Expanded Ligands Based upon Iron(II) Coordination Compounds of Asymmetrical Bis(terpyridine) Domains

Expanded Ligands Based upon Iron(II) Coordination Compounds of Asymmetrical Bis(terpyridine) Domains

The synthesis and characterization of two tritopic ligands containing a 2,2′:6′,2″-terpyridine (tpy) metal binding domain and either a 3,2′:6′,3″- or a 4,2′:6′,4″-tpy domain are detailed. The synthetic routes to these ligands involved the [Pd(dppf)Cl<sub>2</sub>]-catalyzed coupling of a...

Full description

Bibliographic Details
Main Authors:	Dalila Rocco, Alessandro Prescimone, Catherine E. Housecroft, Edwin C. Constable
Format:	Article
Language:	English
Published:	MDPI AG 2022-12-01
Series:	Molecules
Subjects:	2,2′:6′,2″-terpyridine 3,2′:6′,3″-terpyridine 4,2′:6′,4″-terpyridine iron(II) expanded ligand
Online Access:	https://www.mdpi.com/1420-3049/28/1/82

Similar Items

Isomers of Terpyridine as Ligands in Coordination Polymers and Networks Containing Zinc(II) and Cadmium(II)
by: Catherine E. Housecroft, et al.
Published: (2021-05-01)

Isomeric 4,2′:6′,4″- and 3,2′:6′,3″-Terpyridines with Isomeric 4′-Trifluoromethylphenyl Substituents: Effects on the Assembly of Coordination Polymers with [Cu(hfacac)<sub>2</sub>] (Hhfacac = Hexafluoropentane-2,4-dione)
by: Giacomo Manfroni, et al.
Published: (2021-07-01)

Switching the Conformation of 3,2′:6′,3″-tpy Domains in 4′-(4-<i>n</i>-Alkyloxyphenyl)-3,2′:6′,3″-Terpyridines
by: Dalila Rocco, et al.
Published: (2020-07-01)

Directing 2D-Coordination Networks: Combined Effects of a Conformationally Flexible 3,2′:6′,3″-Terpyridine and Chain Length Variation in 4′-(4-<i>n</i>-Alkyloxyphenyl) Substituents
by: Dalila Rocco, et al.
Published: (2020-04-01)

A Tail Does Not Always Make a Difference: Assembly of <i>cds</i> Nets from Co(NCS)<sub>2</sub> and 1,4-bis(<i>n</i>-Alkyloxy)-2,5-bis(3,2′:6′,3″-terpyridin-4′-yl)benzene Ligands
by: Simona S. Capomolla, et al.
Published: (2022-08-01)

To Be or Not to Be a (4,4) Net: Reactions of 4′-{4-(<i>N,N-</i>Diethylaminophenyl)}- and 4′-{4-(<i>N,N-</i>Diphenylaminophenyl)}-3,2′:6′,3″- and 4,2′:6′,4″-Terpyridines with Cobalt(II) Thiocyanate
by: Dalila Rocco, et al.
Published: (2022-08-01)

Adapting (4,4) Networks through Substituent Effects and Conformationally Flexible 3,2’:6’,3”-Terpyridines
by: Dalila Rocco, et al.
Published: (2021-10-01)

Manipulating the Conformation of 3,2′:6′,3″-Terpyridine in [Cu<sub>2</sub>(μ-OAc)<sub>4</sub>(3,2′:6′,3″-tpy)]<i><sub>n</sub></i> 1D-Polymers
by: Dalila Rocco, et al.
Published: (2021-02-01)

Push-Pull Effect of Terpyridine Substituted by Triphenylamine Motive—Impact of Viscosity, Polarity and Protonation on Molecular Optical Properties
by: Anna Maria Maroń, et al.
Published: (2022-10-01)

Synthesis, X-ray Studies and Photophysical Properties of Iridium(III) Complexes Incorporating Functionalized 2,2′:6′,2″ Terpyridines and 2,6-Bis(thiazol-2-yl)pyridines
by: Bartosz Zowiślok, et al.
Published: (2024-05-01)

Imbalance of redox homeostasis and altered cellular signaling induced by the metal complexes of terpyridine
by: Katarzyna Malarz, et al.
Published: (2024-11-01)

Diverse Cobalt(II) and Iron(II/III) Coordination Complexes/Polymers Based on 4′-Pyridyl: 2,2′;6′,2″-Terpyridine: Synthesis, Structures, Catalytic and Anticancer Activities
by: Shu-Yuan Cheng, et al.
Published: (2024-09-01)

Field-Induced Single-Ion Magnet Behavior in Nickel(II) Complexes with Functionalized 2,2′:6′-2″-Terpyridine Derivatives: Preparation and Magneto-Structural Study
by: Francisco Ramón Fortea-Pérez, et al.
Published: (2023-05-01)

The Role of Intraligand Charge Transfer Processes in Iridium(III) Complexes with Morpholine-Decorated 4′-Phenyl-2,2′:6′,2″-terpyridine
by: Joanna Palion-Gazda, et al.
Published: (2024-06-01)

