BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives
Herein, it has been shown that the bismuth ferrite magnetic nanoparticles (BFO-MNPs) are new, efficient and recyclable catalysts for the synthesis of polyhydroquinoline derivatives by the Hantzsch reaction. The one-pot four-component cyclocondensation reaction of dimedone, aromatic aldehydes, ethyl...
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2017-06-01
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Series: | Iranian Journal of Chemistry & Chemical Engineering |
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Online Access: | http://www.ijcce.ac.ir/article_28060_4cec26822f679e1fff2dd2df00c9001d.pdf |
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author | Maryam Khashi Sadegh Allameh Safar Ali Beyramabadi Ali Morsali Elnaz Dastmalchian Azar Gharib |
author_facet | Maryam Khashi Sadegh Allameh Safar Ali Beyramabadi Ali Morsali Elnaz Dastmalchian Azar Gharib |
author_sort | Maryam Khashi |
collection | DOAJ |
description | Herein, it has been shown that the bismuth ferrite magnetic nanoparticles (BFO-MNPs) are new, efficient and recyclable catalysts for the synthesis of polyhydroquinoline derivatives by the Hantzsch reaction. The one-pot four-component cyclocondensation reaction of dimedone, aromatic aldehydes, ethyl acetoacetate and ammonium acetate was carried out under solvent-free conditions. The desired products were obtained in very short reaction times with high yields. The magnetic nanocatalyst was characterized by the X-Ray Diffraction (XRD) and FT-IR analysis. For the first time, the bismuth ferrite magnetic nanoparticles were used as a catalyst in the Hantzsch reaction. The catalyst was found to be reusable, which showed considerable catalytic activity after the third run. |
first_indexed | 2024-12-10T08:02:36Z |
format | Article |
id | doaj.art-fb826ca449a447ea81263f0a0fa3c095 |
institution | Directory Open Access Journal |
issn | 1021-9986 1021-9986 |
language | English |
last_indexed | 2024-12-10T08:02:36Z |
publishDate | 2017-06-01 |
publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
record_format | Article |
series | Iranian Journal of Chemistry & Chemical Engineering |
spelling | doaj.art-fb826ca449a447ea81263f0a0fa3c0952022-12-22T01:56:45ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862017-06-01363455228060BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline DerivativesMaryam Khashi0Sadegh Allameh1Safar Ali Beyramabadi2Ali Morsali3Elnaz Dastmalchian4Azar Gharib5Young Researchers and Elite Club, Mashhad Branch, Islamic Azad University, Mashhad, IranDepartment of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANDepartment of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANDepartment of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANDepartment of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANYoung Researchers and Elite Club, Mashhad Branch, Islamic Azad University, Mashhad, I.R. IRANHerein, it has been shown that the bismuth ferrite magnetic nanoparticles (BFO-MNPs) are new, efficient and recyclable catalysts for the synthesis of polyhydroquinoline derivatives by the Hantzsch reaction. The one-pot four-component cyclocondensation reaction of dimedone, aromatic aldehydes, ethyl acetoacetate and ammonium acetate was carried out under solvent-free conditions. The desired products were obtained in very short reaction times with high yields. The magnetic nanocatalyst was characterized by the X-Ray Diffraction (XRD) and FT-IR analysis. For the first time, the bismuth ferrite magnetic nanoparticles were used as a catalyst in the Hantzsch reaction. The catalyst was found to be reusable, which showed considerable catalytic activity after the third run.http://www.ijcce.ac.ir/article_28060_4cec26822f679e1fff2dd2df00c9001d.pdfbifeo3 nmpsmagnetic nanocatalystspolyhydroquinoline derivativeshantzsch reaction |
spellingShingle | Maryam Khashi Sadegh Allameh Safar Ali Beyramabadi Ali Morsali Elnaz Dastmalchian Azar Gharib BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives Iranian Journal of Chemistry & Chemical Engineering bifeo3 nmps magnetic nanocatalysts polyhydroquinoline derivatives hantzsch reaction |
title | BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives |
title_full | BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives |
title_fullStr | BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives |
title_full_unstemmed | BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives |
title_short | BiFeO3 Magnetic Nanoparticles: A Novel, Efficient and Reusable Magnetic Catalyst for the Synthesis of Polyhydroquinoline Derivatives |
title_sort | bifeo3 magnetic nanoparticles a novel efficient and reusable magnetic catalyst for the synthesis of polyhydroquinoline derivatives |
topic | bifeo3 nmps magnetic nanocatalysts polyhydroquinoline derivatives hantzsch reaction |
url | http://www.ijcce.ac.ir/article_28060_4cec26822f679e1fff2dd2df00c9001d.pdf |
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