Recent Advances on Mg–Li–Al Systems for Solid-State Hydrogen Storage: A Review
The problem of providing compact and safe storage solutions for hydrogen in solid-state materials is demanding and challenging. The storage solutions for hydrogen required high-capacity storage technologies, which preferably operate at low pressures and have good performances in the kinetics of abso...
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| Format: | Article |
| Language: | English |
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Frontiers Media S.A.
2022-04-01
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| Series: | Frontiers in Energy Research |
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| Online Access: | https://www.frontiersin.org/articles/10.3389/fenrg.2022.875405/full |
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| author | Noratiqah Sazelee Nurul Amirah Ali Muhammad Syarifuddin Yahya Nurul Shafikah Mustafa Firdaus Abdul Halim Yap Saiful Bahri Mohamed Muhammad Zahruddin Ghazali Suwarno Suwarno Mohammad Ismail |
| author_facet | Noratiqah Sazelee Nurul Amirah Ali Muhammad Syarifuddin Yahya Nurul Shafikah Mustafa Firdaus Abdul Halim Yap Saiful Bahri Mohamed Muhammad Zahruddin Ghazali Suwarno Suwarno Mohammad Ismail |
| author_sort | Noratiqah Sazelee |
| collection | DOAJ |
| description | The problem of providing compact and safe storage solutions for hydrogen in solid-state materials is demanding and challenging. The storage solutions for hydrogen required high-capacity storage technologies, which preferably operate at low pressures and have good performances in the kinetics of absorption/desorption. Metal hydrides such as magnesium hydride (MgH2) are promising candidates for such storage solutions, but several drawbacks including high onset desorption temperature (>400°C) and slow sorption kinetics need to be overcome. In this study, we reviewed the recent developments in the hydrogen storage performance development of MgH2 and found that the destabilization concept has been extensively explored. Lithium alanate or LiAlH4 has been used as a destabilizing agent in MgH2–LiAlH4 (Mg–Li–Al) due to its high capacity of hydrogen, which is 10.5 wt.%, and low onset desorption temperature (∼150°C). In this article, a review of the recent advances in the Mg–Li–Al system for the solid-state hydrogen storage material is studied. We discussed the effect of the ratio of MgH2 and LiAlH4, milling time, and additives in the Mg–Li–Al system. After the destabilization concept was introduced, the onset of the desorption temperature and activation energy of MgH2 were reduced, and the sorption properties improved. Further study showed that the intermetallic alloys of Li0.92Mg4.08 and Mg17Al12 that were formed in situ during the dehydrogenation process provide synergetic thermodynamic and kinetic destabilization in the Mg-Li-Al composite system.De/rehydrogenation measurements indicate that the intermetallic alloys of Li0.92Mg4.08 and Mg17Al12 were fully reversibly absorbed and desorbed hydrogen. Next, the remaining challenges and a possible development strategy of the Mg–Li–Al system are analyzed. This review is the first systematic study that focuses on the recent advances in the Mg–Li–Al system for storage solutions for hydrogen in solid-state materials. |
| first_indexed | 2024-12-21T10:28:47Z |
| format | Article |
| id | doaj.art-f98167ca865b430c8a069be54baf48b5 |
| institution | Directory Open Access Journal |
| issn | 2296-598X |
| language | English |
| last_indexed | 2024-12-21T10:28:47Z |
| publishDate | 2022-04-01 |
| publisher | Frontiers Media S.A. |
| record_format | Article |
| series | Frontiers in Energy Research |