4′-(2-Methoxyphenyl)-2,2′:6′,2′′-terpyridine
by: Eric M. Njogu, et al.
Published: (2024-11-01)

Synthesis of Bis-Terpyridine-Based Metallopolymers and the Thermoelectric Properties of Their Single Walled Carbon Nanotube Composites
by: Jiahua Li, et al.
Published: (2021-04-01)

Structural and Photophysical Trends in Rhenium(I) Carbonyl Complexes with 2,2′:6′,2″-Terpyridines
by: Joanna Palion-Gazda, et al.
Published: (2024-04-01)

C–H…X (X = F, Cl, Br, I) Versus π-Stacking in the Crystal Packing of Compounds Containing the {M(tpy)X<sub>3</sub>} Motif
by: Catherine E. Housecroft, et al.
Published: (2023-05-01)

Synthesis, characterization, and antibacterial activity of functionalized terpyridine silver(I) complexes
by: Maxime Lynn Pillay, et al.
Published: (2024-08-01)

Preparation of Substituted Pyridines via a Coupling of β-Enamine Carbonyls with Rongalite-Application for Synthesis of Terpyridines
by: Yung-Yuan Lee, et al.
Published: (2022-08-01)

Photoinduced Processes in Rhenium(I) Terpyridine Complexes Bearing Remote Amine Groups: New Insights from Transient Absorption Spectroscopy
by: Joanna Palion-Gazda, et al.
Published: (2022-10-01)

2-(((4-([2,2′:6′,2″-Terpyridin]-4′-yl)phenyl)imino)methyl)-6-methoxyphenol
by: Lingsen Li, et al.
Published: (2023-06-01)

Investigating the Anticancer Properties of Novel Functionalized Platinum(II)–Terpyridine Complexes
by: Roberta Panebianco, et al.
Published: (2024-06-01)

Jahn-Teller distortion in bis(terpyridine)nickel(III) – Elongation or compression?
by: Jeanet Conradie
Published: (2023-12-01)

Acid Hydrolysis of Bis(2,2'; 6',2''–Terpyridyl) Iron(II) Complex in the Water Pools of CTAB/Hexane/Chloroform Reverse Micelles-A Kinetic Study in Confined Medium
by: K. V. Nagalakshmi, et al.
Published: (2020-12-01)

Cyclometalated and NNN Terpyridine Ruthenium Photocatalysts and Their Cytotoxic Activity
by: Maurizio Ballico, et al.
Published: (2024-05-01)

Design of A3B-Porphyrin Conjugates with Terpyridine as Potential Theranostic Agents: Synthesis, Complexation with Fe(III), Gd(III), and Photodynamic Activity
by: Kseniya A. Zhdanova, et al.
Published: (2023-01-01)

Luminescent Iridium–Terpyridine Complexes with Various Bis-Cyclometalated Ligands
by: Ko Ikeda, et al.
Published: (2025-01-01)

Synthesis, Electrochemistry and Density Functional Theory of Osmium(II) Containing Different 2,2′:6′,2″-Terpyridines
by: Nandisiwe G. S. Mateyise, et al.
Published: (2024-10-01)

C–H Metalation of Terpyridine Stereoisomers with Ni(II), Pd(II), and Pt(II)
by: Leo Payen, et al.
Published: (2023-04-01)

Chirality as a Feature of the Crystal Structure of Lanthanide Ion Complexes—Some Simple Examples
by: Lioubov I. Semenova, et al.
Published: (2023-02-01)

A New Unnatural Amino Acid Derived from the Modification of 4′-(p-tolyl)-2,2′:6′,2″-terpyridine and Its Mixed-Ligand Complexes with Ruthenium: Synthesis, Characterization, and Photophysical Properties
by: Konstantinos Ypsilantis, et al.
Published: (2023-01-01)

Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions
by: Young Hoon Lee, et al.
Published: (2021-02-01)

Biocompatibility of ionic liquid tagged terpyridine complexes with potent biological activity
by: M. Antilin Princela, et al.
Published: (2023-12-01)

Ru(terpy)-Based Conducting Polymer in Electrochemical Biosensing of Epinephrine
by: Francesca Meloni, et al.
Published: (2021-02-01)

Rapid, sensitive and highly specific label-free fluorescence biosensor for microRNA by branched rolling circle amplification
by: Ma, Qian, et al.
Published: (2020)

Near-IR Electrochromic Film with High Optical Contrast and Stability Prepared by Oxidative Electropolymerization of Triphenylamine Modified Terpyridine Platinum(II) Chloride
by: Huiying Gu, et al.
Published: (2023-12-01)

Synthesis of an Alternated Heterobimetallic Supramolecular Polymer Based on Ru(II) and Fe(II)
by: Manas Kumar Bera, et al.
Published: (2020-11-01)

Experimental and theoretically calculated structural data of different iron(II)-terpyridine complexes – validation of theoretical method
by: Evangelia Athanasopoulos, et al.
Published: (2024-06-01)

Nano-Theranostics Constructed from Terpyridine-Modified Pillar [5]arene-Based Supramolecular Amphiphile and Its Application in Both Cell Imaging and Cancer Therapy
by: Youjun Zhou, et al.
Published: (2022-09-01)