Study on the effect of lithium nitrate in ionic conduction properties based alginate biopolymer electrolytes
In this present work, the conduction properties of biopolymer electrolytes (BEs) based alginate incorporation with LiNO _3 was studied. FTIR analysis showed there is complexation occurred when incorporation with LiNO _3 via COO ^− group of alginate. The interaction between alginate and LiNO _3 shown...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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IOP Publishing
2019-01-01
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| Series: | Materials Research Express |
| Subjects: | |
| Online Access: | https://doi.org/10.1088/2053-1591/ab57bb |
| _version_ | 1797747280373088256 |
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| author | A F Fuzlin N A Bakri B Sahraoui A S Samsudin |
| author_facet | A F Fuzlin N A Bakri B Sahraoui A S Samsudin |
| author_sort | A F Fuzlin |
| collection | DOAJ |
| description | In this present work, the conduction properties of biopolymer electrolytes (BEs) based alginate incorporation with LiNO _3 was studied. FTIR analysis showed there is complexation occurred when incorporation with LiNO _3 via COO ^− group of alginate. The interaction between alginate and LiNO _3 shown an improvement in ionic conductivity of BEs where was increased from 3.24 × 10 ^–7 S cm ^−1 for un-doped sample and achieved optimum value at 1.14 × 10 ^–4 S cm ^−1 for sample containing with 15 wt. % LiNO _3 . The prepared samples shown that it has thermally assisted when the temperature is increased and shown Arrhenius behavior. Deconvolution approached revealed that the present ionic conduction of BEs influenced by ionic mobility and diffusion coefficient. |
| first_indexed | 2024-03-12T15:48:29Z |
| format | Article |
| id | doaj.art-f9c072e630244b4598902971c79f98b0 |
| institution | Directory Open Access Journal |
| issn | 2053-1591 |
| language | English |
| last_indexed | 2024-03-12T15:48:29Z |
| publishDate | 2019-01-01 |
| publisher | IOP Publishing |
| record_format | Article |
| series | Materials Research Express |
| spelling | doaj.art-f9c072e630244b4598902971c79f98b02023-08-09T15:20:16ZengIOP PublishingMaterials Research Express2053-15912019-01-017101590210.1088/2053-1591/ab57bbStudy on the effect of lithium nitrate in ionic conduction properties based alginate biopolymer electrolytesA F Fuzlin0N A Bakri1B Sahraoui2A S Samsudin3https://orcid.org/0000-0001-7472-2530Ionic Materials Team, Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang , 26300 Pahang, MalaysiaIonic Materials Team, Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang , 26300 Pahang, MalaysiaUniversité d’Angers , CNRS UMR 6200, Laboratoire MOLTECH-Anjou, 2 bd Lavoisier, 49045 ANGERS cedex, FranceIonic Materials Team, Faculty of Industrial Sciences and Technology, Universiti Malaysia Pahang , 26300 Pahang, MalaysiaIn this present work, the conduction properties of biopolymer electrolytes (BEs) based alginate incorporation with LiNO _3 was studied. FTIR analysis showed there is complexation occurred when incorporation with LiNO _3 via COO ^− group of alginate. The interaction between alginate and LiNO _3 shown an improvement in ionic conductivity of BEs where was increased from 3.24 × 10 ^–7 S cm ^−1 for un-doped sample and achieved optimum value at 1.14 × 10 ^–4 S cm ^−1 for sample containing with 15 wt. % LiNO _3 . The prepared samples shown that it has thermally assisted when the temperature is increased and shown Arrhenius behavior. Deconvolution approached revealed that the present ionic conduction of BEs influenced by ionic mobility and diffusion coefficient.https://doi.org/10.1088/2053-1591/ab57bbpolymer electrolytesbiopolymerionic conductivitytransport properties |
| spellingShingle | A F Fuzlin N A Bakri B Sahraoui A S Samsudin Study on the effect of lithium nitrate in ionic conduction properties based alginate biopolymer electrolytes Materials Research Express polymer electrolytes biopolymer ionic conductivity transport properties |
| title | Study on the effect of lithium nitrate in ionic conduction properties based alginate biopolymer electrolytes |
| title_full | Study on the effect of lithium nitrate in ionic conduction properties based alginate biopolymer electrolytes |
| title_fullStr | Study on the effect of lithium nitrate in ionic conduction properties based alginate biopolymer electrolytes |
| title_full_unstemmed | Study on the effect of lithium nitrate in ionic conduction properties based alginate biopolymer electrolytes |
| title_short | Study on the effect of lithium nitrate in ionic conduction properties based alginate biopolymer electrolytes |
| title_sort | study on the effect of lithium nitrate in ionic conduction properties based alginate biopolymer electrolytes |
| topic | polymer electrolytes biopolymer ionic conductivity transport properties |
| url | https://doi.org/10.1088/2053-1591/ab57bb |
| work_keys_str_mv | AT affuzlin studyontheeffectoflithiumnitrateinionicconductionpropertiesbasedalginatebiopolymerelectrolytes AT nabakri studyontheeffectoflithiumnitrateinionicconductionpropertiesbasedalginatebiopolymerelectrolytes AT bsahraoui studyontheeffectoflithiumnitrateinionicconductionpropertiesbasedalginatebiopolymerelectrolytes AT assamsudin studyontheeffectoflithiumnitrateinionicconductionpropertiesbasedalginatebiopolymerelectrolytes |