Removal of Phosphorus from Wastewater by Different Morphological Alumina

In this work, an organic-free method was used to synthesize different morphological boehmite by controlling the crystallization temperature, and alumina adsorbents were obtained by baking the boehmites at 500 °C. The alumina adsorbents were characterized by X-ray diffraction (XRD), High resolution t...

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Main Authors: Jianchuan Sun, Awang Gao, Xuhui Wang, Xiangyu Xu, Jiaqing Song
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/25/13/3092
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author Jianchuan Sun
Awang Gao
Xuhui Wang
Xiangyu Xu
Jiaqing Song
author_facet Jianchuan Sun
Awang Gao
Xuhui Wang
Xiangyu Xu
Jiaqing Song
author_sort Jianchuan Sun
collection DOAJ
description In this work, an organic-free method was used to synthesize different morphological boehmite by controlling the crystallization temperature, and alumina adsorbents were obtained by baking the boehmites at 500 °C. The alumina adsorbents were characterized by X-ray diffraction (XRD), High resolution transmission electron microscope (HRTEM), Fourier transform infrared (FT-IR), N<sub>2</sub> adsorption/desorption analysis, and their phosphorus adsorption properties were comparatively investigated by a series of experiments. The results showed that the self-prepared alumina adsorbents were lamellar and fibrous material, while the industrial adsorbent was a granular material. The lamellar alumina adsorbents had the largest specific surface area and showed better phosphorus adsorption capacity. The maximum adsorption capacity could reach up to 588.2 mg·g<sup>−1</sup>; and only 0.8 g·L<sup>−1</sup> of lamellar alumina adsorbent is needed to treat 100 mg·L<sup>−1</sup> phosphorus solution under the Chinese level 1 discharge standard (0.5 mg·L<sup>−1</sup>). Further investigation suggests that the lamellar alumina adsorbent kept high adsorption capacity in various solution environments.
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spelling doaj.art-f9c5c9f2a7654a80a72b70ef1128b1ef2023-11-20T06:04:34ZengMDPI AGMolecules1420-30492020-07-012513309210.3390/molecules25133092Removal of Phosphorus from Wastewater by Different Morphological AluminaJianchuan Sun0Awang Gao1Xuhui Wang2Xiangyu Xu3Jiaqing Song4College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, ChinaCollege of Chemistry, Beijing University of Chemical Technology, Beijing 100029, ChinaCollege of Chemistry, Beijing University of Chemical Technology, Beijing 100029, ChinaCollege of Chemistry, Beijing University of Chemical Technology, Beijing 100029, ChinaCollege of Chemistry, Beijing University of Chemical Technology, Beijing 100029, ChinaIn this work, an organic-free method was used to synthesize different morphological boehmite by controlling the crystallization temperature, and alumina adsorbents were obtained by baking the boehmites at 500 °C. The alumina adsorbents were characterized by X-ray diffraction (XRD), High resolution transmission electron microscope (HRTEM), Fourier transform infrared (FT-IR), N<sub>2</sub> adsorption/desorption analysis, and their phosphorus adsorption properties were comparatively investigated by a series of experiments. The results showed that the self-prepared alumina adsorbents were lamellar and fibrous material, while the industrial adsorbent was a granular material. The lamellar alumina adsorbents had the largest specific surface area and showed better phosphorus adsorption capacity. The maximum adsorption capacity could reach up to 588.2 mg·g<sup>−1</sup>; and only 0.8 g·L<sup>−1</sup> of lamellar alumina adsorbent is needed to treat 100 mg·L<sup>−1</sup> phosphorus solution under the Chinese level 1 discharge standard (0.5 mg·L<sup>−1</sup>). Further investigation suggests that the lamellar alumina adsorbent kept high adsorption capacity in various solution environments.https://www.mdpi.com/1420-3049/25/13/3092adsorptionaluminaphosphorushigh surface areamorphology
spellingShingle Jianchuan Sun
Awang Gao
Xuhui Wang
Xiangyu Xu
Jiaqing Song
Removal of Phosphorus from Wastewater by Different Morphological Alumina
Molecules
adsorption
alumina
phosphorus
high surface area
morphology
title Removal of Phosphorus from Wastewater by Different Morphological Alumina
title_full Removal of Phosphorus from Wastewater by Different Morphological Alumina
title_fullStr Removal of Phosphorus from Wastewater by Different Morphological Alumina
title_full_unstemmed Removal of Phosphorus from Wastewater by Different Morphological Alumina
title_short Removal of Phosphorus from Wastewater by Different Morphological Alumina
title_sort removal of phosphorus from wastewater by different morphological alumina
topic adsorption
alumina
phosphorus
high surface area
morphology
url https://www.mdpi.com/1420-3049/25/13/3092
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AT xuhuiwang removalofphosphorusfromwastewaterbydifferentmorphologicalalumina
AT xiangyuxu removalofphosphorusfromwastewaterbydifferentmorphologicalalumina
AT jiaqingsong removalofphosphorusfromwastewaterbydifferentmorphologicalalumina