Piezoresistive and mechanical Behavior of CNT based polyurethane foam

Carbon nanotubes (CNT) embedded into a polymeric foam demonstrate an enhancement in electrical and mechanical properties of the final nanocomposite. The enhanced material with new characteristics, e.g., piezoresistivity, can be substituted with the traditional metallic material to design sensors, sw...

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Main Authors: Enea De Meo, Simone Agnelli, Antonino Veca, Valentia Brunella, Marco Zanetti
Format: Article
Language:English
Published: MDPI AG 2020-09-01
Series:Journal of Composites Science
Subjects:
Online Access:https://www.mdpi.com/2504-477X/4/3/131
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author Enea De Meo
Simone Agnelli
Antonino Veca
Valentia Brunella
Marco Zanetti
author_facet Enea De Meo
Simone Agnelli
Antonino Veca
Valentia Brunella
Marco Zanetti
author_sort Enea De Meo
collection DOAJ
description Carbon nanotubes (CNT) embedded into a polymeric foam demonstrate an enhancement in electrical and mechanical properties of the final nanocomposite. The enhanced material with new characteristics, e.g., piezoresistivity, can be substituted with the traditional metallic material to design sensors, switches, and knobs directly into a single multifunctional component. Research activities in this field are moving towards a mono-material fully integrated smarts components. In order to achieve this goal, a simple method is developed to produce piezoresistive polyurethane/CNT foams. The novelty consists in applying the dispersion of CNT considering industrial production constrains, in order to facilitate its introduction into a common industrial practice. Three kinds of PU-CNT foam have been prepared and tested: PU-CNT 1.5%, PU-CNT-COOH 1.0%, and PU-CNT-COOH 1.5%. Polyurethane with CNT-COOH showed an insulating-conductive transition phenomenon when the foam reaches the 80% of its compression strain with a Gauge factor (Gf) of about 30. Instead, PU-CNT showed conductivity only at 1.5% of filler concentration and a steady piezoresistive behavior with a Gf of 80. However, this samples did not show the insulating-conductive transition. Having improved the electromechanical properties of final nanocomposite polyurethane foam demonstrates that the proposed method can be applied differently for design sensors and switches.
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spelling doaj.art-fc42ab410ac5482ca3811760e33eb8552023-11-20T12:45:27ZengMDPI AGJournal of Composites Science2504-477X2020-09-014313110.3390/jcs4030131Piezoresistive and mechanical Behavior of CNT based polyurethane foamEnea De Meo0Simone Agnelli1Antonino Veca2Valentia Brunella3Marco Zanetti4Department of Chemistry, NIS and INSTM Reference Centres, University of Torino, Via P. Giuria 7, 10125 Torino, ItalyDepartment of Chemistry, NIS and INSTM Reference Centres, University of Torino, Via P. Giuria 7, 10125 Torino, ItalyCentro Ricerche Fiat. S.C.p.A.—Group Materials Labs, C.so Settembrini 40, 10135 Torino, ItalyDepartment of Chemistry, NIS and INSTM Reference Centres, University of Torino, Via P. Giuria 7, 10125 Torino, ItalyDepartment of Chemistry, NIS and INSTM Reference Centres, University of Torino, Via P. Giuria 7, 10125 Torino, ItalyCarbon nanotubes (CNT) embedded into a polymeric foam demonstrate an enhancement in electrical and mechanical properties of the final nanocomposite. The enhanced material with new characteristics, e.g., piezoresistivity, can be substituted with the traditional metallic material to design sensors, switches, and knobs directly into a single multifunctional component. Research activities in this field are moving towards a mono-material fully integrated smarts components. In order to achieve this goal, a simple method is developed to produce piezoresistive polyurethane/CNT foams. The novelty consists in applying the dispersion of CNT considering industrial production constrains, in order to facilitate its introduction into a common industrial practice. Three kinds of PU-CNT foam have been prepared and tested: PU-CNT 1.5%, PU-CNT-COOH 1.0%, and PU-CNT-COOH 1.5%. Polyurethane with CNT-COOH showed an insulating-conductive transition phenomenon when the foam reaches the 80% of its compression strain with a Gauge factor (Gf) of about 30. Instead, PU-CNT showed conductivity only at 1.5% of filler concentration and a steady piezoresistive behavior with a Gf of 80. However, this samples did not show the insulating-conductive transition. Having improved the electromechanical properties of final nanocomposite polyurethane foam demonstrates that the proposed method can be applied differently for design sensors and switches.https://www.mdpi.com/2504-477X/4/3/131nanocompositeconductive polymerspolymer-matrix composites (PMCs)electrical properties
spellingShingle Enea De Meo
Simone Agnelli
Antonino Veca
Valentia Brunella
Marco Zanetti
Piezoresistive and mechanical Behavior of CNT based polyurethane foam
Journal of Composites Science
nanocomposite
conductive polymers
polymer-matrix composites (PMCs)
electrical properties
title Piezoresistive and mechanical Behavior of CNT based polyurethane foam
title_full Piezoresistive and mechanical Behavior of CNT based polyurethane foam
title_fullStr Piezoresistive and mechanical Behavior of CNT based polyurethane foam
title_full_unstemmed Piezoresistive and mechanical Behavior of CNT based polyurethane foam
title_short Piezoresistive and mechanical Behavior of CNT based polyurethane foam
title_sort piezoresistive and mechanical behavior of cnt based polyurethane foam
topic nanocomposite
conductive polymers
polymer-matrix composites (PMCs)
electrical properties
url https://www.mdpi.com/2504-477X/4/3/131
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AT antoninoveca piezoresistiveandmechanicalbehaviorofcntbasedpolyurethanefoam
AT valentiabrunella piezoresistiveandmechanicalbehaviorofcntbasedpolyurethanefoam
AT marcozanetti piezoresistiveandmechanicalbehaviorofcntbasedpolyurethanefoam