Synthesis and characterization of Strontium Barium Niobate (SBN) ferroelectric thin films

Strontium barium niobate (SBN) thin films of good quality were deposited on Si and Pt/Si substrates using a polymeric resin produced by different starting precursors. Using X-ray diffraction, the presence of SBN phase could be identified for films annealed between 500-700ºC for 1 hour on both substr...

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Main Authors: Mendes, R. G., Araújo, E. B., Klein, H., Eiras, J. A.
Format: Article
Language:English
Published: Elsevier 1999-10-01
Series:Boletín de la Sociedad Española de Cerámica y Vidrio
Subjects:
Online Access:http://ceramicayvidrio.revistas.csic.es/index.php/ceramicayvidrio/article/view/931/962
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author Mendes, R. G.
Araújo, E. B.
Klein, H.
Eiras, J. A.
author_facet Mendes, R. G.
Araújo, E. B.
Klein, H.
Eiras, J. A.
author_sort Mendes, R. G.
collection DOAJ
description Strontium barium niobate (SBN) thin films of good quality were deposited on Si and Pt/Si substrates using a polymeric resin produced by different starting precursors. Using X-ray diffraction, the presence of SBN phase could be identified for films annealed between 500-700ºC for 1 hour on both substrates. Undesired phases, such as SrNb2O6 and BaNb2O6, appear crystallized in films deposited on Si over annealing temperatures between 500-700ºC. However, these phases appear only at 500ºC for films deposited on Pt/Si. Dielectric characterization of SBN films indicated a dielectric constant 27 and dissipation factor of 0.047 at 100 KHz. Hysteresis loops were observed at room temperature for of SBN film annealed at 700ºC for 1 hour. At 100 Hz frequency, the remanent polarization, Pr, and the coercive field, Ec, were 18.4 mC/cm2 and 147.7 kV/cm, respectively.<br><br>Las láminas delgadas de niobato de estroncio bario de buena calidad fueron depositadas sobre substratos de Si y Pt/Si mediante el empleo de una resina polimérica producida a partir de diferentes precursores. Por medio de difracción de rayos X se identificó la presencia de SBN para láminas tratadas entre 500-700ºC durante 1 hora sobre ambos substratos. Las fases no deseadas, como SrNb2O6 y BaNb2O6, aparecen cristalizadas en láminas depositadas sobre Si tratadas entre 500-700ºC. Sin embargo, estas fases aparecen solo a 500ºC para láminas depositadas sobre Pt/Si. La caracterización dieléctrica de las láminas de SBN presenta una constante dieléctrica de 27 y un factor de disipación de 0.047 a 100 kHz. Las curvas de histéresis fueron observadas a temperatura ambiente para láminas tratadas a 700ºC durante 1 hora. A la frecuencia de 100 Hz, la polarización remanente, Pr, y el campo coercitivo, Ec, fueron 18.4 mC/cm2 y 147.7 kV/cm, respectivamente.
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spelling doaj.art-f99d9cdb74e64ebbbdc68f1a645291042022-12-22T01:03:37ZengElsevierBoletín de la Sociedad Española de Cerámica y Vidrio0366-31751999-10-01385455457Synthesis and characterization of Strontium Barium Niobate (SBN) ferroelectric thin filmsMendes, R. G.Araújo, E. B.Klein, H.Eiras, J. A.Strontium barium niobate (SBN) thin films of good quality were deposited on Si and Pt/Si substrates using a polymeric resin produced by different starting precursors. Using X-ray diffraction, the presence of SBN phase could be identified for films annealed between 500-700ºC for 1 hour on both substrates. Undesired phases, such as SrNb2O6 and BaNb2O6, appear crystallized in films deposited on Si over annealing temperatures between 500-700ºC. However, these phases appear only at 500ºC for films deposited on Pt/Si. Dielectric characterization of SBN films indicated a dielectric constant 27 and dissipation factor of 0.047 at 100 KHz. Hysteresis loops were observed at room temperature for of SBN film annealed at 700ºC for 1 hour. At 100 Hz frequency, the remanent polarization, Pr, and the coercive field, Ec, were 18.4 mC/cm2 and 147.7 kV/cm, respectively.<br><br>Las láminas delgadas de niobato de estroncio bario de buena calidad fueron depositadas sobre substratos de Si y Pt/Si mediante el empleo de una resina polimérica producida a partir de diferentes precursores. Por medio de difracción de rayos X se identificó la presencia de SBN para láminas tratadas entre 500-700ºC durante 1 hora sobre ambos substratos. Las fases no deseadas, como SrNb2O6 y BaNb2O6, aparecen cristalizadas en láminas depositadas sobre Si tratadas entre 500-700ºC. Sin embargo, estas fases aparecen solo a 500ºC para láminas depositadas sobre Pt/Si. La caracterización dieléctrica de las láminas de SBN presenta una constante dieléctrica de 27 y un factor de disipación de 0.047 a 100 kHz. Las curvas de histéresis fueron observadas a temperatura ambiente para láminas tratadas a 700ºC durante 1 hora. A la frecuencia de 100 Hz, la polarización remanente, Pr, y el campo coercitivo, Ec, fueron 18.4 mC/cm2 y 147.7 kV/cm, respectivamente.http://ceramicayvidrio.revistas.csic.es/index.php/ceramicayvidrio/article/view/931/962SBNthin filmsferroelectricSBNlámina delgadaferroeléctricos
spellingShingle Mendes, R. G.
Araújo, E. B.
Klein, H.
Eiras, J. A.
Synthesis and characterization of Strontium Barium Niobate (SBN) ferroelectric thin films
Boletín de la Sociedad Española de Cerámica y Vidrio
SBN
thin films
ferroelectric
SBN
lámina delgada
ferroeléctricos
title Synthesis and characterization of Strontium Barium Niobate (SBN) ferroelectric thin films
title_full Synthesis and characterization of Strontium Barium Niobate (SBN) ferroelectric thin films
title_fullStr Synthesis and characterization of Strontium Barium Niobate (SBN) ferroelectric thin films
title_full_unstemmed Synthesis and characterization of Strontium Barium Niobate (SBN) ferroelectric thin films
title_short Synthesis and characterization of Strontium Barium Niobate (SBN) ferroelectric thin films
title_sort synthesis and characterization of strontium barium niobate sbn ferroelectric thin films
topic SBN
thin films
ferroelectric
SBN
lámina delgada
ferroeléctricos
url http://ceramicayvidrio.revistas.csic.es/index.php/ceramicayvidrio/article/view/931/962
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AT kleinh synthesisandcharacterizationofstrontiumbariumniobatesbnferroelectricthinfilms
AT eirasja synthesisandcharacterizationofstrontiumbariumniobatesbnferroelectricthinfilms