Synthesis and Properties of Cobalt/Nickel-Iron-Antimony(III, V)-Oxo Tartrate Cluster-Based Compounds
Two types of isostructural iron-cobalt/nickel-antimony-oxo tartrate cluster-based compounds, namely (H<sub>3</sub>O)(Me<sub>2</sub>NH<sub>2</sub>)[<i>M</i>(H<sub>2</sub>O)<sub>6</sub>]<sub>2</sub>[Fe<sup>II<...
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MDPI AG
2024-01-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/29/3/591 |
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| author | Weiyang Wen Yanqi Wang Tianyu Pan Qianqian Hu Huiping Xiao Nannan Wang Xiaoqi Li Xinxiong Li Bing Hu Xiaoying Huang |
| author_facet | Weiyang Wen Yanqi Wang Tianyu Pan Qianqian Hu Huiping Xiao Nannan Wang Xiaoqi Li Xinxiong Li Bing Hu Xiaoying Huang |
| author_sort | Weiyang Wen |
| collection | DOAJ |
| description | Two types of isostructural iron-cobalt/nickel-antimony-oxo tartrate cluster-based compounds, namely (H<sub>3</sub>O)(Me<sub>2</sub>NH<sub>2</sub>)[<i>M</i>(H<sub>2</sub>O)<sub>6</sub>]<sub>2</sub>[Fe<sup>II</sup><sub>2</sub>Sb<sup>III</sup><sub>12</sub>(<i>μ</i><sub>4</sub>-O)<sub>3</sub>(<i>μ</i><sub>3</sub>-O)<sub>8</sub>(tta)<sub>6</sub>]·6H<sub>2</sub>O (<i>M</i> = Co (<b>1</b>); Ni (<b>3</b>)), H<sub>5/3</sub>[Co<sub>2.5</sub>Fe<sup>II</sup><sub>4/3</sub>Fe<sup>III</sup><sub>3</sub>(H<sub>2</sub>O)<sub>13</sub>Sb<sup>V</sup><sub>1/3</sub>Fe<sup>III</sup><sub>2/3</sub>(<i>μ</i><sub>4</sub>-O)<sub>2</sub>(<i>μ</i><sub>3</sub>-O)<sub>4</sub>Sb<sup>III</sup><sub>6</sub>(<i>μ</i><sub>3</sub>-O)<sub>2</sub>(tta)<sub>6</sub>]·2H<sub>2</sub>O (<b>2</b>) and H<sub>2</sub>[Ni<sub>2.25</sub>Fe<sup>II</sup><sub>1.5</sub>Fe<sup>III</sup><sub>3</sub>(H<sub>2</sub>O)<sub>14</sub>Sb<sup>V</sup><sub>0.25</sub>Fe<sup>III</sup><sub>0.75</sub>(<i>μ</i><sub>4</sub>-O)<sub>2</sub>(<i>μ</i><sub>3</sub>-O)<sub>4</sub>Sb<sup>III</sup><sub>6</sub>(<i>μ</i><sub>3</sub>-O)<sub>2</sub>(tta)<sub>6</sub>]·2H<sub>2</sub>O (<b>4</b>) (H<sub>4</sub>tta = tartaric acid) were synthesized via simple solvothermal reactions. All the clusters in the structures adopt sandwich configurations, that is, bilayer sandwich configuration in <b>1</b> and <b>3</b> and monolayer sandwich configuration in <b>2</b> and <b>4</b>. Interestingly, the monolayer sandwiched compounds <b>2</b> and <b>4</b> represent rare examples of cluster-based compounds containing mixed-valence Sb(III, V), whose center of the intermediate layer is the co-occupied [Fe<i><sub>x</sub></i>Sb<sup>V</sup><sub>1−<i>x</i></sub>]. This is different from that of previously reported sandwich-type antimony-oxo clusters in which the center position is either occupied by a transition metal ion or a Sb(V) alone. Thus, the discovery of title compounds <b>2</b> and <b>4</b> makes the evolution of center metal ion more complete, that is, from <i>M</i>, <i>M<sub>x</sub></i>Sb<sup>V</sup><sub>1−<i>x</i></sub> to Sb<sup>V</sup>. All the title compounds were fully characterized, and the photocatalysis, proton conduction and magnetism of compounds <b>2</b> and <b>4</b> were studied. |
| first_indexed | 2024-03-08T03:53:15Z |
| format | Article |
| id | doaj.art-fb4ccb6fa8be4f9bb7fd9a88b73cb028 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-08T03:53:15Z |
| publishDate | 2024-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-fb4ccb6fa8be4f9bb7fd9a88b73cb0282024-02-09T15:18:44ZengMDPI AGMolecules1420-30492024-01-0129359110.3390/molecules29030591Synthesis and Properties of Cobalt/Nickel-Iron-Antimony(III, V)-Oxo Tartrate Cluster-Based CompoundsWeiyang Wen0Yanqi Wang1Tianyu Pan2Qianqian Hu3Huiping Xiao4Nannan Wang5Xiaoqi Li6Xinxiong Li7Bing Hu8Xiaoying Huang9State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaFujian Provincial Key Laboratory of Ecology-Toxicological Effects & Control for Emerging Contaminants, College of Environmental and Biological Engineering, Putian University, Putian 351100, ChinaState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaCollege of Chemistry, Fuzhou University, Fuzhou 350108, ChinaFujian