Electrodeposition and Characterization of Sn-Zn Alloy Coatings from Sulfate Based Baths

Tin-Zinc alloy coatings have many applications because of their unique properties such as corrosion resistance, solderability and flexibility. In this study, the effect of current density, temperature and pH on chemical composition, cathodic current efficiency, morphology and structures of the coati...

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Main Authors: S. Akbarzadeh, S.R. Allahkaram, S. Mahdavi
Format: Article
Language:English
Published: Iran University of Science & Technology 2018-06-01
Series:Iranian Journal of Materials Science and Engineering
Subjects:
Online Access:http://ijmse.iust.ac.ir/browse.php?a_code=A-10-167-9&slc_lang=en&sid=1
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author S. Akbarzadeh
S.R. Allahkaram
S. Mahdavi
author_facet S. Akbarzadeh
S.R. Allahkaram
S. Mahdavi
author_sort S. Akbarzadeh
collection DOAJ
description Tin-Zinc alloy coatings have many applications because of their unique properties such as corrosion resistance, solderability and flexibility. In this study, the effect of current density, temperature and pH on chemical composition, cathodic current efficiency, morphology and structures of the coatings was investigated. The results illustrated that, at low current densities (<0.5 mA/cm2), the coatings were relatively pure tin, but Zn content increased with enhancing the current density. At higher currents a relatively pure Zn film was obtained. Temperature and pH also affected chemical composition of the alloy films. Zn content of the coatings was decreased by increasing the temperature, while its variation with pH had ascending-descending trend. Morphological investigation of the coatings revealed that increasing Zn content of deposits led to porous, rough and fine grained films.
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spelling doaj.art-fb51c9ef2756496d8e9a97051d772c9c2022-12-21T19:57:44ZengIran University of Science & TechnologyIranian Journal of Materials Science and Engineering1735-08082383-38822018-06-011525766Electrodeposition and Characterization of Sn-Zn Alloy Coatings from Sulfate Based BathsS. Akbarzadeh0S.R. Allahkaram1S. Mahdavi2 School Metallurgy and Materials Engineering, College of Engineering, University of Tehran School Metallurgy and Materials Engineering, College of Engineering, University of Tehran Research Center for Advanced Materials, Faculty of Materials Engineering, Sahand University of Technology Tin-Zinc alloy coatings have many applications because of their unique properties such as corrosion resistance, solderability and flexibility. In this study, the effect of current density, temperature and pH on chemical composition, cathodic current efficiency, morphology and structures of the coatings was investigated. The results illustrated that, at low current densities (<0.5 mA/cm2), the coatings were relatively pure tin, but Zn content increased with enhancing the current density. At higher currents a relatively pure Zn film was obtained. Temperature and pH also affected chemical composition of the alloy films. Zn content of the coatings was decreased by increasing the temperature, while its variation with pH had ascending-descending trend. Morphological investigation of the coatings revealed that increasing Zn content of deposits led to porous, rough and fine grained films.http://ijmse.iust.ac.ir/browse.php?a_code=A-10-167-9&slc_lang=en&sid=1Sn-Zn Electrodeposition Cathodic current efficiency Alloy coatings SEM.
spellingShingle S. Akbarzadeh
S.R. Allahkaram
S. Mahdavi
Electrodeposition and Characterization of Sn-Zn Alloy Coatings from Sulfate Based Baths
Iranian Journal of Materials Science and Engineering
Sn-Zn
Electrodeposition
Cathodic current efficiency
Alloy coatings
SEM.
title Electrodeposition and Characterization of Sn-Zn Alloy Coatings from Sulfate Based Baths
title_full Electrodeposition and Characterization of Sn-Zn Alloy Coatings from Sulfate Based Baths
title_fullStr Electrodeposition and Characterization of Sn-Zn Alloy Coatings from Sulfate Based Baths
title_full_unstemmed Electrodeposition and Characterization of Sn-Zn Alloy Coatings from Sulfate Based Baths
title_short Electrodeposition and Characterization of Sn-Zn Alloy Coatings from Sulfate Based Baths
title_sort electrodeposition and characterization of sn zn alloy coatings from sulfate based baths
topic Sn-Zn
Electrodeposition
Cathodic current efficiency
Alloy coatings
SEM.
url http://ijmse.iust.ac.ir/browse.php?a_code=A-10-167-9&slc_lang=en&sid=1
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AT srallahkaram electrodepositionandcharacterizationofsnznalloycoatingsfromsulfatebasedbaths
AT smahdavi electrodepositionandcharacterizationofsnznalloycoatingsfromsulfatebasedbaths