Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic Coupling
Mixed-valent trinuclear manganese complex with N,N’-bis(2-hydroxy-3,5-dimethylbenzyl-N,N’-dimethyl-1,2-ethanediamine (H2hdde), [Mn3(hdde)2(CH3CO2)2(CH3O)2], was synthesized. The X-ray crystal structure analysis revealed a linearly arrangement of MnIII-MnII-MnIIIcore, where a ferromagnetic coupling...
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| Format: | Article |
| Language: | English |
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Academy of Sciences of Moldova, Institute of Chemistry
2017-12-01
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| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| Subjects: | |
| Online Access: |
http://cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2017.446-Mikuriya.pdf
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| author | Masahiro Mikuriya Iyo Matsushima Daisuke Yoshioka |
| author_facet | Masahiro Mikuriya Iyo Matsushima Daisuke Yoshioka |
| author_sort | Masahiro Mikuriya |
| collection | DOAJ |
| description | Mixed-valent trinuclear manganese complex with N,N’-bis(2-hydroxy-3,5-dimethylbenzyl-N,N’-dimethyl-1,2-ethanediamine (H2hdde), [Mn3(hdde)2(CH3CO2)2(CH3O)2], was synthesized. The X-ray crystal structure analysis revealed a linearly arrangement of MnIII-MnII-MnIIIcore, where a ferromagnetic coupling (J = 2.62 cm–1) between the MnIII and MnII ions. |
| first_indexed | 2024-12-22T15:24:09Z |
| format | Article |
| id | doaj.art-f9a48172433e494da6a110ce38a6780c |
| institution | Directory Open Access Journal |
| issn | 1857-1727 2345-1688 |
| language | English |
| last_indexed | 2024-12-22T15:24:09Z |
| publishDate | 2017-12-01 |
| publisher | Academy of Sciences of Moldova, Institute of Chemistry |
| record_format | Article |
| series | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
| spelling | doaj.art-f9a48172433e494da6a110ce38a6780c2022-12-21T18:21:33ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882017-12-01122344010.19261/cjm.2017.446446Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic CouplingMasahiro Mikuriya0Iyo Matsushima1Daisuke Yoshioka2 Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan Mixed-valent trinuclear manganese complex with N,N’-bis(2-hydroxy-3,5-dimethylbenzyl-N,N’-dimethyl-1,2-ethanediamine (H2hdde), [Mn3(hdde)2(CH3CO2)2(CH3O)2], was synthesized. The X-ray crystal structure analysis revealed a linearly arrangement of MnIII-MnII-MnIIIcore, where a ferromagnetic coupling (J = 2.62 cm–1) between the MnIII and MnII ions. http://cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2017.446-Mikuriya.pdf manganese complextrinuclear complexmagnetic propertyferromagnetic interaction |
| spellingShingle | Masahiro Mikuriya Iyo Matsushima Daisuke Yoshioka Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic Coupling Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry manganese complex trinuclear complex magnetic property ferromagnetic interaction |
| title | Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic Coupling |
| title_full | Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic Coupling |
| title_fullStr | Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic Coupling |
| title_full_unstemmed | Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic Coupling |
| title_short | Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic Coupling |
| title_sort | trinuclear mixed valent manganese complex with non schiff base tetradentate ligand showing a ferromagnetic coupling |
| topic | manganese complex trinuclear complex magnetic property ferromagnetic interaction |
| url |
http://cjm.asm.md/sites/default/files/article_files/ChemJMold_10.19261cjm.2017.446-Mikuriya.pdf
|
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