Phosphine Functionalized Cp<sup>C</sup> Ligands and Their Metal Complexes
Simple nucleophilic aliphatic substitution gives access to mono- and diphosphine ligands with a Cp<sup>C</sup> group in the backbone. The monophosphine ligand coordinates to gold(I) via the phosphine site, to thallium(I) via the cyclopentadienyl site and to ruthenium(II) via a combinatio...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-04-01
|
| Series: | Chemistry |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2624-8549/5/2/62 |
| _version_ | 1797595566913355776 |
|---|---|
| author | Florian Nährig Yu Sun Werner R. Thiel |
| author_facet | Florian Nährig Yu Sun Werner R. Thiel |
| author_sort | Florian Nährig |
| collection | DOAJ |
| description | Simple nucleophilic aliphatic substitution gives access to mono- and diphosphine ligands with a Cp<sup>C</sup> group in the backbone. The monophosphine ligand coordinates to gold(I) via the phosphine site, to thallium(I) via the cyclopentadienyl site and to ruthenium(II) via a combination of both, resulting in an <i>ansa</i>-type structure. Coordination with the cyclopentadiene site is not possible for the diphosphine ligand. In this case, monodentate coordination to gold(I) and bidentate coordination to the [PdCl(μ<sup>2</sup>-Cl)]<sub>2</sub>, the [Rh(CO)(μ<sup>2</sup>-Cl)]<sub>2</sub>, and the Rh(CO)Cl fragment is observed, showing the variability in coordination modes possible for the long-chain diphosphine ligand. Ligands and complexes were characterized by means of NMR and IR spectroscopy, elemental analysis and X-ray structure analysis. |
| first_indexed | 2024-03-11T02:39:21Z |
| format | Article |
| id | doaj.art-f9c3c112b9924548a2627f02d4d61d99 |
| institution | Directory Open Access Journal |
| issn | 2624-8549 |
| language | English |
| last_indexed | 2024-03-11T02:39:21Z |
| publishDate | 2023-04-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Chemistry |
| spelling | doaj.art-f9c3c112b9924548a2627f02d4d61d992023-11-18T09:45:22ZengMDPI AGChemistry2624-85492023-04-015291293310.3390/chemistry5020062Phosphine Functionalized Cp<sup>C</sup> Ligands and Their Metal ComplexesFlorian Nährig0Yu Sun1Werner R. Thiel2Fachbereich Chemie, RPTU Kaiserslautern-Landau, Erwin-Schrödinger-Straße 54, 67663 Kaiserslautern, GermanyFachbereich Chemie, RPTU Kaiserslautern-Landau, Erwin-Schrödinger-Straße 54, 67663 Kaiserslautern, GermanyFachbereich Chemie, RPTU Kaiserslautern-Landau, Erwin-Schrödinger-Straße 54, 67663 Kaiserslautern, GermanySimple nucleophilic aliphatic substitution gives access to mono- and diphosphine ligands with a Cp<sup>C</sup> group in the backbone. The monophosphine ligand coordinates to gold(I) via the phosphine site, to thallium(I) via the cyclopentadienyl site and to ruthenium(II) via a combination of both, resulting in an <i>ansa</i>-type structure. Coordination with the cyclopentadiene site is not possible for the diphosphine ligand. In this case, monodentate coordination to gold(I) and bidentate coordination to the [PdCl(μ<sup>2</sup>-Cl)]<sub>2</sub>, the [Rh(CO)(μ<sup>2</sup>-Cl)]<sub>2</sub>, and the Rh(CO)Cl fragment is observed, showing the variability in coordination modes possible for the long-chain diphosphine ligand. Ligands and complexes were characterized by means of NMR and IR spectroscopy, elemental analysis and X-ray structure analysis.https://www.mdpi.com/2624-8549/5/2/62cyclopentadienyl ligandphosphine ligandrhodiumpalladiumgoldthallium |
| spellingShingle | Florian Nährig Yu Sun Werner R. Thiel Phosphine Functionalized Cp<sup>C</sup> Ligands and Their Metal Complexes Chemistry cyclopentadienyl ligand phosphine ligand rhodium palladium gold thallium |
| title | Phosphine Functionalized Cp<sup>C</sup> Ligands and Their Metal Complexes |
| title_full | Phosphine Functionalized Cp<sup>C</sup> Ligands and Their Metal Complexes |
| title_fullStr | Phosphine Functionalized Cp<sup>C</sup> Ligands and Their Metal Complexes |
| title_full_unstemmed | Phosphine Functionalized Cp<sup>C</sup> Ligands and Their Metal Complexes |
| title_short | Phosphine Functionalized Cp<sup>C</sup> Ligands and Their Metal Complexes |
| title_sort | phosphine functionalized cp sup c sup ligands and their metal complexes |
| topic | cyclopentadienyl ligand phosphine ligand rhodium palladium gold thallium |
| url | https://www.mdpi.com/2624-8549/5/2/62 |
| work_keys_str_mv | AT floriannahrig phosphinefunctionalizedcpsupcsupligandsandtheirmetalcomplexes AT yusun phosphinefunctionalizedcpsupcsupligandsandtheirmetalcomplexes AT wernerrthiel phosphinefunctionalizedcpsupcsupligandsandtheirmetalcomplexes |