La variété β-NaMoO2(AsO4)
The title compound, sodium dioxidomolybdenum(VI) arsenate(V), β-NaMoO2AsO4, was prepared by solid-state reaction at 953 K. In the crystal structure, the AsO4 tetrahedra and MoO6 octahedra (both with m symmetry) share corner atoms to form a three-dimensional framework that delimits...
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Format: | Article |
Language: | English |
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International Union of Crystallography
2009-02-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809002517 |
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author | Ahmed Driss Mohamed Faouzi Zid Soumaya Ben Hlila |
author_facet | Ahmed Driss Mohamed Faouzi Zid Soumaya Ben Hlila |
author_sort | Ahmed Driss |
collection | DOAJ |
description | The title compound, sodium dioxidomolybdenum(VI) arsenate(V), β-NaMoO2AsO4, was prepared by solid-state reaction at 953 K. In the crystal structure, the AsO4 tetrahedra and MoO6 octahedra (both with m symmetry) share corner atoms to form a three-dimensional framework that delimits cavities parallel to [010] where disordered six-coordinated sodium cations (half-occupation) are located. Structural relationships between the different orthoarsenates of the AMoO2AsO4 series (A = Ag, Li, Na, K and Rb) are discussed. |
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format | Article |
id | doaj.art-fb7995f0226d4c6d8fcd6a63cec9692b |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-22T06:42:10Z |
publishDate | 2009-02-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-fb7995f0226d4c6d8fcd6a63cec9692b2022-12-21T18:35:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652i11i1110.1107/S1600536809002517La variété β-NaMoO2(AsO4)Ahmed DrissMohamed Faouzi ZidSoumaya Ben HlilaThe title compound, sodium dioxidomolybdenum(VI) arsenate(V), β-NaMoO2AsO4, was prepared by solid-state reaction at 953 K. In the crystal structure, the AsO4 tetrahedra and MoO6 octahedra (both with m symmetry) share corner atoms to form a three-dimensional framework that delimits cavities parallel to [010] where disordered six-coordinated sodium cations (half-occupation) are located. Structural relationships between the different orthoarsenates of the AMoO2AsO4 series (A = Ag, Li, Na, K and Rb) are discussed.http://scripts.iucr.org/cgi-bin/paper?S1600536809002517 |
spellingShingle | Ahmed Driss Mohamed Faouzi Zid Soumaya Ben Hlila La variété β-NaMoO2(AsO4) Acta Crystallographica Section E |
title | La variété β-NaMoO2(AsO4) |
title_full | La variété β-NaMoO2(AsO4) |
title_fullStr | La variété β-NaMoO2(AsO4) |
title_full_unstemmed | La variété β-NaMoO2(AsO4) |
title_short | La variété β-NaMoO2(AsO4) |
title_sort | la vari 233 t 233 946 namoo2 aso4 |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536809002517 |
work_keys_str_mv | AT ahmeddriss lavari233t233946namoo2aso4 AT mohamedfaouzizid lavari233t233946namoo2aso4 AT soumayabenhlila lavari233t233946namoo2aso4 |