Prediction of Zero Shear Viscosity of Poly (Vinyl Chloride) Plastisols
The rheological behaviour of PVC plastisols composed of a blend of suspension and micro-suspension resins in different proportions was investigated. The present work was mainly focused on the variation of the zero shear viscosity versus the concentration of the extender resin. Hence, the packing fra...
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Format: | Article |
Language: | English |
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De Gruyter
2006-06-01
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Series: | Applied Rheology |
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Online Access: | https://doi.org/10.1515/arh-2006-0009 |
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author | Lainé Carole Cassagnau Philippe |
author_facet | Lainé Carole Cassagnau Philippe |
author_sort | Lainé Carole |
collection | DOAJ |
description | The rheological behaviour of PVC plastisols composed of a blend of suspension and micro-suspension resins in different proportions was investigated. The present work was mainly focused on the variation of the zero shear viscosity versus the concentration of the extender resin. Hence, the packing fraction Fm was evaluated using the Krieger-Dougherty equation. These experiments confirmed the major influence of particle size distribution concerning the decrease of viscosity for concentrated suspensions. In addition, a model based on the porosity model developed by Ouchiyama et al. (Ouchiyama N, Tanaka T: Porosity estimation for random packings of spherical particle”, Ind. Eng. Chem. Fundam. 23 (1984) 490-493) to predict the packing fraction in the case of multimodal lattices was successfully applied to our PVC plastisols formulations. |
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format | Article |
id | doaj.art-f9163a321a9547e693d54a544bb9f407 |
institution | Directory Open Access Journal |
issn | 1617-8106 |
language | English |
last_indexed | 2024-12-16T12:58:25Z |
publishDate | 2006-06-01 |
publisher | De Gruyter |
record_format | Article |
series | Applied Rheology |
spelling | doaj.art-f9163a321a9547e693d54a544bb9f4072022-12-21T22:30:56ZengDe GruyterApplied Rheology1617-81062006-06-0116313614410.1515/arh-2006-0009Prediction of Zero Shear Viscosity of Poly (Vinyl Chloride) PlastisolsLainé Carole0Cassagnau Philippe1Laboratoire Matériaux Polymères et Biomatériaux (LMPB), UMR CNRS 5627 – Ingénierie des Matériaux Polymères (IMP), 15 Boulevard Latarjet, 69622Villeurbanne Cedex, France.Laboratoire Matériaux Polymères et Biomatériaux (LMPB), UMR CNRS 5627 – Ingénierie des Matériaux Polymères (IMP), 15 Boulevard Latarjet, 69622Villeurbanne Cedex, France.The rheological behaviour of PVC plastisols composed of a blend of suspension and micro-suspension resins in different proportions was investigated. The present work was mainly focused on the variation of the zero shear viscosity versus the concentration of the extender resin. Hence, the packing fraction Fm was evaluated using the Krieger-Dougherty equation. These experiments confirmed the major influence of particle size distribution concerning the decrease of viscosity for concentrated suspensions. In addition, a model based on the porosity model developed by Ouchiyama et al. (Ouchiyama N, Tanaka T: Porosity estimation for random packings of spherical particle”, Ind. Eng. Chem. Fundam. 23 (1984) 490-493) to predict the packing fraction in the case of multimodal lattices was successfully applied to our PVC plastisols formulations.https://doi.org/10.1515/arh-2006-0009pvc plastisolsrheologyparticles size distributionmaximum packing fraction |
spellingShingle | Lainé Carole Cassagnau Philippe Prediction of Zero Shear Viscosity of Poly (Vinyl Chloride) Plastisols Applied Rheology pvc plastisols rheology particles size distribution maximum packing fraction |
title | Prediction of Zero Shear Viscosity of Poly (Vinyl Chloride) Plastisols |
title_full | Prediction of Zero Shear Viscosity of Poly (Vinyl Chloride) Plastisols |
title_fullStr | Prediction of Zero Shear Viscosity of Poly (Vinyl Chloride) Plastisols |
title_full_unstemmed | Prediction of Zero Shear Viscosity of Poly (Vinyl Chloride) Plastisols |
title_short | Prediction of Zero Shear Viscosity of Poly (Vinyl Chloride) Plastisols |
title_sort | prediction of zero shear viscosity of poly vinyl chloride plastisols |
topic | pvc plastisols rheology particles size distribution maximum packing fraction |
url | https://doi.org/10.1515/arh-2006-0009 |
work_keys_str_mv | AT lainecarole predictionofzeroshearviscosityofpolyvinylchlorideplastisols AT cassagnauphilippe predictionofzeroshearviscosityofpolyvinylchlorideplastisols |