao Wang Yuxiao Du Peifeng Li Huanfu Zhou Dawei Wang Investigation of lead-free BiFeO3–BaTiO3 piezoelectric ceramics through precise composition control Journal of Advanced Dielectrics BiFeO3–BaTiO3 morphotropic phase boundary core–shell microstructure piezoelectricity |
title | Investigation of lead-free BiFeO3–BaTiO3 piezoelectric ceramics through precise composition control |
title_full | Investigation of lead-free BiFeO3–BaTiO3 piezoelectric ceramics through precise composition control |
title_fullStr | Investigation of lead-free BiFeO3–BaTiO3 piezoelectric ceramics through precise composition control |
title_full_unstemmed | Investigation of lead-free BiFeO3–BaTiO3 piezoelectric ceramics through precise composition control |
title_short | Investigation of lead-free BiFeO3–BaTiO3 piezoelectric ceramics through precise composition control |
title_sort | investigation of lead free bifeo3 batio3 piezoelectric ceramics through precise composition control |
topic | BiFeO3–BaTiO3 morphotropic phase boundary core–shell microstructure piezoelectricity |
url | https://www.worldscientific.com/doi/10.1142/S2010135X23500182 |
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