Poly[[(μ3-isonicotinato-κ3O:O:N)(triphenylphosphine-κP)silver(I)] ethanol solvate]
In the crystal structure of {[Ag(C6H4NO2)(C18H15P)]·C2H6O}n, the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic r...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-03-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810004733 |
| _version_ | 1819280130696019968 |
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| author | Seik Weng Ng Mostafa M. Amini Omid Sadeghi |
| author_facet | Seik Weng Ng Mostafa M. Amini Omid Sadeghi |
| author_sort | Seik Weng Ng |
| collection | DOAJ |
| description | In the crystal structure of {[Ag(C6H4NO2)(C18H15P)]·C2H6O}n, the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic ring, giving a distorted tetrahedral coordination at the metal atom. The μ3-bridging mode leads to a layer motif; the disordered ethanol molecules are linked to the free carboxyl oxygen atom by O—H...O hydrogen bonds. |
| first_indexed | 2024-12-24T00:38:54Z |
| format | Article |
| id | doaj.art-fb667928cec24b3194b157ed2dce2ab2 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:38:54Z |
| publishDate | 2010-03-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-fb667928cec24b3194b157ed2dce2ab22022-12-21T17:24:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-03-01663m285m28510.1107/S1600536810004733Poly[[(μ3-isonicotinato-κ3O:O:N)(triphenylphosphine-κP)silver(I)] ethanol solvate]Seik Weng NgMostafa M. AminiOmid SadeghiIn the crystal structure of {[Ag(C6H4NO2)(C18H15P)]·C2H6O}n, the 4-pyridylcarboxylate ion binds to the phosphine-coordinated silver atoms through one of the two oxygen atoms of the carboxyl unit, and to a third phosphine-coordinate silver atom through the nitrogen atom of the aromatic ring, giving a distorted tetrahedral coordination at the metal atom. The μ3-bridging mode leads to a layer motif; the disordered ethanol molecules are linked to the free carboxyl oxygen atom by O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536810004733 |
| spellingShingle | Seik Weng Ng Mostafa M. Amini Omid Sadeghi Poly[[(μ3-isonicotinato-κ3O:O:N)(triphenylphosphine-κP)silver(I)] ethanol solvate] Acta Crystallographica Section E |
| title | Poly[[(μ3-isonicotinato-κ3O:O:N)(triphenylphosphine-κP)silver(I)] ethanol solvate] |
| title_full | Poly[[(μ3-isonicotinato-κ3O:O:N)(triphenylphosphine-κP)silver(I)] ethanol solvate] |
| title_fullStr | Poly[[(μ3-isonicotinato-κ3O:O:N)(triphenylphosphine-κP)silver(I)] ethanol solvate] |
| title_full_unstemmed | Poly[[(μ3-isonicotinato-κ3O:O:N)(triphenylphosphine-κP)silver(I)] ethanol solvate] |
| title_short | Poly[[(μ3-isonicotinato-κ3O:O:N)(triphenylphosphine-κP)silver(I)] ethanol solvate] |
| title_sort | poly amp 956 3 isonicotinato amp 954 3o o n triphenylphosphine amp 954 p silver i ethanol solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810004733 |
| work_keys_str_mv | AT seikwengng polyamp9563isonicotinatoamp9543oontriphenylphosphineamp954psilveriethanolsolvate AT mostafamamini polyamp9563isonicotinatoamp9543oontriphenylphosphineamp954psilveriethanolsolvate AT omidsadeghi polyamp9563isonicotinatoamp9543oontriphenylphosphineamp954psilveriethanolsolvate |