Preparation and Characterization of Dicyclopentadienyl Compound of Titanium(IV)I(二环戊二烯基钛(IV)配合物的合成及表征Ⅰ)
选择具有抗菌、抗氧化或抗炎镇痛的药物——水杨酸(HLⅠ)、阿斯匹林(HLⅡ)与具有抗癌活性的二氯二茂钛(Cp2TiCl2)在非水介质中反应, 得到两种具有潜在药理活性的茂钛配合物:Cp2Ti(LⅠ)2,Cp2Ti(LⅡ)2 .经过元素分析、摩尔电导、核磁共振氢谱与碳谱、红外及紫外光谱等测试, 表明水杨酸、阿斯匹林均与二氯二茂钛形成含Ti-O 键的单齿配位的羧酸二取代二茂钛配合物....
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| Format: | Article |
| Language: | zho |
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Zhejiang University Press
1999-01-01
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| Series: | Zhejiang Daxue xuebao. Lixue ban |
| Subjects: | |
| Online Access: | https://doi.org/zjup/1008-9497.1999.26.2.56-60 |
| _version_ | 1827303702837329920 |
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| author | XIEXiao-mei(谢晓梅) SHIWei-yong(石伟勇) MAGuo-rui(马国瑞) (曾正志) |
| author_facet | XIEXiao-mei(谢晓梅) SHIWei-yong(石伟勇) MAGuo-rui(马国瑞) (曾正志) |
| author_sort | XIEXiao-mei(谢晓梅) |
| collection | DOAJ |
| description | 选择具有抗菌、抗氧化或抗炎镇痛的药物——水杨酸(HLⅠ)、阿斯匹林(HLⅡ)与具有抗癌活性的二氯二茂钛(Cp2TiCl2)在非水介质中反应, 得到两种具有潜在药理活性的茂钛配合物:Cp2Ti(LⅠ)2,Cp2Ti(LⅡ)2 .经过元素分析、摩尔电导、核磁共振氢谱与碳谱、红外及紫外光谱等测试, 表明水杨酸、阿斯匹林均与二氯二茂钛形成含Ti-O 键的单齿配位的羧酸二取代二茂钛配合物. |
| first_indexed | 2024-04-24T17:05:28Z |
| format | Article |
| id | doaj.art-fbacbc8f743f43778e129b131f76deb3 |
| institution | Directory Open Access Journal |
| issn | 1008-9497 |
| language | zho |
| last_indexed | 2024-04-24T17:05:28Z |
| publishDate | 1999-01-01 |
| publisher | Zhejiang University Press |
| record_format | Article |
| series | Zhejiang Daxue xuebao. Lixue ban |
| spelling | doaj.art-fbacbc8f743f43778e129b131f76deb32024-03-29T01:58:16ZzhoZhejiang University PressZhejiang Daxue xuebao. Lixue ban1008-94971999-01-012625660zjup/1008-9497.1999.26.2.56-60Preparation and Characterization of Dicyclopentadienyl Compound of Titanium(IV)I(二环戊二烯基钛(IV)配合物的合成及表征Ⅰ)XIEXiao-mei(谢晓梅)0SHIWei-yong(石伟勇)1MAGuo-rui(马国瑞)2(曾正志)Applied Chemistry Research Lab of Soil and Agrochemistry, Zhejiang University, Hangzhou 310029, China( 1.浙江大学华家池校区土化系应用化学研究室，浙江 杭州 310029)Applied Chemistry Research Lab of Soil and Agrochemistry, Zhejiang University, Hangzhou 310029, China( 1.浙江大学华家池校区土化系应用化学研究室，浙江 杭州 310029)Applied Chemistry Research Lab of Soil and Agrochemistry, Zhejiang University, Hangzhou 310029, China( 1.浙江大学华家池校区土化系应用化学研究室，浙江 杭州 310029)选择具有抗菌、抗氧化或抗炎镇痛的药物——水杨酸(HLⅠ)、阿斯匹林(HLⅡ)与具有抗癌活性的二氯二茂钛(Cp2TiCl2)在非水介质中反应, 得到两种具有潜在药理活性的茂钛配合物:Cp2Ti(LⅠ)2,Cp2Ti(LⅡ)2 .经过元素分析、摩尔电导、核磁共振氢谱与碳谱、红外及紫外光谱等测试, 表明水杨酸、阿斯匹林均与二氯二茂钛形成含Ti-O 键的单齿配位的羧酸二取代二茂钛配合物.https://doi.org/zjup/1008-9497.1999.26.2.56-60水杨酸茂钛配合物阿斯匹林茂钛配合物 |
| spellingShingle | XIEXiao-mei(谢晓梅) SHIWei-yong(石伟勇) MAGuo-rui(马国瑞) (曾正志) Preparation and Characterization of Dicyclopentadienyl Compound of Titanium(IV)I(二环戊二烯基钛(IV)配合物的合成及表征Ⅰ) Zhejiang Daxue xuebao. Lixue ban 水杨酸茂钛配合物 阿斯匹林茂钛配合物 |
| title | Preparation and Characterization of Dicyclopentadienyl Compound of Titanium(IV)I(二环戊二烯基钛(IV)配合物的合成及表征Ⅰ) |
| title_full | Preparation and Characterization of Dicyclopentadienyl Compound of Titanium(IV)I(二环戊二烯基钛(IV)配合物的合成及表征Ⅰ) |
| title_fullStr | Preparation and Characterization of Dicyclopentadienyl Compound of Titanium(IV)I(二环戊二烯基钛(IV)配合物的合成及表征Ⅰ) |
| title_full_unstemmed | Preparation and Characterization of Dicyclopentadienyl Compound of Titanium(IV)I(二环戊二烯基钛(IV)配合物的合成及表征Ⅰ) |
| title_short | Preparation and Characterization of Dicyclopentadienyl Compound of Titanium(IV)I(二环戊二烯基钛(IV)配合物的合成及表征Ⅰ) |
| title_sort | preparation and characterization of dicyclopentadienyl compound of titanium iv i 二环戊二烯基钛 iv 配合物的合成及表征i |
| topic | 水杨酸茂钛配合物 阿斯匹林茂钛配合物 |
| url | https://doi.org/zjup/1008-9497.1999.26.2.56-60 |
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