Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes

Achieving the fast oxygen reduction reaction (ORR) kinetics at the cathode of solid oxide fuel cells (SOFCs) is indispensable to enhance the efficiency of SOFCs at intermediate temperatures. Mixed ionic and electronic conducting (MIEC) oxides such as ABO3 perovskites and Ruddlesden-Popper (RP) oxide...

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Main Authors: Gene Yang, Wonsang Jung, Sung-Jin Ahn, Dongkyu Lee
Format: Article
Language:English
Published: MDPI AG 2019-03-01
Series:Applied Sciences
Subjects:
Online Access:http://www.mdpi.com/2076-3417/9/5/1030
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author Gene Yang
Wonsang Jung
Sung-Jin Ahn
Dongkyu Lee
author_facet Gene Yang
Wonsang Jung
Sung-Jin Ahn
Dongkyu Lee
author_sort Gene Yang
collection DOAJ
description Achieving the fast oxygen reduction reaction (ORR) kinetics at the cathode of solid oxide fuel cells (SOFCs) is indispensable to enhance the efficiency of SOFCs at intermediate temperatures. Mixed ionic and electronic conducting (MIEC) oxides such as ABO3 perovskites and Ruddlesden-Popper (RP) oxides (A2BO4) have been widely used as promising cathode materials owing to their attractive physicochemical properties. In particular, oxides in forms of thin films and heterostructures have enabled significant enhancement in the ORR activity. Therefore, we aim to give a comprehensive overview on the recent development of thin film cathodes of SOFCs. We discuss important advances in ABO3 and RP oxide thin film cathodes for SOFCs. Our attention is also paid to the influence of oxide heterostructure interfaces on the ORR activity of SOFC cathodes.
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spelling doaj.art-fa850e1a402649608803d0328e059efc2022-12-21T17:51:06ZengMDPI AGApplied Sciences2076-34172019-03-0195103010.3390/app9051030app9051030Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell CathodesGene Yang0Wonsang Jung1Sung-Jin Ahn2Dongkyu Lee3Department of Mechanical Engineering, University of South Carolina, SC 29208, USADepartment of Mechanical Engineering, University of South Carolina, SC 29208, USAEnergy Lab, Samsung Advanced Institute of Technology, Suwon, Gyeonggi-do 16678, KoreaDepartment of Mechanical Engineering, University of South Carolina, SC 29208, USAAchieving the fast oxygen reduction reaction (ORR) kinetics at the cathode of solid oxide fuel cells (SOFCs) is indispensable to enhance the efficiency of SOFCs at intermediate temperatures. Mixed ionic and electronic conducting (MIEC) oxides such as ABO3 perovskites and Ruddlesden-Popper (RP) oxides (A2BO4) have been widely used as promising cathode materials owing to their attractive physicochemical properties. In particular, oxides in forms of thin films and heterostructures have enabled significant enhancement in the ORR activity. Therefore, we aim to give a comprehensive overview on the recent development of thin film cathodes of SOFCs. We discuss important advances in ABO3 and RP oxide thin film cathodes for SOFCs. Our attention is also paid to the influence of oxide heterostructure interfaces on the ORR activity of SOFC cathodes.http://www.mdpi.com/2076-3417/9/5/1030Solid oxide fuel cellsCathodesOxygen reductions reactionOxygen surface exchange kineticsOxide thin filmsABO3 oxidesRuddlesden-Popper oxidesHeterostructure oxide thin filmsStrain engineeringOxide interfaces
spellingShingle Gene Yang
Wonsang Jung
Sung-Jin Ahn
Dongkyu Lee
Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes
Applied Sciences
Solid oxide fuel cells
Cathodes
Oxygen reductions reaction
Oxygen surface exchange kinetics
Oxide thin films
ABO3 oxides
Ruddlesden-Popper oxides
Heterostructure oxide thin films
Strain engineering
Oxide interfaces
title Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes
title_full Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes
title_fullStr Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes
title_full_unstemmed Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes
title_short Controlling the Oxygen Electrocatalysis on Perovskite and Layered Oxide Thin Films for Solid Oxide Fuel Cell Cathodes
title_sort controlling the oxygen electrocatalysis on perovskite and layered oxide thin films for solid oxide fuel cell cathodes
topic Solid oxide fuel cells
Cathodes
Oxygen reductions reaction
Oxygen surface exchange kinetics
Oxide thin films
ABO3 oxides
Ruddlesden-Popper oxides
Heterostructure oxide thin films
Strain engineering
Oxide interfaces
url http://www.mdpi.com/2076-3417/9/5/1030
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AT sungjinahn controllingtheoxygenelectrocatalysisonperovskiteandlayeredoxidethinfilmsforsolidoxidefuelcellcathodes
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