Synthesis of Cationic [4], [5], and [6]Azahelicenes with Extended π-Conjugated Systems

The scope of Rh-catalyzed C–C bond cleavage/annulation of biphenylene with various aromatic nitriles was studied. The subsequent Rh- and Ir-catalyzed C–H bond activation/annulation sequence of the formed 9-arylphenanthridines with alkynes gave rise to cationic [4], [5], [6] helical quinolizinium sal...

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Bibliographic Details
Main Authors: Samuel Hrubý, Jan Ulč, Ivana Císařová, Martin Kotora
Format: Article
Language:English
Published: MDPI AG 2023-05-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/13/5/912

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