Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents

A series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature isolat...

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Main Authors: Ušćumlić Gordana S., Zreigh Mohamed M., Mijin Dušan Ž.
Format: Article
Language:English
Published: Serbian Chemical Society 2006-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390605445U.pdf
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author Ušćumlić Gordana S.
Zreigh Mohamed M.
Mijin Dušan Ž.
author_facet Ušćumlić Gordana S.
Zreigh Mohamed M.
Mijin Dušan Ž.
author_sort Ušćumlić Gordana S.
collection DOAJ
description A series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature isolation techniques, as well as purification and identification of the products. All the synthesized isocyanurates were identified by their melting point and FTIR, 1H NMR and UV spectroscopic data. Fourier transform infrared spectrophotometry was also used to study the interaction between ammonium perchlorate, hydroxyl terminated poly(butadiene), carboxyl terminated poly(butadiene), poly(butadiene-co-acrylonitrile), poly(propylene ether) cyclotrimethylenetrinitramine and the compounds synthesized in this work which can serve as bonding agents. The results show that tris(2-hydroxyethyl)isocyanurate is a universal bonding agent for the ammonium perchlorate/carboxyl terminated poly(butadiene)/cyclotrimethylenetrinitramine composite propellant system.
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spelling doaj.art-f9498beb7ac04e2daee99887823e6a802022-12-21T21:11:37ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212006-01-0171544545810.2298/JSC0605445U0352-51390605445UInvestigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agentsUšćumlić Gordana S.0Zreigh Mohamed M.1Mijin Dušan Ž.2Tehnološko-metalurški fakultet, BeogradTehnološko-metalurški fakultet, BeogradTehnološko-metalurški fakultet, BeogradA series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature isolation techniques, as well as purification and identification of the products. All the synthesized isocyanurates were identified by their melting point and FTIR, 1H NMR and UV spectroscopic data. Fourier transform infrared spectrophotometry was also used to study the interaction between ammonium perchlorate, hydroxyl terminated poly(butadiene), carboxyl terminated poly(butadiene), poly(butadiene-co-acrylonitrile), poly(propylene ether) cyclotrimethylenetrinitramine and the compounds synthesized in this work which can serve as bonding agents. The results show that tris(2-hydroxyethyl)isocyanurate is a universal bonding agent for the ammonium perchlorate/carboxyl terminated poly(butadiene)/cyclotrimethylenetrinitramine composite propellant system.http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390605445U.pdfisocyanuratesbinderbonding agentinteractionscomposite materialhydrogen bondingftir
spellingShingle Ušćumlić Gordana S.
Zreigh Mohamed M.
Mijin Dušan Ž.
Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents
Journal of the Serbian Chemical Society
isocyanurates
binder
bonding agent
interactions
composite material
hydrogen bonding
ftir
title Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents
title_full Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents
title_fullStr Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents
title_full_unstemmed Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents
title_short Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents
title_sort investigation of the interfacial bonding in composite propellants 1 3 5 trisubstituted isocyanurates as universal bonding agents
topic isocyanurates
binder
bonding agent
interactions
composite material
hydrogen bonding
ftir
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390605445U.pdf
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