Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis(diphenylphosphinothioyl)ethane-κ2S:S′] dibromidoaurate(I)]

Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis(diphenylphosphinothioyl)ethane-κ2S:S′] dibromidoaurate(I)]

In the title compound, {[Au(C26H24P2S2)][AuBr2]}n, the gold(I) centres of the cation are coordinated by the P=S groups of the disulfide ligands to form a chain polymer parallel to the c axis. Both independent gold atoms lie on the same twofold axis, and the midpoint of the H2C—CH2 bond lies on an in...

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Bibliographic Details
Main Authors:	Christina Taouss, Marina Calvo, Peter G. Jones
Format:	Article
Language:	English
Published:	International Union of Crystallography 2020-11-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure polymer phosphine sulfide gold
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989020013675

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