STRUCTURAL DISTORTIONS OF COORDINATED KETENE MOLECULE INDUCED BY THE PSEUDO JAHN-TELLER EFFECT
It is demonstrated that the only reason of structural distortions of ketene molecule coordinated in the complexes VCp2-H2C2O (I) and Pt(PPh3)2-H2C2O (II) is the pseudo Jahn-Teller effect (PJTE) induced by the orbital charge transfers (OCTs) by coordination. It is shown that the η2 -(C-O) coordinatio...
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| Format: | Article |
| Language: | English |
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Academy of Sciences of Moldova, Institute of Chemistry
2016-12-01
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| Series: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry |
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| Online Access: | http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201611(2)_99-104_Gorinchoy.pdf |