A Convenient One-Pot Synthesis of a Sterically Demanding Aniline from Aryllithium Using Trimethylsilyl Azide, Conversion to <i>β</i>-Diketimines and Synthesis of a <i>β</i>-Diketiminate Magnesium Hydride Complex

A Convenient One-Pot Synthesis of a Sterically Demanding Aniline from Aryllithium Using Trimethylsilyl Azide, Conversion to <i>β</i>-Diketimines and Synthesis of a <i>β</i>-Diketiminate Magnesium Hydride Complex

This work reports the one-pot synthesis of sterically demanding aniline derivatives from aryllithium species utilising trimethylsilyl azide to introduce amine functionalities and conversions to new examples of a common <i>N,N</i>′-chelating ligand system. The reaction of TripLi (Trip = 2...

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Bibliographic Details
Main Authors: Nikita Demidov, Mateus Grebogi, Connor Bourne, Aidan P. McKay, David B. Cordes, Andreas Stasch
Format: Article
Language:English
Published: MDPI AG 2023-11-01
Series:Molecules
Subjects:
aniline synthesis
azides
<i>β</i>-diketiminates
magnesium hydride
metal-halogen exchange
organolithium reagents
Online Access:https://www.mdpi.com/1420-3049/28/22/7569

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