Polyvinyl Chloride / Attapulgite / Micro-crystalline Cellulose (MCC) Composites Preparation and Analysis of the Role of MCC as a Compatibilizer

To improve the performance of polyvinyl chloride (PVC), composites incorporating polyvinyl chloride (PVC), attapulgite nanoparticles (ANPs), and microcrystalline cellulose (MCC) were successfully prepared. The composites had higher vicat softening temperatures (VSTs) and the MCC had a great influenc...

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Main Authors: Bo Wang, Hai-Rong Zhang, Chao Huang, Xue-Fang Chen, Si-Lan Shi, Lian Xiong, Jun Luo, Xin-De Chen
Format: Article
Language:English
Published: North Carolina State University 2015-09-01
Series:BioResources
Subjects:
Online Access:http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_10_4_7693_Wang_Polyvinyl_Chloride_Cellulose_Composites
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author Bo Wang
Hai-Rong Zhang
Chao Huang
Xue-Fang Chen
Si-Lan Shi
Lian Xiong
Jun Luo
Xin-De Chen
author_facet Bo Wang
Hai-Rong Zhang
Chao Huang
Xue-Fang Chen
Si-Lan Shi
Lian Xiong
Jun Luo
Xin-De Chen
author_sort Bo Wang
collection DOAJ
description To improve the performance of polyvinyl chloride (PVC), composites incorporating polyvinyl chloride (PVC), attapulgite nanoparticles (ANPs), and microcrystalline cellulose (MCC) were successfully prepared. The composites had higher vicat softening temperatures (VSTs) and the MCC had a great influence on mechanical properties of the composites. When MCC was added from 0 to 5 per hundred parts of PVC (phr), the mechanical properties of the composites increased, but the mechanical properties of the composites decreased when the MCC was more than 5 phr. The tensile breaking stress, tensile strength, and impact strength were maximized with increases of 19.76 N (4.1%), 29.66 MPa (15.5%), and 13.8 MPa (7%) when 5 phr MCC was added. Infrared spectral analysis indicated that MCC and ANPs were present in the composites. Scanning electron microscopy showed that the composites system was distributed into two phases, which indicated that MCC in composites was dissolved in the PVC matrix, and some of MCC coated the surface of ANPs as a compatibilizer. Overall, this study provided a promising method for PVC modification to improve its performance.
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spelling doaj.art-faae1412688d45a39232891d2168f8cd2022-12-22T00:19:49ZengNorth Carolina State UniversityBioResources1930-21261930-21262015-09-011047693770310.15376/biores.10.4.7693-7703Polyvinyl Chloride / Attapulgite / Micro-crystalline Cellulose (MCC) Composites Preparation and Analysis of the Role of MCC as a CompatibilizerBo Wang0Hai-Rong Zhang1Chao Huang2Xue-Fang Chen3Si-Lan Shi4Lian Xiong5Jun Luo6Xin-De Chen7University of Chinese Academy of Sciences, Beijing 100049, China; Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; R&D Center of Xuyi Attapulgite Applied Technology, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; R&D Center of Xuyi Attapulgite Applied Technology, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; ChinaUniversity of Chinese Academy of Sciences, Beijing 100049, China; Key Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; ChinaKey Laboratory of Renewable Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences; ChinaTo improve the performance of polyvinyl chloride (PVC), composites incorporating polyvinyl chloride (PVC), attapulgite nanoparticles (ANPs), and microcrystalline cellulose (MCC) were successfully prepared. The composites had higher vicat softening temperatures (VSTs) and the MCC had a great influence on mechanical properties of the composites. When MCC was added from 0 to 5 per hundred parts of PVC (phr), the mechanical properties of the composites increased, but the mechanical properties of the composites decreased when the MCC was more than 5 phr. The tensile breaking stress, tensile strength, and impact strength were maximized with increases of 19.76 N (4.1%), 29.66 MPa (15.5%), and 13.8 MPa (7%) when 5 phr MCC was added. Infrared spectral analysis indicated that MCC and ANPs were present in the composites. Scanning electron microscopy showed that the composites system was distributed into two phases, which indicated that MCC in composites was dissolved in the PVC matrix, and some of MCC coated the surface of ANPs as a compatibilizer. Overall, this study provided a promising method for PVC modification to improve its performance.http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_10_4_7693_Wang_Polyvinyl_Chloride_Cellulose_CompositesPolyvinyl chlorideAttapulgiteMicrocrystalline celluloseCompatibilizer
spellingShingle Bo Wang
Hai-Rong Zhang
Chao Huang
Xue-Fang Chen
Si-Lan Shi
Lian Xiong
Jun Luo
Xin-De Chen
Polyvinyl Chloride / Attapulgite / Micro-crystalline Cellulose (MCC) Composites Preparation and Analysis of the Role of MCC as a Compatibilizer
BioResources
Polyvinyl chloride
Attapulgite
Microcrystalline cellulose
Compatibilizer
title Polyvinyl Chloride / Attapulgite / Micro-crystalline Cellulose (MCC) Composites Preparation and Analysis of the Role of MCC as a Compatibilizer
title_full Polyvinyl Chloride / Attapulgite / Micro-crystalline Cellulose (MCC) Composites Preparation and Analysis of the Role of MCC as a Compatibilizer
title_fullStr Polyvinyl Chloride / Attapulgite / Micro-crystalline Cellulose (MCC) Composites Preparation and Analysis of the Role of MCC as a Compatibilizer
title_full_unstemmed Polyvinyl Chloride / Attapulgite / Micro-crystalline Cellulose (MCC) Composites Preparation and Analysis of the Role of MCC as a Compatibilizer
title_short Polyvinyl Chloride / Attapulgite / Micro-crystalline Cellulose (MCC) Composites Preparation and Analysis of the Role of MCC as a Compatibilizer
title_sort polyvinyl chloride attapulgite micro crystalline cellulose mcc composites preparation and analysis of the role of mcc as a compatibilizer
topic Polyvinyl chloride
Attapulgite
Microcrystalline cellulose
Compatibilizer
url http://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_10_4_7693_Wang_Polyvinyl_Chloride_Cellulose_Composites
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