Ultra-sensitive ppb-level methane detection based on NIR all-optical photoacoustic spectroscopy by using differential fiber-optic microphones with gold-chromium composite nanomembrane

In this paper, we propose and experimentally demonstrate an ultra-sensitive all-optical PAS gas sensor, incorporating with a near-infrared (NIR) diode laser, fiber-optic microphones (FOMs) and a double channel differential T-type photoacoustic cell. The FOM is realized by Fabry-Perot interferometry...

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Main Authors: Hanping Xiao, Jinbiao Zhao, Chaotan Sima, Ping Lu, Yanhong Long, Yan Ai, Wanjin Zhang, Yufeng Pan, Jiangshan Zhang, Deming Liu
Format: Article
Language:English
Published: Elsevier 2022-06-01
Series:Photoacoustics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2213597922000222
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author Hanping Xiao
Jinbiao Zhao
Chaotan Sima
Ping Lu
Yanhong Long
Yan Ai
Wanjin Zhang
Yufeng Pan
Jiangshan Zhang
Deming Liu
author_facet Hanping Xiao
Jinbiao Zhao
Chaotan Sima
Ping Lu
Yanhong Long
Yan Ai
Wanjin Zhang
Yufeng Pan
Jiangshan Zhang
Deming Liu
author_sort Hanping Xiao
collection DOAJ
description In this paper, we propose and experimentally demonstrate an ultra-sensitive all-optical PAS gas sensor, incorporating with a near-infrared (NIR) diode laser, fiber-optic microphones (FOMs) and a double channel differential T-type photoacoustic cell. The FOM is realized by Fabry-Perot interferometry and novel gold-chromium (Au-Cr) composite nanomembranes. To meet the demand of high sensitivity and flat frequency response for the FOMs, the Au-Cr composite diaphragm is deliberately designed and fabricated by E-beam evaporation deposition with 330 nm in thickness and 6.35 mm in radius. Experimental results show that the FOM has a sensitivity of about 30 V/Pa and a flat frequency response from 300 to 900 Hz with fluctuation below 1 dB. Moreover, a double channel differential T-type photoacoustic cell is designed and employed in the all-optical PAS gas sensor, with the first-order resonant frequency of 610 Hz. The all-optical gas sensor is established and verified for CH4 detection and the normalized noise equivalent absorption (NNEA) is 4.42 × 10−10 W∙cm−1∙Hz−1/2. The minimum detection limit (MDL) of 36.45 ppb is achieved with a 1 s integration time. The MDL could be further enhanced to 4.87 ppb with an integration time of 81 s, allowing ultra-sensitive trace gas detection.
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spelling doaj.art-fa8c6924cafd4567a891d12c77e0ba802022-12-22T02:11:07ZengElsevierPhotoacoustics2213-59792022-06-0126100353Ultra-sensitive ppb-level methane detection based on NIR all-optical photoacoustic spectroscopy by using differential fiber-optic microphones with gold-chromium composite nanomembraneHanping Xiao0Jinbiao Zhao1Chaotan Sima2Ping Lu3Yanhong Long4Yan Ai5Wanjin Zhang6Yufeng Pan7Jiangshan Zhang8Deming Liu9Wuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China; Shenzhen Huazhong University of Science and Technology Research Institute, Shenzhen 518000, ChinaWuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China; Shenzhen Huazhong University of Science and Technology Research Institute, Shenzhen 518000, ChinaWuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China; Shenzhen Huazhong University of Science and Technology Research Institute, Shenzhen 518000, China; Corresponding authors at: Wuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, ChinaWuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China; Shenzhen Huazhong University of Science and Technology Research Institute, Shenzhen 518000, China; Corresponding authors at: Wuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, ChinaWuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, ChinaWuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, ChinaWuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, ChinaWuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, ChinaDepartment of Electronics and Information Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaWuhan National Laboratory for Optoelectronics (WNLO) and National Engineering Laboratory for Next Generation Internet Access System, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, ChinaIn this paper, we propose and experimentally demonstrate an ultra-sensitive all-optical PAS gas sensor, incorporating with a near-infrared (NIR) diode laser, fiber-optic microphones (FOMs) and a double channel differential T-type photoacoustic cell. The FOM is realized by Fabry-Perot interferometry and novel gold-chromium (Au-Cr) composite nanomembranes. To meet the demand of high sensitivity and flat frequency response for the FOMs, the Au-Cr composite diaphragm is deliberately designed and fabricated by E-beam evaporation deposition with 330 nm in thickness and 6.35 mm in radius. Experimental results show that the FOM has a sensitivity of about 30 V/Pa and a flat frequency response from 300 to 900 Hz with fluctuation below 1 dB. Moreover, a double channel differential T-type photoacoustic cell is designed and employed in the all-optical PAS gas sensor, with the first-order resonant frequency of 610 Hz. The all-optical gas sensor is established and verified for CH4 detection and the normalized noise equivalent absorption (NNEA) is 4.42 × 10−10 W∙cm−1∙Hz−1/2. The minimum detection limit (MDL) of 36.45 ppb is achieved with a 1 s integration time. The MDL could be further enhanced to 4.87 ppb with an integration time of 81 s, allowing ultra-sensitive trace gas detection.http://www.sciencedirect.com/science/article/pii/S2213597922000222InfraredPhotoacoustic spectroscopyFiber-optic microphoneGas detection
spellingShingle Hanping Xiao
Jinbiao Zhao
Chaotan Sima
Ping Lu
Yanhong Long
Yan Ai
Wanjin Zhang
Yufeng Pan
Jiangshan Zhang
Deming Liu
Ultra-sensitive ppb-level methane detection based on NIR all-optical photoacoustic spectroscopy by using differential fiber-optic microphones with gold-chromium composite nanomembrane
Photoacoustics
Infrared
Photoacoustic spectroscopy
Fiber-optic microphone
Gas detection
title Ultra-sensitive ppb-level methane detection based on NIR all-optical photoacoustic spectroscopy by using differential fiber-optic microphones with gold-chromium composite nanomembrane
title_full Ultra-sensitive ppb-level methane detection based on NIR all-optical photoacoustic spectroscopy by using differential fiber-optic microphones with gold-chromium composite nanomembrane
title_fullStr Ultra-sensitive ppb-level methane detection based on NIR all-optical photoacoustic spectroscopy by using differential fiber-optic microphones with gold-chromium composite nanomembrane
title_full_unstemmed Ultra-sensitive ppb-level methane detection based on NIR all-optical photoacoustic spectroscopy by using differential fiber-optic microphones with gold-chromium composite nanomembrane
title_short Ultra-sensitive ppb-level methane detection based on NIR all-optical photoacoustic spectroscopy by using differential fiber-optic microphones with gold-chromium composite nanomembrane
title_sort ultra sensitive ppb level methane detection based on nir all optical photoacoustic spectroscopy by using differential fiber optic microphones with gold chromium composite nanomembrane
topic Infrared
Photoacoustic spectroscopy
Fiber-optic microphone
Gas detection
url http://www.sciencedirect.com/science/article/pii/S2213597922000222
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