Copper strip corrosion testing in hydrocracked base oil in the presence of different inhibitors
In this paper, the corrosion test of copper in hydrocracked base oil HC-6 was performed in the presence of an additive for extremely high pressures (EP additive) in different concentrations. EP additives are used to reduce wear in industrial applications, under high load conditions. Since m...
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Format: | Article |
Language: | English |
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Association of Chemical Engineers of Serbia
2022-01-01
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Series: | Hemijska Industrija |
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Online Access: | http://www.doiserbia.nb.rs/img/doi/0367-598X/2022/0367-598X2203159M.pdf |
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author | Malinović Borislav N. Borković Aleksandra Đuričić Tijana |
author_facet | Malinović Borislav N. Borković Aleksandra Đuričić Tijana |
author_sort | Malinović Borislav N. |
collection | DOAJ |
description | In this paper, the corrosion test of copper in hydrocracked base oil HC-6 was
performed in the presence of an additive for extremely high pressures (EP
additive) in different concentrations. EP additives are used to reduce
wear in industrial applications, under high load conditions. Since most of
these additives are sulfur-based, whose compounds can be corrosive at high
temperatures, their use leads to corrosion of some materials. To prevent
corrosion in the base oil with the EP additive, three commercial corrosion
inhibitors are added. By chemical composition, the inhibitor RC 8210 is a
derivate of dimercaptothia-diazole, RC 4220 is a synthetic neutral calcium
sulfonate, and IRGAMET 39 is a derivative of tolutriazole. Efficiency of the
inhibitors was monitored by standard test methods for corrosiveness to
copper arising from petroleum products by the copper strip test (ASTM D-130)
and the gravimetric method, while oxidation stability of the base oil was
monitored by peroxide number determination. Oxidation was performed at 100±1°C for 3 and 24 h. Results of these studies have shown that IRGAMET 39 is
the most effective inhibitor in the presence of the EP additive at both
examined oxidation times. |
first_indexed | 2024-12-11T16:24:54Z |
format | Article |
id | doaj.art-fac5464a58c84c6da25bf252ad0e789d |
institution | Directory Open Access Journal |
issn | 0367-598X 2217-7426 |
language | English |
last_indexed | 2024-12-11T16:24:54Z |
publishDate | 2022-01-01 |
publisher | Association of Chemical Engineers of Serbia |
record_format | Article |
series | Hemijska Industrija |
spelling | doaj.art-fac5464a58c84c6da25bf252ad0e789d2022-12-22T00:58:45ZengAssociation of Chemical Engineers of SerbiaHemijska Industrija0367-598X2217-74262022-01-0176315916610.2298/HEMIND220113012M0367-598X2203159MCopper strip corrosion testing in hydrocracked base oil in the presence of different inhibitorsMalinović Borislav N.0https://orcid.org/0000-0003-3161-5115Borković Aleksandra1https://orcid.org/0000-0002-4446-1736Đuričić Tijana2University of Banja Luka, Faculty of Technology, Banja Luka, Bosnia and HerzegovinaUniversity of Banja Luka, Faculty of Technology, Banja Luka, Bosnia and HerzegovinaUniversity of Banja Luka, Faculty of Technology, Banja Luka, Bosnia and HerzegovinaIn this paper, the corrosion test of copper in hydrocracked base oil HC-6 was performed in the presence of an additive for extremely high pressures (EP additive) in different concentrations. EP additives are used to reduce wear in industrial applications, under high load conditions. Since most of these additives are sulfur-based, whose compounds can be corrosive at high temperatures, their use leads to corrosion of some materials. To prevent corrosion in the base oil with the EP additive, three commercial corrosion inhibitors are added. By chemical composition, the inhibitor RC 8210 is a derivate of dimercaptothia-diazole, RC 4220 is a synthetic neutral calcium sulfonate, and IRGAMET 39 is a derivative of tolutriazole. Efficiency of the inhibitors was monitored by standard test methods for corrosiveness to copper arising from petroleum products by the copper strip test (ASTM D-130) and the gravimetric method, while oxidation stability of the base oil was monitored by peroxide number determination. Oxidation was performed at 100±1°C for 3 and 24 h. Results of these studies have shown that IRGAMET 39 is the most effective inhibitor in the presence of the EP additive at both examined oxidation times.http://www.doiserbia.nb.rs/img/doi/0367-598X/2022/0367-598X2203159M.pdfastm d-130copper couponslubricating oilextreme pressure additive |
spellingShingle | Malinović Borislav N. Borković Aleksandra Đuričić Tijana Copper strip corrosion testing in hydrocracked base oil in the presence of different inhibitors Hemijska Industrija astm d-130 copper coupons lubricating oil extreme pressure additive |
title | Copper strip corrosion testing in hydrocracked base oil in the presence of different inhibitors |
title_full | Copper strip corrosion testing in hydrocracked base oil in the presence of different inhibitors |
title_fullStr | Copper strip corrosion testing in hydrocracked base oil in the presence of different inhibitors |
title_full_unstemmed | Copper strip corrosion testing in hydrocracked base oil in the presence of different inhibitors |
title_short | Copper strip corrosion testing in hydrocracked base oil in the presence of different inhibitors |
title_sort | copper strip corrosion testing in hydrocracked base oil in the presence of different inhibitors |
topic | astm d-130 copper coupons lubricating oil extreme pressure additive |
url | http://www.doiserbia.nb.rs/img/doi/0367-598X/2022/0367-598X2203159M.pdf |
work_keys_str_mv | AT malinovicborislavn copperstripcorrosiontestinginhydrocrackedbaseoilinthepresenceofdifferentinhibitors AT borkovicaleksandra copperstripcorrosiontestinginhydrocrackedbaseoilinthepresenceofdifferentinhibitors AT đuricictijana copperstripcorrosiontestinginhydrocrackedbaseoilinthepresenceofdifferentinhibitors |