Recent progress in ternary mixed matrix membranes for CO2 separation
Mixed matrix membranes (MMMs) could combine the advantages of both polymeric membranes and porous fillers, making them an effective alternative to conventional polymer membranes. However, interfacial incompatibility issues, such as the presence of interfacial voids, hardening of polymer chains, and...
| Main Authors: | , , , , , , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
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KeAi Communications Co., Ltd.
2024-05-01
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| Series: | Green Energy & Environment |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2468025723000626 |
| _version_ | 1797238004767522816 |
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| author | Zikang Qin Yulei Ma Jing Wei Hongfang Guo Bangda Wang Jing Deng Chunhai Yi Nanwen Li Shouliang Yi Yi Deng Wentao Du Jian Shen Wenju Jiang Lu Yao Lin Yang Zhongde Dai |
| author_facet | Zikang Qin Yulei Ma Jing Wei Hongfang Guo Bangda Wang Jing Deng Chunhai Yi Nanwen Li Shouliang Yi Yi Deng Wentao Du Jian Shen Wenju Jiang Lu Yao Lin Yang Zhongde Dai |
| author_sort | Zikang Qin |
| collection | DOAJ |
| description | Mixed matrix membranes (MMMs) could combine the advantages of both polymeric membranes and porous fillers, making them an effective alternative to conventional polymer membranes. However, interfacial incompatibility issues, such as the presence of interfacial voids, hardening of polymer chains, and blockage of micropores by polymers between common MMMs fillers and the polymer matrix, currently limit the gas separation performance of MMMs. Ternary phase MMMs (consisting of a filler, an additive, and a matrix) made by adding a third compound, usually functionalized additives, can overcome the structural problems of binary phase MMMs and positively impact membrane separation performance. This review introduces the structure and fabrication processes for ternary MMMs, categorizes various nanofillers and the third component, and summarizes and analyzes in detail the CO2 separation performance of newly developed ternary MMMs based on both rubbery and glassy polymers. Based on this separation data, the challenges of ternary MMMs are also discussed. Finally, future directions for ternary MMMs are proposed. |
| first_indexed | 2024-04-24T17:28:45Z |
| format | Article |
| id | doaj.art-fc92dd0a54004f90837945a0e0aef2a6 |
| institution | Directory Open Access Journal |
| issn | 2468-0257 |
| language | English |
| last_indexed | 2024-04-24T17:28:45Z |
| publishDate | 2024-05-01 |
| publisher | KeAi Communications Co., Ltd. |
| record_format | Article |
| series | Green Energy & Environment |
| spelling | doaj.art-fc92dd0a54004f90837945a0e0aef2a62024-03-28T06:38:31ZengKeAi Communications Co., Ltd.Green Energy & Environment2468-02572024-05-0195831858Recent progress in ternary mixed matrix membranes for CO2 separationZikang Qin0Yulei Ma1Jing Wei2Hongfang Guo3Bangda Wang4Jing Deng5Chunhai Yi6Nanwen Li7Shouliang Yi8Yi Deng9Wentao Du10Jian Shen11Wenju Jiang12Lu Yao13Lin Yang14Zhongde Dai15College of Architecture and Environment, Sichuan University, Chengdu, 610065, China; College of Carbon Neutrality Future Technology, Sichuan University, Chengdu, 610065, China; National Engineering Research Centre for Flue Gas Desulfurization, Chengdu, 610065, China; Carbon Neutral Technology Innovation Center of Sichuan, Chengdu, 610065, ChinaCollege of Architecture and Environment, Sichuan University, Chengdu, 610065, China; College of Carbon Neutrality Future Technology, Sichuan University, Chengdu, 610065, China; National Engineering Research Centre for Flue Gas Desulfurization, Chengdu, 610065, China; Carbon Neutral Technology Innovation Center of Sichuan, Chengdu, 610065, ChinaCollege of Architecture and Environment, Sichuan University, Chengdu, 610065, China; College of Carbon Neutrality Future Technology, Sichuan University, Chengdu, 610065, China; National Engineering Research Centre for Flue Gas Desulfurization, Chengdu, 610065, China; Carbon Neutral Technology Innovation Center of Sichuan, Chengdu, 610065, ChinaCollege of Architecture and Environment, Sichuan University, Chengdu, 610065, China; College of Carbon Neutrality Future Technology, Sichuan University, Chengdu, 610065, China; National Engineering Research Centre for Flue Gas Desulfurization, Chengdu, 610065, China; Carbon Neutral Technology Innovation Center of Sichuan, Chengdu, 610065, ChinaCollege