Influence of Functional Bio-Based Coatings Including Chitin Nanofibrils or Polyphenols on Mechanical Properties of Paper Tissues

The paper tissue industry is a constantly evolving sector that supplies markets that require products with different specific properties. In order to meet the demand of functional properties, ensuring a green approach at the same time, research on bio-coatings has been very active in recent decades....

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Main Authors: Luca Panariello, Maria-Beatrice Coltelli, Simone Giangrandi, María Carmen Garrigós, Ahdi Hadrich, Andrea Lazzeri, Patrizia Cinelli
Format: Article
Language:English
Published: MDPI AG 2022-06-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/11/2274
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author Luca Panariello
Maria-Beatrice Coltelli
Simone Giangrandi
María Carmen Garrigós
Ahdi Hadrich
Andrea Lazzeri
Patrizia Cinelli
author_facet Luca Panariello
Maria-Beatrice Coltelli
Simone Giangrandi
María Carmen Garrigós
Ahdi Hadrich
Andrea Lazzeri
Patrizia Cinelli
author_sort Luca Panariello
collection DOAJ
description The paper tissue industry is a constantly evolving sector that supplies markets that require products with different specific properties. In order to meet the demand of functional properties, ensuring a green approach at the same time, research on bio-coatings has been very active in recent decades. The attention dedicated to research on functional properties has not been given to the study of the morphological and mechanical properties of the final products. This paper studied the effect of two representative bio-based coatings on paper tissue. Coatings based on chitin nanofibrils or polyphenols were sprayed on paper tissues to provide them, respectively, with antibacterial and antioxidant activity. The chemical structure of the obtained samples was preliminarily compared by ATR-FTIR before and after their application. Coatings were applied on paper tissues and, after drying, their homogeneity was investigated by ATR-FTIR on different surface areas. Antimicrobial and antioxidant properties were found for chitin nanofibrils- and polyphenols-treated paper tissues, respectively. The mechanical properties of treated and untreated paper tissues were studied, considering as a reference the same tissue paper sample treated only with water. Different mechanical tests were performed on tissues, including penetration, tensile, and tearing tests in two perpendicular directions, to consider the anisotropy of the produced tissues for industrial applications. The morphology of uncoated and coated paper tissues was analysed by field emission scanning electron microscopy. Results from mechanical properties evidenced a correlation between morphological and mechanical changes. The addition of polyphenols resulted in a reduction in mechanical resistance, while the addition of chitin enhanced this property. This study evidenced the different effects produced by two novel coatings on paper tissues for personal care in terms of properties and structure.
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spelling doaj.art-fa24154e9a9b4b68bf2fb88ba49a6c9b2023-11-23T14:42:22ZengMDPI AGPolymers2073-43602022-06-011411227410.3390/polym14112274Influence of Functional Bio-Based Coatings Including Chitin Nanofibrils or Polyphenols on Mechanical Properties of Paper TissuesLuca Panariello0Maria-Beatrice Coltelli1Simone Giangrandi2María Carmen Garrigós3Ahdi Hadrich4Andrea Lazzeri5Patrizia Cinelli6National Interuniversity Consortium of Materials Science and Technology (INSTM), 50121 Firenze, ItalyNational Interuniversity Consortium of Materials Science and Technology (INSTM), 50121 Firenze, ItalyLUCENSE SCaRL, 55100 Lucca, ItalyDepartment of Analytical Chemistry, Nutrition and Food Sciences, University of Alicante, 03080 Alicante, SpainBiomass Valorization Platform-Materials, CELABOR s.c.r.l., 4650 Chaineux, BelgiumNational Interuniversity Consortium of Materials Science and Technology (INSTM), 50121 Firenze, ItalyNational Interuniversity Consortium of Materials Science and Technology (INSTM), 50121 Firenze, ItalyThe paper tissue industry is a constantly evolving sector that supplies markets that require products with different specific properties. In order to meet the demand of functional properties, ensuring a green approach at the same time, research on bio-coatings has been very active in recent decades. The attention dedicated to research on functional properties has not been given to the study of the morphological and mechanical properties of the final products. This paper studied the effect of two representative bio-based coatings on paper tissue. Coatings based on chitin nanofibrils or polyphenols were sprayed on paper tissues to provide them, respectively, with antibacterial and antioxidant activity. The chemical structure of the obtained samples was preliminarily compared by ATR-FTIR before and after their application. Coatings were applied on paper tissues and, after drying, their homogeneity was investigated by ATR-FTIR on different surface areas. Antimicrobial and antioxidant properties were found for chitin nanofibrils- and polyphenols-treated paper tissues, respectively. The mechanical properties of treated and untreated paper tissues were studied, considering as a reference the same tissue paper sample treated only with water. Different mechanical tests were performed on tissues, including penetration, tensile, and tearing tests in two perpendicular directions, to consider the anisotropy of the produced tissues for industrial applications. The morphology of uncoated and coated paper tissues was analysed by field emission scanning electron microscopy. Results from mechanical properties evidenced a correlation between morphological and mechanical changes. The addition of polyphenols resulted in a reduction in mechanical resistance, while the addition of chitin enhanced this property. This study evidenced the different effects produced by two novel coatings on paper tissues for personal care in terms of properties and structure.https://www.mdpi.com/2073-4360/14/11/2274chitin nanofibrilspolyphenolspaper tissuesmechanical propertiesbio-based coatings
spellingShingle Luca Panariello
Maria-Beatrice Coltelli
Simone Giangrandi
María Carmen Garrigós
Ahdi Hadrich
Andrea Lazzeri
Patrizia Cinelli
Influence of Functional Bio-Based Coatings Including Chitin Nanofibrils or Polyphenols on Mechanical Properties of Paper Tissues
Polymers
chitin nanofibrils
polyphenols
paper tissues
mechanical properties
bio-based coatings
title Influence of Functional Bio-Based Coatings Including Chitin Nanofibrils or Polyphenols on Mechanical Properties of Paper Tissues
title_full Influence of Functional Bio-Based Coatings Including Chitin Nanofibrils or Polyphenols on Mechanical Properties of Paper Tissues
title_fullStr Influence of Functional Bio-Based Coatings Including Chitin Nanofibrils or Polyphenols on Mechanical Properties of Paper Tissues
title_full_unstemmed Influence of Functional Bio-Based Coatings Including Chitin Nanofibrils or Polyphenols on Mechanical Properties of Paper Tissues
title_short Influence of Functional Bio-Based Coatings Including Chitin Nanofibrils or Polyphenols on Mechanical Properties of Paper Tissues
title_sort influence of functional bio based coatings including chitin nanofibrils or polyphenols on mechanical properties of paper tissues
topic chitin nanofibrils
polyphenols
paper tissues
mechanical properties
bio-based coatings
url https://www.mdpi.com/2073-4360/14/11/2274
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