Metasomatic Evolution of Coesite-Bearing Diamondiferous Eclogite from the Udachnaya Kimberlite

A coesite-bearing diamondiferous eclogite from the Udachnaya kimberlite (Daldyn field, Siberian craton) has been studied to trace its complex evolution recorded in rock-forming and minor mineral constituents. The eclogite sample is composed of rock-forming omphacite (60 vol%), garnet (35 vol%) and q...

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Main Authors: Denis Mikhailenko, Alexander Golovin, Andrey Korsakov, Sonja Aulbach, Axel Gerdes, Alexey Ragozin
Format: Article
Language:English
Published: MDPI AG 2020-04-01
Series:Minerals
Subjects:
Online Access:https://www.mdpi.com/2075-163X/10/4/383
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author Denis Mikhailenko
Alexander Golovin
Andrey Korsakov
Sonja Aulbach
Axel Gerdes
Alexey Ragozin
author_facet Denis Mikhailenko
Alexander Golovin
Andrey Korsakov
Sonja Aulbach
Axel Gerdes
Alexey Ragozin
author_sort Denis Mikhailenko
collection DOAJ
description A coesite-bearing diamondiferous eclogite from the Udachnaya kimberlite (Daldyn field, Siberian craton) has been studied to trace its complex evolution recorded in rock-forming and minor mineral constituents. The eclogite sample is composed of rock-forming omphacite (60 vol%), garnet (35 vol%) and quartz/coesite (5 vol%) and contains intergranular euhedral zoned olivine crystals, up to 200 µm long, coexisting with phlogopite, orthopyroxene, clinopyroxene (secondary), K-feldspar, plagioclase, spinel, sodalite and djerfisherite. Garnet grains are zoned, with a relatively homogeneous core and a more magnesian overgrowth rim. The rim zones further differ from the core in having higher Zr/Y (6 times that in the cores), ascribed to interaction with, or precipitation from, a kimberlite-related melt. Judging by pressure-temperature estimates (~1200 °C; 6.2 GPa), the xenolith originated at depths of ~180–200 km at the base of the continental lithosphere. The spatial coexistence of olivine, orthopyroxene and coesite/quartz with K-Na-Cl minerals in the xenolith indicates that eclogite reacted with a deep-seated kimberlite melt. However, Fe-rich olivine, orthopyroxene and low-pressure minerals (sodalite and djerfisherite) likely result from metasomatic reaction at shallower depths during transport of the eclogite by the erupting kimberlite melt. Our results demonstrate that a mixed eclogitic-peridotitic paragenesis, reported previously from inclusions in diamond, can form by interaction of eclogite and a kimberlite-related melt.
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spelling doaj.art-f98b6002658a47ffabb1b88778d235672023-11-19T22:35:01ZengMDPI AGMinerals2075-163X2020-04-0110438310.3390/min10040383Metasomatic Evolution of Coesite-Bearing Diamondiferous Eclogite from the Udachnaya KimberliteDenis Mikhailenko0Alexander Golovin1Andrey Korsakov2Sonja Aulbach3Axel Gerdes4Alexey Ragozin5Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, RussiaSobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, RussiaSobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, RussiaInstitut für Geowissenschaften, Goethe-Universität, Frankfurt am Main, 60323 Frankfurt, GermanyInstitut für Geowissenschaften, Goethe-Universität, Frankfurt am Main, 60323 Frankfurt, GermanySobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090, RussiaA coesite-bearing diamondiferous eclogite from the Udachnaya kimberlite (Daldyn field, Siberian craton) has been studied to trace its complex evolution recorded in rock-forming and minor mineral constituents. The eclogite sample is composed of rock-forming omphacite (60 vol%), garnet (35 vol%) and quartz/coesite (5 vol%) and contains intergranular euhedral zoned olivine crystals, up to 200 µm long, coexisting with phlogopite, orthopyroxene, clinopyroxene (secondary), K-feldspar, plagioclase, spinel, sodalite and djerfisherite. Garnet grains are zoned, with a relatively homogeneous core and a more magnesian overgrowth rim. The rim zones further differ from the core in having higher Zr/Y (6 times that in the cores), ascribed to interaction with, or precipitation from, a kimberlite-related melt. Judging by pressure-temperature estimates (~1200 °C; 6.2 GPa), the xenolith originated at depths of ~180–200 km at the base of the continental lithosphere. The spatial coexistence of olivine, orthopyroxene and coesite/quartz with K-Na-Cl minerals in the xenolith indicates that eclogite reacted with a deep-seated kimberlite melt. However, Fe-rich olivine, orthopyroxene and low-pressure minerals (sodalite and djerfisherite) likely result from metasomatic reaction at shallower depths during transport of the eclogite by the erupting kimberlite melt. Our results demonstrate that a mixed eclogitic-peridotitic paragenesis, reported previously from inclusions in diamond, can form by interaction of eclogite and a kimberlite-related melt.https://www.mdpi.com/2075-163X/10/4/383eclogitelithospheric mantlekimberliteUdachnaya pipemeltingmetasomatism
spellingShingle Denis Mikhailenko
Alexander Golovin
Andrey Korsakov
Sonja Aulbach
Axel Gerdes
Alexey Ragozin
Metasomatic Evolution of Coesite-Bearing Diamondiferous Eclogite from the Udachnaya Kimberlite
Minerals
eclogite
lithospheric mantle
kimberlite
Udachnaya pipe
melting
metasomatism
title Metasomatic Evolution of Coesite-Bearing Diamondiferous Eclogite from the Udachnaya Kimberlite
title_full Metasomatic Evolution of Coesite-Bearing Diamondiferous Eclogite from the Udachnaya Kimberlite
title_fullStr Metasomatic Evolution of Coesite-Bearing Diamondiferous Eclogite from the Udachnaya Kimberlite
title_full_unstemmed Metasomatic Evolution of Coesite-Bearing Diamondiferous Eclogite from the Udachnaya Kimberlite
title_short Metasomatic Evolution of Coesite-Bearing Diamondiferous Eclogite from the Udachnaya Kimberlite
title_sort metasomatic evolution of coesite bearing diamondiferous eclogite from the udachnaya kimberlite
topic eclogite
lithospheric mantle
kimberlite
Udachnaya pipe
melting
metasomatism
url https://www.mdpi.com/2075-163X/10/4/383
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