Unconventional Chiral Amplification in Luminescent Supramolecular Polymers Based on Trisbiphenylamine-tricarboxamides

Unconventional Chiral Amplification in Luminescent Supramolecular Polymers Based on Trisbiphenylamine-tricarboxamides

Abstract We describe the synthesis of two propeller-shaped, emissive trisbiphenylamines 1 and (S)-2. Whilst achiral 1 forms supramolecular polymers following a cooperative mechanism, the self-assembly of chiral (S)-2 can be described by an isodesmic mechanism. Despite the isodesmic character of the...

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Bibliographic Details
Main Authors:	Yeray Dorca, Cristina Naranjo, Goutam Ghosh, Rafael Gómez, Gustavo Fernández, Luis Sánchez
Format:	Article
Language:	English
Published:	Georg Thieme Verlag 2020-01-01
Series:	Organic Materials
Subjects:	cooperativity isodesmic helical structures supramolecular polymerization triarylamines
Online Access:	http://www.thieme-connect.de/DOI/DOI?10.1055/s-0040-1705124

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