BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives

Herein, it has been shown that the bismuth ferrite magnetic nanoparticles (BFO-MNPs) are new, efficient and recyclable catalysts for the synthesis of polyhydroquinoline derivatives by the Hantzsch reaction. The one-pot four-component cyclocondensation reaction of dimedone, aromatic aldehydes, ethyl...

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Main Authors: Maryam Khashi, Sadegh Allameh, Safar Ali Beyramabadi, Ali Morsali, Elnaz Dastmalchian, Azar Gharib
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2017-06-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_28060_4cec26822f679e1fff2dd2df00c9001d.pdf
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author Maryam Khashi
Sadegh Allameh
Safar Ali Beyramabadi
Ali Morsali
Elnaz Dastmalchian
Azar Gharib
author_facet Maryam Khashi
Sadegh Allameh
Safar Ali Beyramabadi
Ali Morsali
Elnaz Dastmalchian
Azar Gharib
author_sort Maryam Khashi
collection DOAJ
description Herein, it has been shown that the bismuth ferrite magnetic nanoparticles (BFO-MNPs) are new, efficient and recyclable catalysts for the synthesis of polyhydroquinoline derivatives by the Hantzsch reaction. The one-pot four-component cyclocondensation reaction of dimedone, aromatic aldehydes, ethyl acetoacetate and ammonium acetate was carried out under solvent-free conditions. The desired products were obtained in very short reaction times with high yields. The magnetic nanocatalyst was characterized by the X-Ray Diffraction (XRD) and FT-IR analysis. For the first time, the bismuth ferrite magnetic nanoparticles were used as a catalyst in the Hantzsch reaction. The catalyst was found to be reusable, which showed considerable catalytic activity after the third run.
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spelling doaj.art-fb826ca449a447ea81263f0a0fa3c0952022-12-22T01:56:45ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862017-06-01363455228060BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline DerivativesMaryam Khashi0Sadegh Allameh1Safar Ali Beyramabadi2Ali Morsali3Elnaz Dastmalchian4Azar Gharib5Young Researchers and Elite Club, Mashhad Branch, Islamic Azad University, Mashhad, IranDepartment of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANDepartment of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANDepartment of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANDepartment of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANYoung Researchers and Elite Club, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANHerein, it has been shown that the bismuth ferrite magnetic nanoparticles (BFO-MNPs) are new, efficient and recyclable catalysts for the synthesis of polyhydroquinoline derivatives by the Hantzsch reaction. The one-pot four-component cyclocondensation reaction of dimedone, aromatic aldehydes, ethyl acetoacetate and ammonium acetate was carried out under solvent-free conditions. The desired products were obtained in very short reaction times with high yields. The magnetic nanocatalyst was characterized by the X-Ray Diffraction (XRD) and FT-IR analysis. For the first time, the bismuth ferrite magnetic nanoparticles were used as a catalyst in the Hantzsch reaction. The catalyst was found to be reusable, which showed considerable catalytic activity after the third run.http://www.ijcce.ac.ir/article_28060_4cec26822f679e1fff2dd2df00c9001d.pdfbifeo3 nmpsmagnetic nanocatalystspolyhydroquinoline derivativeshantzsch reaction
spellingShingle Maryam Khashi
Sadegh Allameh
Safar Ali Beyramabadi
Ali Morsali
Elnaz Dastmalchian
Azar Gharib
BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives
Iranian Journal of Chemistry & Chemical Engineering
bifeo3 nmps
magnetic nanocatalysts
polyhydroquinoline derivatives
hantzsch reaction
title BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives
title_full BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives
title_fullStr BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives
title_full_unstemmed BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives
title_short BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives
title_sort bifeo3 magnetic nanoparticles a novel efficient and reusable magnetic catalyst for the synthesis of polyhydroquinoline derivatives
topic bifeo3 nmps
magnetic nanocatalysts
polyhydroquinoline derivatives
hantzsch reaction
url http://www.ijcce.ac.ir/article_28060_4cec26822f679e1fff2dd2df00c9001d.pdf
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