Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples
Monitoring synthetic colorants in foods is important due to their potential toxicity and pathogenicity. We propose here a new and simple method for the extraction and determination of erythrosine B (ERT-B) in food samples. A composite of polydopamine-based molecularly imprinted polymers coating magn...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-10-01
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| Series: | Materials |
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| Online Access: | https://www.mdpi.com/1996-1944/15/21/7653 |
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| author | Dounia Elfadil Flavio Della Pelle Dario Compagnone Aziz Amine |
| author_facet | Dounia Elfadil Flavio Della Pelle Dario Compagnone Aziz Amine |
| author_sort | Dounia Elfadil |
| collection | DOAJ |
| description | Monitoring synthetic colorants in foods is important due to their potential toxicity and pathogenicity. We propose here a new and simple method for the extraction and determination of erythrosine B (ERT-B) in food samples. A composite of polydopamine-based molecularly imprinted polymers coating magnetic nanoparticles (Fe<sub>3</sub>O<sub>4</sub>@PDA@MIP) was synthesized using a green approach and exploited for the magnetic dispersive solid-phase extraction (MDSPE) of ERT-B. Fe<sub>3</sub>O<sub>4</sub>@PDA@MIP provides a rapid extraction of ERT-B, exhibiting good reusability and preconcentration ability. Moreover, the MIP showed a relatively good imprinting factor (3.0 ± 0.05), demonstrating excellent selectivity against patent blue (an interfering dye) and other food matrix components. The proposed MDSPE was coupled to colorimetric smartphone-based detection that allowed us to obtain similar performances of UV–Vis spectroscopy detection. The smartphone-based optical detection facilitated the determination of ERT-B in the 0.5–10 mg/L range, with a limit of detection of 0.04 mg/L. The developed method was successfully employed to determine ERT-B in food samples (juice, candy, and candied cherries) with good recovery values (82–97%). |
| first_indexed | 2024-03-09T18:54:20Z |
| format | Article |
| id | doaj.art-f99580f355bc4098a5ecef14c6819d32 |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-09T18:54:20Z |
| publishDate | 2022-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-f99580f355bc4098a5ecef14c6819d322023-11-24T05:38:39ZengMDPI AGMaterials1996-19442022-10-011521765310.3390/ma15217653Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food SamplesDounia Elfadil0Flavio Della Pelle1Dario Compagnone2Aziz Amine3Faculty of Bioscience and Technology for Food, Agriculture and Environment, University of Teramo, via Renato Balzarini 1, 64100 Teramo, ItalyFaculty of Bioscience and Technology for Food, Agriculture and Environment, University of Teramo, via Renato Balzarini 1, 64100 Teramo, ItalyFaculty of Bioscience and Technology for Food, Agriculture and Environment, University of Teramo, via Renato Balzarini 1, 64100 Teramo, ItalyLaboratory of Process Engineering and Environment, Faculty of Sciences and Techniques, Hassan II University of Casablanca, Mohammedia 20650, MoroccoMonitoring synthetic colorants in foods is important due to their potential toxicity and pathogenicity. We propose here a new and simple method for the extraction and determination of erythrosine B (ERT-B) in food samples. A composite of polydopamine-based molecularly imprinted polymers coating magnetic nanoparticles (Fe<sub>3</sub>O<sub>4</sub>@PDA@MIP) was synthesized using a green approach and exploited for the magnetic dispersive solid-phase extraction (MDSPE) of ERT-B. Fe<sub>3</sub>O<sub>4</sub>@PDA@MIP provides a rapid extraction of ERT-B, exhibiting good reusability and preconcentration ability. Moreover, the MIP showed a relatively good imprinting factor (3.0 ± 0.05), demonstrating excellent selectivity against patent blue (an interfering dye) and other food matrix components. The proposed MDSPE was coupled to colorimetric smartphone-based detection that allowed us to obtain similar performances of UV–Vis spectroscopy detection. The smartphone-based optical detection facilitated the determination of ERT-B in the 0.5–10 mg/L range, with a limit of detection of 0.04 mg/L. The developed method was successfully employed to determine ERT-B in food samples (juice, candy, and candied cherries) with good recovery values (82–97%).https://www.mdpi.com/1996-1944/15/21/7653synthetic colorantsfood samplesmagnetic dispersive solid-phase extractionpolydopaminemolecularly imprinted polymers |
| spellingShingle | Dounia Elfadil Flavio Della Pelle Dario Compagnone Aziz Amine Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples Materials synthetic colorants food samples magnetic dispersive solid-phase extraction polydopamine molecularly imprinted polymers |
| title | Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples |
| title_full | Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples |
| title_fullStr | Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples |
| title_full_unstemmed | Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples |
| title_short | Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples |
| title_sort | green synthesis of molecularly imprinted polymers for dispersive magnetic solid phase extraction of erythrosine b associated with smartphone detection in food samples |
| topic | synthetic colorants food samples magnetic dispersive solid-phase extraction polydopamine molecularly imprinted polymers |
| url | https://www.mdpi.com/1996-1944/15/21/7653 |
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