3-Hydroxy-4-phenyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one: cis isomer
In the title compound, C15H14N2O2, the seven-membered benzodiazepine ring adopts a twist-boat conformation and the two aromatic rings are inclined to one another by 81.06 (15)°. In the crystal, molecules are linked by N—H...O hydrogen bonds, forming chains propagating along the [10-1] direction. The...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-11-01
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616018794 |
| _version_ | 1818066821196021760 |
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| author | Mohammed Rida Youness El Bakri Mohamadou Lamine Doumbia Mohammed Benchidmi El Mokhtar Essassi Joel T Mague |
| author_facet | Mohammed Rida Youness El Bakri Mohamadou Lamine Doumbia Mohammed Benchidmi El Mokhtar Essassi Joel T Mague |
| author_sort | Mohammed Rida |
| collection | DOAJ |
| description | In the title compound, C15H14N2O2, the seven-membered benzodiazepine ring adopts a twist-boat conformation and the two aromatic rings are inclined to one another by 81.06 (15)°. In the crystal, molecules are linked by N—H...O hydrogen bonds, forming chains propagating along the [10-1] direction. The chains are linked by C—H...O hydrogen bonds, forming sheets parallel to the ac plane. Within the sheets, there are N—H...π interactions present, and C—H...π interactions link the sheets to form a three-dimensional structure. |
| first_indexed | 2024-12-10T15:13:52Z |
| format | Article |
| id | doaj.art-fa214767d68143fc9d74e872e227c2dc |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-10T15:13:52Z |
| publishDate | 2016-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-fa214767d68143fc9d74e872e227c2dc2022-12-22T01:43:52ZengInternational Union of CrystallographyIUCrData2414-31462016-11-01111x16187910.1107/S2414314616018794su40963-Hydroxy-4-phenyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one: cis isomerMohammed Rida0Youness El Bakri1Mohamadou Lamine Doumbia2Mohammed Benchidmi3El Mokhtar Essassi4Joel T Mague5Laboratoire de Chimie Organique Hétérocyclique, URAC 21, Pôle de Compétence Pharmacochimie, Av Ibn Battouta, BP 1014, Faculté des Sciences, Mohammed V University, Rabat, MoroccoLaboratoire de Chimie Organique Hétérocyclique, URAC 21, Pôle de Compétence Pharmacochimie, Av Ibn Battouta, BP 1014, Faculté des Sciences, Mohammed V University, Rabat, MoroccoUFR-Environnement, UNIV Jean Lorougnon Guédé, BP 150, Daloa, Ivory CoastLaboratoire de Chimie Organique Hétérocyclique, URAC 21, Pôle de Compétence Pharmacochimie, Av Ibn Battouta, BP 1014, Faculté des Sciences, Mohammed V University, Rabat, MoroccoLaboratoire de Chimie Organique Hétérocyclique, URAC 21, Pôle de Compétence Pharmacochimie, Av Ibn Battouta, BP 1014, Faculté des Sciences, Mohammed V University, Rabat, MoroccoDepartment of Chemistry, Tulane University, New Orleans, LA 70118, USAIn the title compound, C15H14N2O2, the seven-membered benzodiazepine ring adopts a twist-boat conformation and the two aromatic rings are inclined to one another by 81.06 (15)°. In the crystal, molecules are linked by N—H...O hydrogen bonds, forming chains propagating along the [10-1] direction. The chains are linked by C—H...O hydrogen bonds, forming sheets parallel to the ac plane. Within the sheets, there are N—H...π interactions present, and C—H...π interactions link the sheets to form a three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S2414314616018794crystal structurebenzodiazepinecis isomerhydrogen bondingN—H...π interactionsC—H...π interactions |
| spellingShingle | Mohammed Rida Youness El Bakri Mohamadou Lamine Doumbia Mohammed Benchidmi El Mokhtar Essassi Joel T Mague 3-Hydroxy-4-phenyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one: cis isomer IUCrData crystal structure benzodiazepine cis isomer hydrogen bonding N—H...π interactions C—H...π interactions |
| title | 3-Hydroxy-4-phenyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one: cis isomer |
| title_full | 3-Hydroxy-4-phenyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one: cis isomer |
| title_fullStr | 3-Hydroxy-4-phenyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one: cis isomer |
| title_full_unstemmed | 3-Hydroxy-4-phenyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one: cis isomer |
| title_short | 3-Hydroxy-4-phenyl-2,3,4,5-tetrahydro-1H-1,5-benzodiazepin-2-one: cis isomer |
| title_sort | 3 hydroxy 4 phenyl 2 3 4 5 tetrahydro 1h 1 5 benzodiazepin 2 one cis isomer |
| topic | crystal structure benzodiazepine cis isomer hydrogen bonding N—H...π interactions C—H...π interactions |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616018794 |
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