Highly Efficient Kinetic Resolution of Aryl-Alkenyl Alcohols by Ru-Catalyzed Hydrogen Transfer

Highly Efficient Kinetic Resolution of Aryl-Alkenyl Alcohols by Ru-Catalyzed Hydrogen Transfer

No matter through asymmetric reduction of ketones or kinetic resolution of secondary alcohols, enantioselective synthesis of the corresponding secondary alcohols is challenging when the two groups attached to the prochiral or chiral centers are spatially or electronically similar. For examples, dial...

Full description

Bibliographic Details
Main Authors:	Yipeng You, Ming Yu Jin, Guanyu Tao, Xiangyou Xing
Format:	Article
Language:	English
Published:	MDPI AG 2021-12-01
Series:	Molecules
Subjects:	asymmetric transfer hydrogenation kinetic resolution aryl-alkenyl alcohols selectivity factor Ru-catalyst
Online Access:	https://www.mdpi.com/1420-3049/26/24/7475

Similar Items

Aryl acrylonitriles synthesis enabled by palladium-catalyzed α-alkenylation of arylacetonitriles with vinyl halides/triflates
by: Yonggang Jiang, et al.
Published: (2022-12-01)

Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
by: Xu, Wengang, et al.
Published: (2018)

Iron-Catalyzed Cross-Coupling of <i>Bis</i>-(aryl)manganese Nucleophiles with Alkenyl Halides: Optimization and Mechanistic Investigations
by: Lidie Rousseau, et al.
Published: (2020-02-01)

Ru/Me-BIPAM-Catalyzed Asymmetric Addition of Arylboronic Acids to Aliphatic Aldehydes and α-Ketoesters
by: Momoko Watanabe, et al.
Published: (2011-06-01)

Copper-catalyzed O-alkenylation of phosphonates
by: Nuria Vázquez-Galiñanes, et al.
Published: (2020-04-01)

Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
by: Wengang Xu, et al.
Published: (2018-03-01)

A Simple Iron-Catalyst for Alkenylation of Ketones Using Primary Alcohols
by: Motahar Sk, et al.
Published: (2020-03-01)

Synthesis and reactions of alkenyl-gem-dichlorocyclopropanes obtained from piperylene
by: A. I. Musin, et al.
Published: (2020-11-01)

Ketoreductase Catalyzed (Dynamic) Kinetic Resolution for Biomanufacturing of Chiral Chemicals
by: Chenming Huang, et al.
Published: (2022-06-01)

Synthesis of long-chain alkyl and alkenyl bromides
by: Wolfgang J. Baumann, et al.
Published: (1966-07-01)

A New Method for Production of Chiral 2-Aryl-2-fluoropropanoic Acids Using an Effective Kinetic Resolution of Racemic 2-Aryl-2-fluoropropanoic Acids
by: Atsushi Tengeiji, et al.
Published: (2012-06-01)

Chromium(II)-catalyzed enantioselective arylation of ketones
by: Gang Wang, et al.
Published: (2016-12-01)

Ionic [Ru] complex with recyclability by electro-adsorption for efficient catalytic transfer hydrogenation of aryl ketones
by: Yue Chuan-Jun, et al.
Published: (2017-12-01)

Ferrous Salt-Catalyzed Oxidative Alkenylation of Indoles: Facile Access to 3-Alkylideneindolin-2-Ones
by: Yunfei Tian, et al.
Published: (2023-05-01)

Copper-catalyzed asymmetric arylation of N-heteroaryl aldimines : elementary step of a 1,4-insertion
by: Wu, Chunlin, et al.
Published: (2021)

Palladium-catalyzed dual C–H or N–H functionalization of unfunctionalized indole derivatives with alkenes and arenes
by: Gianluigi Broggini, et al.
Published: (2012-10-01)

A general method for asymmetric arylation and vinylation of silyl ketene acetals
by: Yang, Junfeng, et al.
Published: (2018)

Hydroamination of alkenyl N-arylhydrazones mediated by t-BuOK for the synthesis of nitrogen heterocycles
by: Peng, Xingao, et al.
Published: (2022)

Recent Developments in Transition-Metal Catalyzed Direct C–H Alkenylation, Alkylation, and Alkynylation of Azoles
by: Su Chen, et al.
Published: (2020-10-01)