| spelling | doaj.art-f98167ca865b430c8a069be54baf48b52022-12-21T19:07:16ZengFrontiers Media S.A.Frontiers in Energy Research2296-598X2022-04-011010.3389/fenrg.2022.875405875405Recent Advances on Mg–Li–Al Systems for Solid-State Hydrogen Storage: A ReviewNoratiqah Sazelee0Nurul Amirah Ali1Muhammad Syarifuddin Yahya2Nurul Shafikah Mustafa3Firdaus Abdul Halim Yap4Saiful Bahri Mohamed5Muhammad Zahruddin Ghazali6Suwarno Suwarno7Mohammad Ismail8Energy Storage Research Group, Faculty of Ocean Engineering Technology and Informatics, Universiti Malaysia Terengganu, Kuala Nerus, MalaysiaEnergy Storage Research Group, Faculty of Ocean Engineering Technology and Informatics, Universiti Malaysia Terengganu, Kuala Nerus, MalaysiaEnergy Storage Research Group, Faculty of Ocean Engineering Technology and Informatics, Universiti Malaysia Terengganu, Kuala Nerus, MalaysiaEnergy Storage Research Group, Faculty of Ocean Engineering Technology and Informatics, Universiti Malaysia Terengganu, Kuala Nerus, MalaysiaFaculty of Innovative Design and Technology, Universiti Sultan Zainal Abidin, Kuala Nerus, MalaysiaFaculty of Innovative Design and Technology, Universiti Sultan Zainal Abidin, Kuala Nerus, MalaysiaCasa Armada Sdn. Bhd., Kemaman, MalaysiaDepartment of Mechanical Engineering, Institut Teknologi Sepuluh Nopember (ITS), Surabaya, IndonesiaEnergy Storage Research Group, Faculty of Ocean Engineering Technology and Informatics, Universiti Malaysia Terengganu, Kuala Nerus, MalaysiaThe problem of providing compact and safe storage solutions for hydrogen in solid-state materials is demanding and challenging. The storage solutions for hydrogen required high-capacity storage technologies, which preferably operate at low pressures and have good performances in the kinetics of absorption/desorption. Metal hydrides such as magnesium hydride (MgH2) are promising candidates for such storage solutions, but several drawbacks including high onset desorption temperature (>400°C) and slow sorption kinetics need to be overcome. In this study, we reviewed the recent developments in the hydrogen storage performance development of MgH2 and found that the destabilization concept has been extensively explored. Lithium alanate or LiAlH4 has been used as a destabilizing agent in MgH2–LiAlH4 (Mg–Li–Al) due to its high capacity of hydrogen, which is 10.5 wt.%, and low onset desorption temperature (∼150°C). In this article, a review of the recent advances in the Mg–Li–Al system for the solid-state hydrogen storage material is studied. We discussed the effect of the ratio of MgH2 and LiAlH4, milling time, and additives in the Mg–Li–Al system. After the destabilization concept was introduced, the onset of the desorption temperature and activation energy of MgH2 were reduced, and the sorption properties improved. Further study showed that the intermetallic alloys of Li0.92Mg4.08 and Mg17Al12 that were formed in situ during the dehydrogenation process provide synergetic thermodynamic and kinetic destabilization in the Mg-Li-Al composite system.De/rehydrogenation measurements indicate that the intermetallic alloys of Li0.92Mg4.08 and Mg17Al12 were fully reversibly absorbed and desorbed hydrogen. Next, the remaining challenges and a possible development strategy of the Mg–Li–Al system are analyzed. This review is the first systematic study that focuses on the recent advances in the Mg–Li–Al system for storage solutions for hydrogen in solid-state materials.https://www.frontiersin.org/articles/10.3389/fenrg.2022.875405/fullMg–Li–Al systemmagnesium hydridelithium alanatehydrogen storagesolid-state storage |
| spellingShingle | Noratiqah Sazelee Nurul Amirah Ali Muhammad Syarifuddin Yahya Nurul Shafikah Mustafa Firdaus Abdul Halim Yap Saiful Bahri Mohamed Muhammad Zahruddin Ghazali Suwarno Suwarno Mohammad Ismail Recent Advances on Mg–Li–Al Systems for Solid-State Hydrogen Storage: A Review Frontiers in Energy Research Mg–Li–Al system magnesium hydride lithium alanate hydrogen storage solid-state storage |
| title | Recent Advances on Mg–Li–Al Systems for Solid-State Hydrogen Storage: A Review |
| title_full | Recent Advances on Mg–Li–Al Systems for Solid-State Hydrogen Storage: A Review |
| title_fullStr | Recent Advances on Mg–Li–Al Systems for Solid-State Hydrogen Storage: A Review |
| title_full_unstemmed | Recent Advances on Mg–Li–Al Systems for Solid-State Hydrogen Storage: A Review |
| title_short | Recent Advances on Mg–Li–Al Systems for Solid-State Hydrogen Storage: A Review |
| title_sort | recent advances on mg li al systems for solid state hydrogen storage a review |
| topic | Mg–Li–Al system magnesium hydride lithium alanate hydrogen storage solid-state storage |
| url | https://www.frontiersin.org/articles/10.3389/fenrg.2022.875405/full |
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