Removal of chromium (VI) from aqueous solution using vesicular basalt: A potential low cost wastewater treatment system

In this study, vesicular basalt volcanic rock was taken and its application for adsorption of chromium (VI) from aqueous solution was investigated. Different physical and chemical properties of the powdered rock was studied using Fourier transform infrared spectroscopy (FT-IR), Powder X-ray diffract...

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Main Authors: Agegnehu Alemu, Brook Lemma, Nigus Gabbiye, Melisew Tadele Alula, Minyahl Teferi Desta
Format: Article
Language:English
Published: Elsevier 2018-07-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844017339130
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author Agegnehu Alemu
Brook Lemma
Nigus Gabbiye
Melisew Tadele Alula
Minyahl Teferi Desta
author_facet Agegnehu Alemu
Brook Lemma
Nigus Gabbiye
Melisew Tadele Alula
Minyahl Teferi Desta
author_sort Agegnehu Alemu
collection DOAJ
description In this study, vesicular basalt volcanic rock was taken and its application for adsorption of chromium (VI) from aqueous solution was investigated. Different physical and chemical properties of the powdered rock was studied using Fourier transform infrared spectroscopy (FT-IR), Powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). A series of batch experiments were carried out to study the effect of various experimental parameters (pH, ionic strength and contact time) on chromium (VI) adsorption. It was found that the removal efficiency of chromium (VI) decreased with increasing pH and ionic strength. The adsorption process was optimal at pH 2. The maximum adsorption capacity was 79.20 mg kg−1 at an initial concentration of 5.0 mg L−1 and adsorbent dosage of 50 g L−1. In individual adsorption tests, Pseudo-second-order kinetic and Freundlich isotherm models could better describe chromium (VI) adsorption on the vesicular basalt. This study indicated that vesicular basalt, which is inexpensive, has the potential to remove chromium (VI) from polluted water.
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spelling doaj.art-fa8646755afa4672a4a610209a73f1fe2022-12-22T00:33:46ZengElsevierHeliyon2405-84402018-07-0147e00682Removal of chromium (VI) from aqueous solution using vesicular basalt: A potential low cost wastewater treatment systemAgegnehu Alemu0Brook Lemma1Nigus Gabbiye2Melisew Tadele Alula3Minyahl Teferi Desta4Ethiopian Institute of Water Resources, Addis Ababa University, P.O Box 1176, Addis Ababa, Ethiopia; College of Science, Bahir Dar University, P.O Box 79, Bahir Dar, Ethiopia; Corresponding author.College of Natural and Computational Science, Addis Ababa University, P.O Box 1176, Addis Ababa, EthiopiaFaculty of Chemical and Food Engineering, Bahir Dar University, P.O. Box 26, Bahir Dar, EthiopiaBotswana International University of Science and Technology, Private Bag 16, BotswanaSchool of Earth Science, Bahir Dar University, P.O Box 79, Bahir Dar, EthiopiaIn this study, vesicular basalt volcanic rock was taken and its application for adsorption of chromium (VI) from aqueous solution was investigated. Different physical and chemical properties of the powdered rock was studied using Fourier transform infrared spectroscopy (FT-IR), Powder X-ray diffraction (XRD) and scanning electron microscopy (SEM). A series of batch experiments were carried out to study the effect of various experimental parameters (pH, ionic strength and contact time) on chromium (VI) adsorption. It was found that the removal efficiency of chromium (VI) decreased with increasing pH and ionic strength. The adsorption process was optimal at pH 2. The maximum adsorption capacity was 79.20 mg kg−1 at an initial concentration of 5.0 mg L−1 and adsorbent dosage of 50 g L−1. In individual adsorption tests, Pseudo-second-order kinetic and Freundlich isotherm models could better describe chromium (VI) adsorption on the vesicular basalt. This study indicated that vesicular basalt, which is inexpensive, has the potential to remove chromium (VI) from polluted water.http://www.sciencedirect.com/science/article/pii/S2405844017339130Environmental science
spellingShingle Agegnehu Alemu
Brook Lemma
Nigus Gabbiye
Melisew Tadele Alula
Minyahl Teferi Desta
Removal of chromium (VI) from aqueous solution using vesicular basalt: A potential low cost wastewater treatment system
Heliyon
Environmental science
title Removal of chromium (VI) from aqueous solution using vesicular basalt: A potential low cost wastewater treatment system
title_full Removal of chromium (VI) from aqueous solution using vesicular basalt: A potential low cost wastewater treatment system
title_fullStr Removal of chromium (VI) from aqueous solution using vesicular basalt: A potential low cost wastewater treatment system
title_full_unstemmed Removal of chromium (VI) from aqueous solution using vesicular basalt: A potential low cost wastewater treatment system
title_short Removal of chromium (VI) from aqueous solution using vesicular basalt: A potential low cost wastewater treatment system
title_sort removal of chromium vi from aqueous solution using vesicular basalt a potential low cost wastewater treatment system
topic Environmental science
url http://www.sciencedirect.com/science/article/pii/S2405844017339130
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AT brooklemma removalofchromiumvifromaqueoussolutionusingvesicularbasaltapotentiallowcostwastewatertreatmentsystem
AT nigusgabbiye removalofchromiumvifromaqueoussolutionusingvesicularbasaltapotentiallowcostwastewatertreatmentsystem
AT melisewtadelealula removalofchromiumvifromaqueoussolutionusingvesicularbasaltapotentiallowcostwastewatertreatmentsystem
AT minyahlteferidesta removalofchromiumvifromaqueoussolutionusingvesicularbasaltapotentiallowcostwastewatertreatmentsystem