Synthesis of Cationic [4], [5], and [6]Azahelicenes with Extended π-Conjugated Systems
The scope of Rh-catalyzed C–C bond cleavage/annulation of biphenylene with various aromatic nitriles was studied. The subsequent Rh- and Ir-catalyzed C–H bond activation/annulation sequence of the formed 9-arylphenanthridines with alkynes gave rise to cationic [4], [5], [6] helical quinolizinium sal...
Main Authors: | Samuel Hrubý, Jan Ulč, Ivana Císařová, Martin Kotora |
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Format: | Article |
Language: | English |
Published: |
MDPI AG
2023-05-01
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Series: | Catalysts |
Subjects: | |
Online Access: | https://www.mdpi.com/2073-4344/13/5/912 |
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