Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdosilicate tetrahydrate
The asymmetric unit of the title compound, [Ni(C8H7N3)3]2[SiMo12O40]·4H2O, consists of a complex [Ni(C8H7N3)3]2+ cation, half of a Keggin-type heteropolyanion [SiMo12O40]4− and two uncoordinated water molecules. The Ni2+ cation is surrounded in a slightly distorted octahed...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-02-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810000978 |
| _version_ | 1819349421085687808 |
|---|---|
| author | Xiutang Zhang Dong Yuan Peihai Wei Bin Li Bo Hu |
| author_facet | Xiutang Zhang Dong Yuan Peihai Wei Bin Li Bo Hu |
| author_sort | Xiutang Zhang |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, [Ni(C8H7N3)3]2[SiMo12O40]·4H2O, consists of a complex [Ni(C8H7N3)3]2+ cation, half of a Keggin-type heteropolyanion [SiMo12O40]4− and two uncoordinated water molecules. The Ni2+ cation is surrounded in a slightly distorted octahedral coordination by six N atoms from three chelating 3-(2-pyridyl)-1H-pyrazole ligands. In the heteropolyanion, two O atoms of the central SiO4 group (overline{1} symmetry) are equally disordered about an inversion centre. N—H...O and O—H...O hydrogen bonding between the cations, anions and the uncoordinated water molecules leads to a consolidation of the structure. |
| first_indexed | 2024-12-24T19:00:15Z |
| format | Article |
| id | doaj.art-f92d6cebf13b4e06886ce68f0880ee54 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T19:00:15Z |
| publishDate | 2010-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-f92d6cebf13b4e06886ce68f0880ee542022-12-21T16:43:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m152m15310.1107/S1600536810000978Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdosilicate tetrahydrateXiutang ZhangDong YuanPeihai WeiBin LiBo HuThe asymmetric unit of the title compound, [Ni(C8H7N3)3]2[SiMo12O40]·4H2O, consists of a complex [Ni(C8H7N3)3]2+ cation, half of a Keggin-type heteropolyanion [SiMo12O40]4− and two uncoordinated water molecules. The Ni2+ cation is surrounded in a slightly distorted octahedral coordination by six N atoms from three chelating 3-(2-pyridyl)-1H-pyrazole ligands. In the heteropolyanion, two O atoms of the central SiO4 group (overline{1} symmetry) are equally disordered about an inversion centre. N—H...O and O—H...O hydrogen bonding between the cations, anions and the uncoordinated water molecules leads to a consolidation of the structure.http://scripts.iucr.org/cgi-bin/paper?S1600536810000978 |
| spellingShingle | Xiutang Zhang Dong Yuan Peihai Wei Bin Li Bo Hu Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdosilicate tetrahydrate Acta Crystallographica Section E |
| title | Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdosilicate tetrahydrate |
| title_full | Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdosilicate tetrahydrate |
| title_fullStr | Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdosilicate tetrahydrate |
| title_full_unstemmed | Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdosilicate tetrahydrate |
| title_short | Bis{tris[3-(2-pyridyl)-1H-pyrazole]nickel(II)} dodecamolybdosilicate tetrahydrate |
| title_sort | bis tris 3 2 pyridyl 1h pyrazole nickel ii dodecamolybdosilicate tetrahydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810000978 |
| work_keys_str_mv | AT xiutangzhang bistris32pyridyl1hpyrazolenickeliidodecamolybdosilicatetetrahydrate AT dongyuan bistris32pyridyl1hpyrazolenickeliidodecamolybdosilicatetetrahydrate AT peihaiwei bistris32pyridyl1hpyrazolenickeliidodecamolybdosilicatetetrahydrate AT binli bistris32pyridyl1hpyrazolenickeliidodecamolybdosilicatetetrahydrate AT bohu bistris32pyridyl1hpyrazolenickeliidodecamolybdosilicatetetrahydrate |