Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II)
In the title compound, [Hg(C14H13N4O3)Cl], the HgII atom is four-coordinated by one O atom and two N atoms from a tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenide ligand and one terminal chloride ion in a distorted square-planar geometry. In the crystal structure, the mononuclear complexes...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810027819 |
| _version_ | 1818489387460067328 |
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| author | Mohammad Reza Melardi Zeynab Roohi Nazanin Heidari Mohammad Kazem Rofouei |
| author_facet | Mohammad Reza Melardi Zeynab Roohi Nazanin Heidari Mohammad Kazem Rofouei |
| author_sort | Mohammad Reza Melardi |
| collection | DOAJ |
| description | In the title compound, [Hg(C14H13N4O3)Cl], the HgII atom is four-coordinated by one O atom and two N atoms from a tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenide ligand and one terminal chloride ion in a distorted square-planar geometry. In the crystal structure, the mononuclear complexes are linked into pairs through C—H...O and C—H...Cl hydrogen bonds as well as π–π and C—H...π stacking interactions. In addition, weak Hg–μ6-arene π-interactions [mean distance of 3.667 (2) Å] are present between these dimers. The π–π stacking interactions are between aromatic rings with a centroid–centroid distance of 3.884 (2) Å. Moreover, edge-to-face interactions are present between ethoxy CH groups and aromatic rings with H...π distances of 2.81 Å. |
| first_indexed | 2024-12-10T17:03:15Z |
| format | Article |
| id | doaj.art-f9267095a3014723b974f9b3416aa7f6 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T17:03:15Z |
| publishDate | 2010-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f9267095a3014723b974f9b3416aa7f62022-12-22T01:40:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m975m97510.1107/S1600536810027819Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II)Mohammad Reza MelardiZeynab RoohiNazanin HeidariMohammad Kazem RofoueiIn the title compound, [Hg(C14H13N4O3)Cl], the HgII atom is four-coordinated by one O atom and two N atoms from a tridentate 1-(2-ethoxyphenyl)-3-(4-nitrophenyl)triazenide ligand and one terminal chloride ion in a distorted square-planar geometry. In the crystal structure, the mononuclear complexes are linked into pairs through C—H...O and C—H...Cl hydrogen bonds as well as π–π and C—H...π stacking interactions. In addition, weak Hg–μ6-arene π-interactions [mean distance of 3.667 (2) Å] are present between these dimers. The π–π stacking interactions are between aromatic rings with a centroid–centroid distance of 3.884 (2) Å. Moreover, edge-to-face interactions are present between ethoxy CH groups and aromatic rings with H...π distances of 2.81 Å.http://scripts.iucr.org/cgi-bin/paper?S1600536810027819 |
| spellingShingle | Mohammad Reza Melardi Zeynab Roohi Nazanin Heidari Mohammad Kazem Rofouei Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) Acta Crystallographica Section E |
| title | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
| title_full | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
| title_fullStr | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
| title_full_unstemmed | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
| title_short | Chlorido[1-(2-ethoxyphenyl)3-(4-nitrophenyl)triazenido]mercury(II) |
| title_sort | chlorido 1 2 ethoxyphenyl 3 4 nitrophenyl triazenido mercury ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810027819 |
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