3-Chloro-5-(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-one
3-Chloro-5-trifluoromethanesulfonate-4H-1,2,6-thiadiazin-4-one 3 reacts with (4-dodecylthiophen-2-yl)trimethylstannane 5 (1 equiv.) in the presence of Pd(Ph3P)2Cl2 (5 mol%) in benzene at ca. 20 °C for 5 h to give 3-chloro-5-(4-dodecylthien-2-yl)-1,2,6-thiadiazinone 6 in 87% yield.
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2012-10-01
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| Series: | Molbank |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1422-8599/2012/4/M782 |
| _version_ | 1818314547317964800 |
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| author | Panayiotis A. Koutentis Heraklidia A. Ioannidou |
| author_facet | Panayiotis A. Koutentis Heraklidia A. Ioannidou |
| author_sort | Panayiotis A. Koutentis |
| collection | DOAJ |
| description | 3-Chloro-5-trifluoromethanesulfonate-4H-1,2,6-thiadiazin-4-one 3 reacts with (4-dodecylthiophen-2-yl)trimethylstannane 5 (1 equiv.) in the presence of Pd(Ph3P)2Cl2 (5 mol%) in benzene at ca. 20 °C for 5 h to give 3-chloro-5-(4-dodecylthien-2-yl)-1,2,6-thiadiazinone 6 in 87% yield. |
| first_indexed | 2024-12-13T08:51:22Z |
| format | Article |
| id | doaj.art-fae686c5aead4886b44a8eee809ffe3c |
| institution | Directory Open Access Journal |
| issn | 1422-8599 |
| language | English |
| last_indexed | 2024-12-13T08:51:22Z |
| publishDate | 2012-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj.art-fae686c5aead4886b44a8eee809ffe3c2022-12-21T23:53:21ZengMDPI AGMolbank1422-85992012-10-0120124M78210.3390/M7823-Chloro-5-(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-onePanayiotis A. KoutentisHeraklidia A. Ioannidou3-Chloro-5-trifluoromethanesulfonate-4H-1,2,6-thiadiazin-4-one 3 reacts with (4-dodecylthiophen-2-yl)trimethylstannane 5 (1 equiv.) in the presence of Pd(Ph3P)2Cl2 (5 mol%) in benzene at ca. 20 °C for 5 h to give 3-chloro-5-(4-dodecylthien-2-yl)-1,2,6-thiadiazinone 6 in 87% yield.http://www.mdpi.com/1422-8599/2012/4/M7821,2,6-thiadiazinesthiophenesheterocyclesoligomers |
| spellingShingle | Panayiotis A. Koutentis Heraklidia A. Ioannidou 3-Chloro-5-(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-one Molbank 1,2,6-thiadiazines thiophenes heterocycles oligomers |
| title | 3-Chloro-5-(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_full | 3-Chloro-5-(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_fullStr | 3-Chloro-5-(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_full_unstemmed | 3-Chloro-5-(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_short | 3-Chloro-5-(4-dodecylthiophen-2-yl)-4H-1,2,6-thiadiazin-4-one |
| title_sort | 3 chloro 5 4 dodecylthiophen 2 yl 4h 1 2 6 thiadiazin 4 one |
| topic | 1,2,6-thiadiazines thiophenes heterocycles oligomers |
| url | http://www.mdpi.com/1422-8599/2012/4/M782 |
| work_keys_str_mv | AT panayiotisakoutentis 3chloro54dodecylthiophen2yl4h126thiadiazin4one AT heraklidiaaioannidou 3chloro54dodecylthiophen2yl4h126thiadiazin4one |