Synthesis and properties of PI composite films using carbon quantum dots as fillers

Polyimide (PI) is widely used in the field of microelectronics because of its excellent thermal, mechanical, optical, and electrical properties. With the development of electronics and information industry, PI as a dielectric material needs to possess low dielectric loss. PI/carbon quantum dots (PI/...

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Main Authors: Zhang Yuyin, Guo Hongtao, Jiang Shaohua, Hu Zhaoyu, Zha Guojun, Liu Kunming, Hou Haoqing
Format: Article
Language:English
Published: De Gruyter 2022-07-01
Series:e-Polymers
Subjects:
Online Access:https://doi.org/10.1515/epoly-2022-0054
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author Zhang Yuyin
Guo Hongtao
Jiang Shaohua
Hu Zhaoyu
Zha Guojun
Liu Kunming
Hou Haoqing
author_facet Zhang Yuyin
Guo Hongtao
Jiang Shaohua
Hu Zhaoyu
Zha Guojun
Liu Kunming
Hou Haoqing
author_sort Zhang Yuyin
collection DOAJ
description Polyimide (PI) is widely used in the field of microelectronics because of its excellent thermal, mechanical, optical, and electrical properties. With the development of electronics and information industry, PI as a dielectric material needs to possess low dielectric loss. PI/carbon quantum dots (PI/CQDs) composite films with low dielectric loss were prepared by introducing CQDs into PI matrix. At 25°C and 1 kHz voltage, the dielectric loss of pure PI film is about 0.0057. The dielectric loss of PI/CQDs composite film is about 0.0018, which is about 68% lower than that of pure PI film. The dielectric loss of PI/CQD composite film is greatly reduced while the mechanical properties and thermal properties of PI/CQDs composite film roughly remain unchanged. Due to the cross-linking structure formed between CQDs and PI molecular chain, the relative movement of PI molecular chain is hindered.
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spelling doaj.art-f9b29f494f2e4c7598b6c7a54c37d86f2022-12-22T04:29:00ZengDe Gruytere-Polymers1618-72292022-07-0122157758410.1515/epoly-2022-0054Synthesis and properties of PI composite films using carbon quantum dots as fillersZhang Yuyin0Guo Hongtao1Jiang Shaohua2Hu Zhaoyu3Zha Guojun4Liu Kunming5Hou Haoqing6College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, ChinaJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, 210037, ChinaJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, 210037, ChinaCollege of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, ChinaCollege of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, ChinaFaculty of Materials Metallurgy and Chemistry, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaCollege of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang, ChinaPolyimide (PI) is widely used in the field of microelectronics because of its excellent thermal, mechanical, optical, and electrical properties. With the development of electronics and information industry, PI as a dielectric material needs to possess low dielectric loss. PI/carbon quantum dots (PI/CQDs) composite films with low dielectric loss were prepared by introducing CQDs into PI matrix. At 25°C and 1 kHz voltage, the dielectric loss of pure PI film is about 0.0057. The dielectric loss of PI/CQDs composite film is about 0.0018, which is about 68% lower than that of pure PI film. The dielectric loss of PI/CQD composite film is greatly reduced while the mechanical properties and thermal properties of PI/CQDs composite film roughly remain unchanged. Due to the cross-linking structure formed between CQDs and PI molecular chain, the relative movement of PI molecular chain is hindered.https://doi.org/10.1515/epoly-2022-0054picqdscompositesdielectric propertiesmechanical properties
spellingShingle Zhang Yuyin
Guo Hongtao
Jiang Shaohua
Hu Zhaoyu
Zha Guojun
Liu Kunming
Hou Haoqing
Synthesis and properties of PI composite films using carbon quantum dots as fillers
e-Polymers
pi
cqds
composites
dielectric properties
mechanical properties
title Synthesis and properties of PI composite films using carbon quantum dots as fillers
title_full Synthesis and properties of PI composite films using carbon quantum dots as fillers
title_fullStr Synthesis and properties of PI composite films using carbon quantum dots as fillers
title_full_unstemmed Synthesis and properties of PI composite films using carbon quantum dots as fillers
title_short Synthesis and properties of PI composite films using carbon quantum dots as fillers
title_sort synthesis and properties of pi composite films using carbon quantum dots as fillers
topic pi
cqds
composites
dielectric properties
mechanical properties
url https://doi.org/10.1515/epoly-2022-0054
work_keys_str_mv AT zhangyuyin synthesisandpropertiesofpicompositefilmsusingcarbonquantumdotsasfillers
AT guohongtao synthesisandpropertiesofpicompositefilmsusingcarbonquantumdotsasfillers
AT jiangshaohua synthesisandpropertiesofpicompositefilmsusingcarbonquantumdotsasfillers
AT huzhaoyu synthesisandpropertiesofpicompositefilmsusingcarbonquantumdotsasfillers
AT zhaguojun synthesisandpropertiesofpicompositefilmsusingcarbonquantumdotsasfillers
AT liukunming synthesisandpropertiesofpicompositefilmsusingcarbonquantumdotsasfillers
AT houhaoqing synthesisandpropertiesofpicompositefilmsusingcarbonquantumdotsasfillers