Exploring the Properties of Niobium Oxide Films for Electron Transport Layers in Perovskite Solar Cells

In this work, niobium oxide films were deposited by reactive magnetron sputtering under different oxygen flow rate and applied as electron transport layer in perovskite solar cells. It was found that the deposition made using 3.5 sccm of oxygen flow resulted in films with better electrical propertie...

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Main Authors: Silvia Leticia Fernandes, Luiz Gustavo Simão Albano, Lucas Jorge Affonço, José Humberto Dias da Silva, Elson Longo, Carlos Frederico de Oliveira Graeff
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-02-01
Series:Frontiers in Chemistry
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00050/full
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author Silvia Leticia Fernandes
Luiz Gustavo Simão Albano
Lucas Jorge Affonço
José Humberto Dias da Silva
Elson Longo
Carlos Frederico de Oliveira Graeff
author_facet Silvia Leticia Fernandes
Luiz Gustavo Simão Albano
Lucas Jorge Affonço
José Humberto Dias da Silva
Elson Longo
Carlos Frederico de Oliveira Graeff
author_sort Silvia Leticia Fernandes
collection DOAJ
description In this work, niobium oxide films were deposited by reactive magnetron sputtering under different oxygen flow rate and applied as electron transport layer in perovskite solar cells. It was found that the deposition made using 3.5 sccm of oxygen flow resulted in films with better electrical properties which helped the extraction of the photogenerated electrons to the external circuit, improving the Jsc and consequently the device efficiency. In addition, by photoluminescence measurements, we found a better charge transfer from perovskite to TiO2/niobium oxide film deposited at 3.5 sccm of oxygen flow.
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spelling doaj.art-f92b384c7d2b4b2e98118c8f822da50c2022-12-21T19:07:25ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462019-02-01710.3389/fchem.2019.00050430070Exploring the Properties of Niobium Oxide Films for Electron Transport Layers in Perovskite Solar CellsSilvia Leticia Fernandes0Luiz Gustavo Simão Albano1Lucas Jorge Affonço2José Humberto Dias da Silva3Elson Longo4Carlos Frederico de Oliveira Graeff5Department of Chemistry, Federal University of São Carlos (UFSCAR), São Carlos, BrazilDepartment of Physics, School of Sciences, São Paulo State University (UNESP), Bauru, BrazilDepartment of Physics, School of Sciences, São Paulo State University (UNESP), Bauru, BrazilDepartment of Physics, School of Sciences, São Paulo State University (UNESP), Bauru, BrazilDepartment of Chemistry, Federal University of São Carlos (UFSCAR), São Carlos, BrazilDepartment of Physics, School of Sciences, São Paulo State University (UNESP), Bauru, BrazilIn this work, niobium oxide films were deposited by reactive magnetron sputtering under different oxygen flow rate and applied as electron transport layer in perovskite solar cells. It was found that the deposition made using 3.5 sccm of oxygen flow resulted in films with better electrical properties which helped the extraction of the photogenerated electrons to the external circuit, improving the Jsc and consequently the device efficiency. In addition, by photoluminescence measurements, we found a better charge transfer from perovskite to TiO2/niobium oxide film deposited at 3.5 sccm of oxygen flow.https://www.frontiersin.org/article/10.3389/fchem.2019.00050/fullniobium oxide filmperovskite solar cellelectron transport layermethyl ammonium lead iodidereactive sputtering
spellingShingle Silvia Leticia Fernandes
Luiz Gustavo Simão Albano
Lucas Jorge Affonço
José Humberto Dias da Silva
Elson Longo
Carlos Frederico de Oliveira Graeff
Exploring the Properties of Niobium Oxide Films for Electron Transport Layers in Perovskite Solar Cells
Frontiers in Chemistry
niobium oxide film
perovskite solar cell
electron transport layer
methyl ammonium lead iodide
reactive sputtering
title Exploring the Properties of Niobium Oxide Films for Electron Transport Layers in Perovskite Solar Cells
title_full Exploring the Properties of Niobium Oxide Films for Electron Transport Layers in Perovskite Solar Cells
title_fullStr Exploring the Properties of Niobium Oxide Films for Electron Transport Layers in Perovskite Solar Cells
title_full_unstemmed Exploring the Properties of Niobium Oxide Films for Electron Transport Layers in Perovskite Solar Cells
title_short Exploring the Properties of Niobium Oxide Films for Electron Transport Layers in Perovskite Solar Cells
title_sort exploring the properties of niobium oxide films for electron transport layers in perovskite solar cells
topic niobium oxide film
perovskite solar cell
electron transport layer
methyl ammonium lead iodide
reactive sputtering
url https://www.frontiersin.org/article/10.3389/fchem.2019.00050/full
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