of Architecture and Environment, Sichuan University, Chengdu, 610065, China; National Engineering Research Centre for Flue Gas Desulfurization, Chengdu, 610065, China; Carbon Neutral Technology Innovation Center of Sichuan, Chengdu, 610065, ChinaSchool of Chemical, Biological and Materials Engineering, University of Oklahoma, Norman, OK, 73019, USAShaanxi Key Laboratory of Energy Chemical Process Intensification, School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, 710049, ChinaState Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, ChinaUS DOE, Natl Energy Technol Lab, 626 Cochrans Mill Rd, Pittsburgh, PA 15236, USADongFang Boiler Co.,Ltd., China; Clean Combustion and Flue Gas Purification Key Laboratory of Sichuan Province, Chengdu, 611731, ChinaDongFang Boiler Co.,Ltd., China; Clean Combustion and Flue Gas Purification Key Laboratory of Sichuan Province, Chengdu, 611731, ChinaCollege of Environment and Resources, Xiangtan University, Xiangtan, 411105, ChinaCollege of Architecture and Environment, Sichuan University, Chengdu, 610065, China; National Engineering Research Centre for Flue Gas Desulfurization, Chengdu, 610065, China; Carbon Neutral Technology Innovation Center of Sichuan, Chengdu, 610065, ChinaCollege of Architecture and Environment, Sichuan University, Chengdu, 610065, China; National Engineering Research Centre for Flue Gas Desulfurization, Chengdu, 610065, China; Carbon Neutral Technology Innovation Center of Sichuan, Chengdu, 610065, ChinaCollege of Architecture and Environment, Sichuan University, Chengdu, 610065, China; National Engineering Research Centre for Flue Gas Desulfurization, Chengdu, 610065, China; Carbon Neutral Technology Innovation Center of Sichuan, Chengdu, 610065, China; Corresponding authors. College of Carbon Neutrality Future Technology, Sichuan University, Chengdu, 610065, China.College of Architecture and Environment, Sichuan University, Chengdu, 610065, China; National Engineering Research Centre for Flue Gas Desulfurization, Chengdu, 610065, China; Carbon Neutral Technology Innovation Center of Sichuan, Chengdu, 610065, China; Corresponding authors. College of Carbon Neutrality Future Technology, Sichuan University, Chengdu, 610065, China.Mixed matrix membranes (MMMs) could combine the advantages of both polymeric membranes and porous fillers, making them an effective alternative to conventional polymer membranes. However, interfacial incompatibility issues, such as the presence of interfacial voids, hardening of polymer chains, and blockage of micropores by polymers between common MMMs fillers and the polymer matrix, currently limit the gas separation performance of MMMs. Ternary phase MMMs (consisting of a filler, an additive, and a matrix) made by adding a third compound, usually functionalized additives, can overcome the structural problems of binary phase MMMs and positively impact membrane separation performance. This review introduces the structure and fabrication processes for ternary MMMs, categorizes various nanofillers and the third component, and summarizes and analyzes in detail the CO2 separation performance of newly developed ternary MMMs based on both rubbery and glassy polymers. Based on this separation data, the challenges of ternary MMMs are also discussed. Finally, future directions for ternary MMMs are proposed.http://www.sciencedirect.com/science/article/pii/S2468025723000626CO2 separationMixed matrix membranesTernary phase |
| spellingShingle | Zikang Qin Yulei Ma Jing Wei Hongfang Guo Bangda Wang Jing Deng Chunhai Yi Nanwen Li Shouliang Yi Yi Deng Wentao Du Jian Shen Wenju Jiang Lu Yao Lin Yang Zhongde Dai Recent progress in ternary mixed matrix membranes for CO2 separation Green Energy & Environment CO2 separation Mixed matrix membranes Ternary phase |
| title | Recent progress in ternary mixed matrix membranes for CO2 separation |
| title_full | Recent progress in ternary mixed matrix membranes for CO2 separation |
| title_fullStr | Recent progress in ternary mixed matrix membranes for CO2 separation |
| title_full_unstemmed | Recent progress in ternary mixed matrix membranes for CO2 separation |
| title_short | Recent progress in ternary mixed matrix membranes for CO2 separation |
| title_sort | recent progress in ternary mixed matrix membranes for co2 separation |
| topic | CO2 separation Mixed matrix membranes Ternary phase |
| url | http://www.sciencedirect.com/science/article/pii/S2468025723000626 |
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