Preparation of Activated Carbons from Sawdust by Chemical Activation

Activated carbons were prepared from sawdust by chemical activation with H 3 PO 4 . The effects of various parameters such as the impregnation ratio, activation temperature and time on the nitrogen adsorption isotherms, specific surface areas and pore volumes of the activated carbons were measured a...

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Main Authors: Huiping Zhang, Ying Yan, Lichun Yang
Format: Article
Language:English
Published: SAGE Publishing 2008-09-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.26.7.533
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author Huiping Zhang
Ying Yan
Lichun Yang
author_facet Huiping Zhang
Ying Yan
Lichun Yang
author_sort Huiping Zhang
collection DOAJ
description Activated carbons were prepared from sawdust by chemical activation with H 3 PO 4 . The effects of various parameters such as the impregnation ratio, activation temperature and time on the nitrogen adsorption isotherms, specific surface areas and pore volumes of the activated carbons were measured and analyzed in order to optimize the operational conditions. The nitrogen adsorption capacity of the activated carbons was significantly affected by the impregnation ratio and the activation temperature. The most important operational parameter in chemical activation with H 3 PO 4 was found to be the H 3 PO 4 /sawdust impregnation ratio. The specific surface area of the activated carbon prepared with a 1:1 H 3 PO 4 /sawdust ratio and activated at 500°C for 90 min attained the relatively high value of 1642 m 2 /g. The experimental results show that, under the experimental conditions studied, an activated carbon containing well-developed micropores and mesopores exhibiting improved nitrogen adsorption properties can be obtained via a H 3 PO 4 activation process under the optimum operation conditions, viz. activated with an impregnation ratio of 1.0–1.5H 3 PO 4 /sawdust at 500°C for 60–90 min.
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spelling doaj.art-fb32e496a69a46b8ac312dedfd73a6a62025-01-02T22:39:35ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382008-09-012610.1260/0263-6174.26.7.533Preparation of Activated Carbons from Sawdust by Chemical ActivationHuiping Zhang0Ying Yan1Lichun Yang2 School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, P. R. China School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, P. R. China Department of Chemical Engineering, Xiamen University, Xiamen 361005, P. R. ChinaActivated carbons were prepared from sawdust by chemical activation with H 3 PO 4 . The effects of various parameters such as the impregnation ratio, activation temperature and time on the nitrogen adsorption isotherms, specific surface areas and pore volumes of the activated carbons were measured and analyzed in order to optimize the operational conditions. The nitrogen adsorption capacity of the activated carbons was significantly affected by the impregnation ratio and the activation temperature. The most important operational parameter in chemical activation with H 3 PO 4 was found to be the H 3 PO 4 /sawdust impregnation ratio. The specific surface area of the activated carbon prepared with a 1:1 H 3 PO 4 /sawdust ratio and activated at 500°C for 90 min attained the relatively high value of 1642 m 2 /g. The experimental results show that, under the experimental conditions studied, an activated carbon containing well-developed micropores and mesopores exhibiting improved nitrogen adsorption properties can be obtained via a H 3 PO 4 activation process under the optimum operation conditions, viz. activated with an impregnation ratio of 1.0–1.5H 3 PO 4 /sawdust at 500°C for 60–90 min.https://doi.org/10.1260/0263-6174.26.7.533
spellingShingle Huiping Zhang
Ying Yan
Lichun Yang
Preparation of Activated Carbons from Sawdust by Chemical Activation
Adsorption Science & Technology
title Preparation of Activated Carbons from Sawdust by Chemical Activation
title_full Preparation of Activated Carbons from Sawdust by Chemical Activation
title_fullStr Preparation of Activated Carbons from Sawdust by Chemical Activation
title_full_unstemmed Preparation of Activated Carbons from Sawdust by Chemical Activation
title_short Preparation of Activated Carbons from Sawdust by Chemical Activation
title_sort preparation of activated carbons from sawdust by chemical activation
url https://doi.org/10.1260/0263-6174.26.7.533
work_keys_str_mv AT huipingzhang preparationofactivatedcarbonsfromsawdustbychemicalactivation
AT yingyan preparationofactivatedcarbonsfromsawdustbychemicalactivation
AT lichunyang preparationofactivatedcarbonsfromsawdustbychemicalactivation