The Kinetic Simulation of Persulfate Activation by Nano-Ferrosoferric Oxide

Nano-ferrosoferric-oxide (nFe<sub>3</sub>O<sub>4</sub>)-activated persulfate (PS) technology was used to remove pollutant bisphenol A (BPA) in water. The effects of nFe<sub>3</sub>O<sub>4</sub> concentration, PS concentration, BPA concentration, temper...

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Bibliographic Details
Main Authors: Tiehong Song, Yanjiao Gao, Guanqiao Li, Yaxin Chen, Qiang Li
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/12/11/1353
Description
Summary:Nano-ferrosoferric-oxide (nFe<sub>3</sub>O<sub>4</sub>)-activated persulfate (PS) technology was used to remove pollutant bisphenol A (BPA) in water. The effects of nFe<sub>3</sub>O<sub>4</sub> concentration, PS concentration, BPA concentration, temperature, and pH were investigated in terms of the degradation effect of BPA. The results showed that more PS dosage and lower BPA concentration could improve the degradation rate of BPA. When other conditions were constant, the degradation rate of BPA increased with the increase of temperature. When pH was 5, the degradation rate of BPA was the highest. When the initial PS concentration and pH were changed, the degradation rate of BPA was consistent with the pseudo-secondary kinetic model. Under other conditions, the degradation rate of BPA was consistent with the pseudo-first-order kinetic model. Sulfate radical (SO<sub>4</sub><sup>•−</sup>) produced by nFe<sub>3</sub>O<sub>4</sub>/PS system was mainly responsible for the degradation of BPA.
ISSN:2073-4344