Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents
A series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature isolat...
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Serbian Chemical Society
2006-01-01
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Series: | Journal of the Serbian Chemical Society |
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Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390605445U.pdf |
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author | Ušćumlić Gordana S. Zreigh Mohamed M. Mijin Dušan Ž. |
author_facet | Ušćumlić Gordana S. Zreigh Mohamed M. Mijin Dušan Ž. |
author_sort | Ušćumlić Gordana S. |
collection | DOAJ |
description | A series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature isolation techniques, as well as purification and identification of the products. All the synthesized isocyanurates were identified by their melting point and FTIR, 1H NMR and UV spectroscopic data. Fourier transform infrared spectrophotometry was also used to study the interaction between ammonium perchlorate, hydroxyl terminated poly(butadiene), carboxyl terminated poly(butadiene), poly(butadiene-co-acrylonitrile), poly(propylene ether) cyclotrimethylenetrinitramine and the compounds synthesized in this work which can serve as bonding agents. The results show that tris(2-hydroxyethyl)isocyanurate is a universal bonding agent for the ammonium perchlorate/carboxyl terminated poly(butadiene)/cyclotrimethylenetrinitramine composite propellant system. |
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id | doaj.art-f9498beb7ac04e2daee99887823e6a80 |
institution | Directory Open Access Journal |
issn | 0352-5139 1820-7421 |
language | English |
last_indexed | 2024-12-18T10:02:28Z |
publishDate | 2006-01-01 |
publisher | Serbian Chemical Society |
record_format | Article |
series | Journal of the Serbian Chemical Society |
spelling | doaj.art-f9498beb7ac04e2daee99887823e6a802022-12-21T21:11:37ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391820-74212006-01-0171544545810.2298/JSC0605445U0352-51390605445UInvestigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agentsUšćumlić Gordana S.0Zreigh Mohamed M.1Mijin Dušan Ž.2Tehnološko-metalurški fakultet, BeogradTehnološko-metalurški fakultet, BeogradTehnološko-metalurški fakultet, BeogradA series of 1,3,5-trisubstituted isocyanurates (substituents: CH2CH2OH CH2CH=CH2 and CH2CH2COOH) was synthesized according to a modified literature procedure. Experimental investigations included modification of the synthetic procedure in terms of the starting materials, solvents, temperature isolation techniques, as well as purification and identification of the products. All the synthesized isocyanurates were identified by their melting point and FTIR, 1H NMR and UV spectroscopic data. Fourier transform infrared spectrophotometry was also used to study the interaction between ammonium perchlorate, hydroxyl terminated poly(butadiene), carboxyl terminated poly(butadiene), poly(butadiene-co-acrylonitrile), poly(propylene ether) cyclotrimethylenetrinitramine and the compounds synthesized in this work which can serve as bonding agents. The results show that tris(2-hydroxyethyl)isocyanurate is a universal bonding agent for the ammonium perchlorate/carboxyl terminated poly(butadiene)/cyclotrimethylenetrinitramine composite propellant system.http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390605445U.pdfisocyanuratesbinderbonding agentinteractionscomposite materialhydrogen bondingftir |
spellingShingle | Ušćumlić Gordana S. Zreigh Mohamed M. Mijin Dušan Ž. Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents Journal of the Serbian Chemical Society isocyanurates binder bonding agent interactions composite material hydrogen bonding ftir |
title | Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents |
title_full | Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents |
title_fullStr | Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents |
title_full_unstemmed | Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents |
title_short | Investigation of the interfacial bonding in composite propellants. 1,3,5-trisubstituted isocyanurates as universal bonding agents |
title_sort | investigation of the interfacial bonding in composite propellants 1 3 5 trisubstituted isocyanurates as universal bonding agents |
topic | isocyanurates binder bonding agent interactions composite material hydrogen bonding ftir |
url | http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390605445U.pdf |
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