(7,8-Dimethyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodithioate
In the title compound, C18H21NO2S2, the 2H-chromene ring systems is nearly planar, with a maximum deviation of 0.023 (2) Å. The coumarin unit makes a dihedral angle of 60.54 (8)° with the piperidine ring, which adopts a chair conformation. The carbodithioate group is present in a synperiplanar confo...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-02-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616001711 |
| _version_ | 1828808461779992576 |
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| author | A. J. Ravi K. Mahesh Kumar H. C. Devarajegowda |
| author_facet | A. J. Ravi K. Mahesh Kumar H. C. Devarajegowda |
| author_sort | A. J. Ravi |
| collection | DOAJ |
| description | In the title compound, C18H21NO2S2, the 2H-chromene ring systems is nearly planar, with a maximum deviation of 0.023 (2) Å. The coumarin unit makes a dihedral angle of 60.54 (8)° with the piperidine ring, which adopts a chair conformation. The carbodithioate group is present in a synperiplanar conformation with respect to the piperidine ring, as indicated by the torsion angle of −4.7 (2)°. A short intramolecular C—H...S conatct generates an S(5) ring. No directional interactions beyond van der Waals contacts could be identified in the crystal. |
| first_indexed | 2024-12-12T08:42:01Z |
| format | Article |
| id | doaj.art-f9217a006ec747108d46ba06ab6cd0bd |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-12T08:42:01Z |
| publishDate | 2016-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-f9217a006ec747108d46ba06ab6cd0bd2022-12-22T00:30:46ZengInternational Union of CrystallographyIUCrData2414-31462016-02-0112x16017110.1107/S2414314616001711hb4015(7,8-Dimethyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodithioateA. J. Ravi0K. Mahesh Kumar1H. C. Devarajegowda2Department of Physics, Yuvaraja's College (Constituent College), University of Mysore, Mysore 570 005, Karnataka, IndiaDepartment of Chemistry, Karnatak University's Karnatak Science College, Dharwad, Karnataka 580 001, IndiaDepartment of Physics, Yuvaraja's College (Constituent College), University of Mysore, Mysore 570 005, Karnataka, IndiaIn the title compound, C18H21NO2S2, the 2H-chromene ring systems is nearly planar, with a maximum deviation of 0.023 (2) Å. The coumarin unit makes a dihedral angle of 60.54 (8)° with the piperidine ring, which adopts a chair conformation. The carbodithioate group is present in a synperiplanar conformation with respect to the piperidine ring, as indicated by the torsion angle of −4.7 (2)°. A short intramolecular C—H...S conatct generates an S(5) ring. No directional interactions beyond van der Waals contacts could be identified in the crystal.http://scripts.iucr.org/cgi-bin/paper?S2414314616001711crystal structurecoumarinpiperidinehydrogen bonding |
| spellingShingle | A. J. Ravi K. Mahesh Kumar H. C. Devarajegowda (7,8-Dimethyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodithioate IUCrData crystal structure coumarin piperidine hydrogen bonding |
| title | (7,8-Dimethyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodithioate |
| title_full | (7,8-Dimethyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodithioate |
| title_fullStr | (7,8-Dimethyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodithioate |
| title_full_unstemmed | (7,8-Dimethyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodithioate |
| title_short | (7,8-Dimethyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbodithioate |
| title_sort | 7 8 dimethyl 2 oxo 2h chromen 4 yl methyl piperidine 1 carbodithioate |
| topic | crystal structure coumarin piperidine hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616001711 |
| work_keys_str_mv | AT ajravi 78dimethyl2oxo2hchromen4ylmethylpiperidine1carbodithioate AT kmaheshkumar 78dimethyl2oxo2hchromen4ylmethylpiperidine1carbodithioate AT hcdevarajegowda 78dimethyl2oxo2hchromen4ylmethylpiperidine1carbodithioate |