Kinetic and dynamic kinetic resolution of racemic tertiary bromides by pentanidium‐catalyzed phase‐transfer azidation
by: Ren, Jingyun, et al.
Published: (2023)

Highly Efficient and Reusable Copper-Catalyzed N-Arylation of Nitrogen-Containing Heterocycles with Aryl Halides
by: Kang Hyun Park, et al.
Published: (2009-12-01)

Iron-catalyzed decarboxylative alkenylation of cycloalkanes with arylvinyl carboxylic acids via a radical process
by: Jiancan Zhao, et al.
Published: (2013-08-01)

A switchable [2]rotaxane with two active alkenyl groups
by: Xiu-Li Zheng, et al.
Published: (2018-08-01)

Combustion-Synthesized Porous CuO-CeO<sub>2</sub>-SiO<sub>2</sub> Composites as Solid Catalysts for the Alkenylation of C(sp<sup>3</sup>)-H Bonds Adjacent to a Heteroatom via Cross-Dehydrogenative Coupling
by: Ha V. Le, et al.
Published: (2021-10-01)

PDDA-Montmorillonite Composites Loaded with Ru Nanoparticles: Synthesis, Characterization, and Catalytic Properties in Hydrogenation of 2-Butanone
by: Ewa M. Serwicka, et al.
Published: (2018-08-01)

Synthesis and Characterization of Ru‐Loaded Anodized Aluminum Oxide for Hydrogenation Catalysis
by: Annelies Vandekerkhove, et al.
Published: (2019-04-01)

Tailoring the Chemical Environment of Ru–Mo Composites for Efficient Hydrogen and Oxygen Evolution Reactions
by: Chunfeng Li, et al.
Published: (2024-03-01)

N-heterocyclic iminium ions catalyzed Friedel–Crafts type alkenylation of arenes with alkynes: A metal free and solvent free approach
by: Preethi Raja, et al.
Published: (2023-09-01)

SnCl4 induced formation of C3–C11 alkenyl galactopyranosides as precursors for unsaturated neutral bolaforms
by: STANIMIR KONSTANTINOVIC, et al.
Published: (2005-07-01)

C-Arylation reactions catalyzed by CuO-nanoparticles under ligand free conditions
by: Mazaahir Kidwai, et al.
Published: (2010-04-01)

Synthesis of 3-alkenylindoles through regioselective C–H alkenylation of indoles by a ruthenium nanocatalyst
by: Abhijit Paul, et al.
Published: (2020-01-01)

Stability of Cs/Ru/MgO Catalyst for Ammonia Synthesis as a Hydrogen and Energy Carrier
by: Rahat Javaid, et al.
Published: (2022-05-01)

Synthesis of 2-aryl-benzothiazoles via Ni-catalyzed coupling of benzothiazoles and aryl sulfamates
by: Yu Xiaofeng, et al.
Published: (2020-02-01)

Hydrogenation of Furfural to Furfuryl Alcohol over Ru Particles Supported on Mildly Oxidized Biochar
by: Raoof Bardestani, et al.
Published: (2020-08-01)

Palladium-Catalyzed C–H Arylation of Benzofurans with Triarylantimony Difluorides for the Synthesis of 2-Arylbenzofurans
by: Yuki Kitamura, et al.
Published: (2020-12-01)

Chemoenzymatic Stereoselective Synthesis of <i>trans</i>-Flavan-4-ols via Lipase-Catalyzed Kinetic Resolutions
by: Martín Soto, et al.
Published: (2021-10-01)

Synthesis of a 1,2-Dithienylethene-Containing Donor-Acceptor Polymer via Palladium-Catalyzed Direct Arylation Polymerization (DArP)
by: Masayuki Wakioka, et al.
Published: (2018-04-01)

Rhodium-catalyzed triarylphosphine synthesis via cross-coupling of aryl iodides and acylphosphines
by: Jiefang Yang, et al.
Published: (2018-01-01)

Iron-Catalyzed Conjugate Addition of Aryl Iodides onto Activated Alkenes under Air in Water
by: Chung-Min Huang, et al.
Published: (2020-11-01)

Structure–activity relationships over Ru/NiAl2O4 catalysts in anisole demethoxylation: spectroscopic and kinetic studies
by: Lingxiao Li, et al.
Published: (2024-02-01)