Provincial Key Laboratory of Advanced Materials Oriented Chemical Engineering, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, ChinaFujian Provincial Key Laboratory of Advanced Materials Oriented Chemical Engineering, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, ChinaCollege of Chemistry, Fuzhou University, Fuzhou 350108, ChinaState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, ChinaTwo types of isostructural iron-cobalt/nickel-antimony-oxo tartrate cluster-based compounds, namely (H<sub>3</sub>O)(Me<sub>2</sub>NH<sub>2</sub>)[<i>M</i>(H<sub>2</sub>O)<sub>6</sub>]<sub>2</sub>[Fe<sup>II</sup><sub>2</sub>Sb<sup>III</sup><sub>12</sub>(<i>μ</i><sub>4</sub>-O)<sub>3</sub>(<i>μ</i><sub>3</sub>-O)<sub>8</sub>(tta)<sub>6</sub>]·6H<sub>2</sub>O (<i>M</i> = Co (<b>1</b>); Ni (<b>3</b>)), H<sub>5/3</sub>[Co<sub>2.5</sub>Fe<sup>II</sup><sub>4/3</sub>Fe<sup>III</sup><sub>3</sub>(H<sub>2</sub>O)<sub>13</sub>Sb<sup>V</sup><sub>1/3</sub>Fe<sup>III</sup><sub>2/3</sub>(<i>μ</i><sub>4</sub>-O)<sub>2</sub>(<i>μ</i><sub>3</sub>-O)<sub>4</sub>Sb<sup>III</sup><sub>6</sub>(<i>μ</i><sub>3</sub>-O)<sub>2</sub>(tta)<sub>6</sub>]·2H<sub>2</sub>O (<b>2</b>) and H<sub>2</sub>[Ni<sub>2.25</sub>Fe<sup>II</sup><sub>1.5</sub>Fe<sup>III</sup><sub>3</sub>(H<sub>2</sub>O)<sub>14</sub>Sb<sup>V</sup><sub>0.25</sub>Fe<sup>III</sup><sub>0.75</sub>(<i>μ</i><sub>4</sub>-O)<sub>2</sub>(<i>μ</i><sub>3</sub>-O)<sub>4</sub>Sb<sup>III</sup><sub>6</sub>(<i>μ</i><sub>3</sub>-O)<sub>2</sub>(tta)<sub>6</sub>]·2H<sub>2</sub>O (<b>4</b>) (H<sub>4</sub>tta = tartaric acid) were synthesized via simple solvothermal reactions. All the clusters in the structures adopt sandwich configurations, that is, bilayer sandwich configuration in <b>1</b> and <b>3</b> and monolayer sandwich configuration in <b>2</b> and <b>4</b>. Interestingly, the monolayer sandwiched compounds <b>2</b> and <b>4</b> represent rare examples of cluster-based compounds containing mixed-valence Sb(III, V), whose center of the intermediate layer is the co-occupied [Fe<i><sub>x</sub></i>Sb<sup>V</sup><sub>1−<i>x</i></sub>]. This is different from that of previously reported sandwich-type antimony-oxo clusters in which the center position is either occupied by a transition metal ion or a Sb(V) alone. Thus, the discovery of title compounds <b>2</b> and <b>4</b> makes the evolution of center metal ion more complete, that is, from <i>M</i>, <i>M<sub>x</sub></i>Sb<sup>V</sup><sub>1−<i>x</i></sub> to Sb<sup>V</sup>. All the title compounds were fully characterized, and the photocatalysis, proton conduction and magnetism of compounds <b>2</b> and <b>4</b> were studied.https://www.mdpi.com/1420-3049/29/3/591mixed-valenceantimony-oxo clustertransition metalphotodegradationproton conductionmagnetism |
| spellingShingle | Weiyang Wen Yanqi Wang Tianyu Pan Qianqian Hu Huiping Xiao Nannan Wang Xiaoqi Li Xinxiong Li Bing Hu Xiaoying Huang Synthesis and Properties of Cobalt/Nickel-Iron-Antimony(III, V)-Oxo Tartrate Cluster-Based Compounds Molecules mixed-valence antimony-oxo cluster transition metal photodegradation proton conduction magnetism |
| title | Synthesis and Properties of Cobalt/Nickel-Iron-Antimony(III, V)-Oxo Tartrate Cluster-Based Compounds |
| title_full | Synthesis and Properties of Cobalt/Nickel-Iron-Antimony(III, V)-Oxo Tartrate Cluster-Based Compounds |
| title_fullStr | Synthesis and Properties of Cobalt/Nickel-Iron-Antimony(III, V)-Oxo Tartrate Cluster-Based Compounds |
| title_full_unstemmed | Synthesis and Properties of Cobalt/Nickel-Iron-Antimony(III, V)-Oxo Tartrate Cluster-Based Compounds |
| title_short | Synthesis and Properties of Cobalt/Nickel-Iron-Antimony(III, V)-Oxo Tartrate Cluster-Based Compounds |
| title_sort | synthesis and properties of cobalt nickel iron antimony iii v oxo tartrate cluster based compounds |
| topic | mixed-valence antimony-oxo cluster transition metal photodegradation proton conduction magnetism |
| url | https://www.mdpi.com/1420-3049/29/3/591 |
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