Sol-gel prepared active ternary oxide coating on titanium in cathodic protection
The characteristics of a ternary oxide coating, on titanium, which consisted of TiO2, RuO2 and IrO2 in the molar ratio 0.6:0.3:0.1, calculated on the metal atom, were investigated for potential application for cathodic protection in a seawater environment. The oxide coatings on titanium were prepare...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
2007-12-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/JSCS/Vol72/No12/JSCS_V72_No12-23.pdf |
| _version_ | 1811334722891022336 |
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| author | VLADIMIR V. PANIC BRANISLAV Z. NIKOLIC |
| author_facet | VLADIMIR V. PANIC BRANISLAV Z. NIKOLIC |
| author_sort | VLADIMIR V. PANIC |
| collection | DOAJ |
| description | The characteristics of a ternary oxide coating, on titanium, which consisted of TiO2, RuO2 and IrO2 in the molar ratio 0.6:0.3:0.1, calculated on the metal atom, were investigated for potential application for cathodic protection in a seawater environment. The oxide coatings on titanium were prepared by the sol gel procedure from a mixture of inorganic oxide sols, which were obtained by forced hydrolysis of metal chlorides. The morphology of the coating was examined by scanning electron microscopy. The electrochemical properties of activated titanium anodes were investigated by cyclic voltammetry and polarization measurements in a H2SO4- and NaCl-containing electrolyte, as well as in seawater sampled on the Adriatic coast in Tivat, Montenegro. The anode stability during operation in seawater was investigated by the galvanostatic accelerated corrosion stability test. The morphology and electrochemical characteristics of the ternary coating are compared to that of a sol-gel-prepared binary Ti0.6Ru0.4O2 coating. The activity of the ternary coating was similar to that of the binary Ti0.6Ru0.4O2 coating in the investigated solutions. However, the corrosion stability in seawater is found to be considerably greater for the ternary coating. |
| first_indexed | 2024-04-13T17:12:29Z |
| format | Article |
| id | doaj.art-fb73ffcad1a64945ab57d10647a00429 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-04-13T17:12:29Z |
| publishDate | 2007-12-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-fb73ffcad1a64945ab57d10647a004292022-12-22T02:38:14ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51392007-12-01721213931402Sol-gel prepared active ternary oxide coating on titanium in cathodic protectionVLADIMIR V. PANICBRANISLAV Z. NIKOLICThe characteristics of a ternary oxide coating, on titanium, which consisted of TiO2, RuO2 and IrO2 in the molar ratio 0.6:0.3:0.1, calculated on the metal atom, were investigated for potential application for cathodic protection in a seawater environment. The oxide coatings on titanium were prepared by the sol gel procedure from a mixture of inorganic oxide sols, which were obtained by forced hydrolysis of metal chlorides. The morphology of the coating was examined by scanning electron microscopy. The electrochemical properties of activated titanium anodes were investigated by cyclic voltammetry and polarization measurements in a H2SO4- and NaCl-containing electrolyte, as well as in seawater sampled on the Adriatic coast in Tivat, Montenegro. The anode stability during operation in seawater was investigated by the galvanostatic accelerated corrosion stability test. The morphology and electrochemical characteristics of the ternary coating are compared to that of a sol-gel-prepared binary Ti0.6Ru0.4O2 coating. The activity of the ternary coating was similar to that of the binary Ti0.6Ru0.4O2 coating in the investigated solutions. However, the corrosion stability in seawater is found to be considerably greater for the ternary coating.http://www.shd.org.yu/JSCS/Vol72/No12/JSCS_V72_No12-23.pdfruthenium-oxide-based coatingssol-gel procedureiridium oxidecathodic protectionstability |
| spellingShingle | VLADIMIR V. PANIC BRANISLAV Z. NIKOLIC Sol-gel prepared active ternary oxide coating on titanium in cathodic protection Journal of the Serbian Chemical Society ruthenium-oxide-based coatings sol-gel procedure iridium oxide cathodic protection stability |
| title | Sol-gel prepared active ternary oxide coating on titanium in cathodic protection |
| title_full | Sol-gel prepared active ternary oxide coating on titanium in cathodic protection |
| title_fullStr | Sol-gel prepared active ternary oxide coating on titanium in cathodic protection |
| title_full_unstemmed | Sol-gel prepared active ternary oxide coating on titanium in cathodic protection |
| title_short | Sol-gel prepared active ternary oxide coating on titanium in cathodic protection |
| title_sort | sol gel prepared active ternary oxide coating on titanium in cathodic protection |
| topic | ruthenium-oxide-based coatings sol-gel procedure iridium oxide cathodic protection stability |
| url | http://www.shd.org.yu/JSCS/Vol72/No12/JSCS_V72_No12-23.pdf |
| work_keys_str_mv | AT vladimirvpanic solgelpreparedactiveternaryoxidecoatingontitaniumincathodicprotection AT branislavznikolic solgelpreparedactiveternaryoxidecoatingontitaniumincathodicprotection |