Molecular Hydrogen and its Proxies HCO+ and CO in the Diffuse Interstellar Medium

There is a robust polyatomic chemistry in diffuse, partially molecular interstellar gas that is readily accessible in absorption at radio/millimeter/submillimeter wavelengths. Accurate column densities are derived owing to the weak internal excitation, so relative molecular abundances are well known...

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Main Authors: Harvey Liszt, Maryvonne Gerin
Format: Article
Language:English
Published: IOP Publishing 2023-01-01
Series:The Astrophysical Journal
Subjects:
Online Access:https://doi.org/10.3847/1538-4357/acae83
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author Harvey Liszt
Maryvonne Gerin
author_facet Harvey Liszt
Maryvonne Gerin
author_sort Harvey Liszt
collection DOAJ
description There is a robust polyatomic chemistry in diffuse, partially molecular interstellar gas that is readily accessible in absorption at radio/millimeter/submillimeter wavelengths. Accurate column densities are derived owing to the weak internal excitation, so relative molecular abundances are well known with respect to each other but not with respect to H _2 . Here we consider the use of proxies for hydrogen column densities N (H _2 ) and N (H) = N (H i )+2 N (H _2 ) based on measurements of HCO ^+ absorption and CO emission and absorption, and we compare these with results obtained by others when observing H i , H _2 and CO toward stars and active galactic nuclei. We consider the use of HCO ^+ as a proxy for H _2 and show that the assumption of a relative abundance N (H _2 ) = N (HCO ^+ )/3 × 10 ^−9 gives the same view of the atomic–molecular hydrogen transition that is seen in UV absorption toward stars. CO on the other hand shows differences between the radio and optical regimes because emission is always detected when N (HCO ^+ ) ≳ 6 × 10 ^11 cm ^−2 or N (H _2 ) ≳ 2 × 10 ^20 cm ^−2 . Wide variations in the integrated CO J = 1 − 0 brightness W _CO and N (CO)/ N (H _2 ) imply equivalent variations in the CO-H _2 conversion factor even while the ensemble mean is near the usual Galactic values. Gas/reddening ratios found in absorption toward stars, N (H)/ E ( B − V ) = 6.2 × 10 ^21 H cm ^−2 (mag) ^−1 overall or 6.8 × 10 ^21 H cm ^−2 (mag) ^−1 for sightlines at E ( B − V ) ≤ 0.08 mag lacking H _2 are well below the Galactic mean measured at low reddening and high Galactic latitude, 8.3 × 10 ^21 H cm ^−2 (mag) ^−1 .
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spelling doaj.art-f991e8d6f6014b91b18d33ee12e4e5802023-09-03T13:07:59ZengIOP PublishingThe Astrophysical Journal1538-43572023-01-01943217210.3847/1538-4357/acae83Molecular Hydrogen and its Proxies HCO+ and CO in the Diffuse Interstellar MediumHarvey Liszt0https://orcid.org/0000-0002-6116-1911Maryvonne Gerin1National Radio Astronomy Observatory, 520 Edgemont Road , Charlottesville, VA 22903, USA ; hliszt@nrao.eduLERMA, Observatoire de Paris, PSL Research University , CNRS, Sorbonne Université, France ; maryvonne.gerin@observatoiredeparis.psl.euThere is a robust polyatomic chemistry in diffuse, partially molecular interstellar gas that is readily accessible in absorption at radio/millimeter/submillimeter wavelengths. Accurate column densities are derived owing to the weak internal excitation, so relative molecular abundances are well known with respect to each other but not with respect to H _2 . Here we consider the use of proxies for hydrogen column densities N (H _2 ) and N (H) = N (H i )+2 N (H _2 ) based on measurements of HCO ^+ absorption and CO emission and absorption, and we compare these with results obtained by others when observing H i , H _2 and CO toward stars and active galactic nuclei. We consider the use of HCO ^+ as a proxy for H _2 and show that the assumption of a relative abundance N (H _2 ) = N (HCO ^+ )/3 × 10 ^−9 gives the same view of the atomic–molecular hydrogen transition that is seen in UV absorption toward stars. CO on the other hand shows differences between the radio and optical regimes because emission is always detected when N (HCO ^+ ) ≳ 6 × 10 ^11 cm ^−2 or N (H _2 ) ≳ 2 × 10 ^20 cm ^−2 . Wide variations in the integrated CO J = 1 − 0 brightness W _CO and N (CO)/ N (H _2 ) imply equivalent variations in the CO-H _2 conversion factor even while the ensemble mean is near the usual Galactic values. Gas/reddening ratios found in absorption toward stars, N (H)/ E ( B − V ) = 6.2 × 10 ^21 H cm ^−2 (mag) ^−1 overall or 6.8 × 10 ^21 H cm ^−2 (mag) ^−1 for sightlines at E ( B − V ) ≤ 0.08 mag lacking H _2 are well below the Galactic mean measured at low reddening and high Galactic latitude, 8.3 × 10 ^21 H cm ^−2 (mag) ^−1 .https://doi.org/10.3847/1538-4357/acae83Diffuse interstellar cloudsInterstellar atomic gasInterstellar molecules
spellingShingle Harvey Liszt
Maryvonne Gerin
Molecular Hydrogen and its Proxies HCO+ and CO in the Diffuse Interstellar Medium
The Astrophysical Journal
Diffuse interstellar clouds
Interstellar atomic gas
Interstellar molecules
title Molecular Hydrogen and its Proxies HCO+ and CO in the Diffuse Interstellar Medium
title_full Molecular Hydrogen and its Proxies HCO+ and CO in the Diffuse Interstellar Medium
title_fullStr Molecular Hydrogen and its Proxies HCO+ and CO in the Diffuse Interstellar Medium
title_full_unstemmed Molecular Hydrogen and its Proxies HCO+ and CO in the Diffuse Interstellar Medium
title_short Molecular Hydrogen and its Proxies HCO+ and CO in the Diffuse Interstellar Medium
title_sort molecular hydrogen and its proxies hco and co in the diffuse interstellar medium
topic Diffuse interstellar clouds
Interstellar atomic gas
Interstellar molecules
url https://doi.org/10.3847/1538-4357/acae83
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