[μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[triphenylstibine-3κSb]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C18H15Sb)(CO)9], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and arsine ligands are equatorial with respect to the Ru3 triangle....
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809049927 |
| _version_ | 1818489188184489984 |
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| author | Omar bin Shawkataly Imthyaz Ahmed Khan Chin Sing Yeap Hoong-Kun Fun |
| author_facet | Omar bin Shawkataly Imthyaz Ahmed Khan Chin Sing Yeap Hoong-Kun Fun |
| author_sort | Omar bin Shawkataly |
| collection | DOAJ |
| description | In the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C18H15Sb)(CO)9], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and arsine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted phenyl rings make dihedral angles of 84.3 (3), 80.4 (3) and 70.5 (3)° with each other. The dihedral angles between the two phenyl rings are 85.9 (3) and 75.2 (3)° for the two diphenylarsine groups. In the crystal packing, molecules are linked into chains down the c axis via intermolecular C—H...O hydrogen bonds. Weak intermolecular C—H...π interactions further stabilize the crystal structure. |
| first_indexed | 2024-12-10T17:01:03Z |
| format | Article |
| id | doaj.art-fc992b951cc1439c935d2299c5be488a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T17:01:03Z |
| publishDate | 2010-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-fc992b951cc1439c935d2299c5be488a2022-12-22T01:40:34ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m94m9510.1107/S1600536809049927[μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[triphenylstibine-3κSb]-triangulo-triruthenium(0)Omar bin ShawkatalyImthyaz Ahmed KhanChin Sing YeapHoong-Kun FunIn the title triangulo-triruthenium compound, [Ru3(C25H22As2)(C18H15Sb)(CO)9], the bis(diphenylarsino)methane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and arsine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted phenyl rings make dihedral angles of 84.3 (3), 80.4 (3) and 70.5 (3)° with each other. The dihedral angles between the two phenyl rings are 85.9 (3) and 75.2 (3)° for the two diphenylarsine groups. In the crystal packing, molecules are linked into chains down the c axis via intermolecular C—H...O hydrogen bonds. Weak intermolecular C—H...π interactions further stabilize the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536809049927 |
| spellingShingle | Omar bin Shawkataly Imthyaz Ahmed Khan Chin Sing Yeap Hoong-Kun Fun [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[triphenylstibine-3κSb]-triangulo-triruthenium(0) Acta Crystallographica Section E |
| title | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[triphenylstibine-3κSb]-triangulo-triruthenium(0) |
| title_full | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[triphenylstibine-3κSb]-triangulo-triruthenium(0) |
| title_fullStr | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[triphenylstibine-3κSb]-triangulo-triruthenium(0) |
| title_full_unstemmed | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[triphenylstibine-3κSb]-triangulo-triruthenium(0) |
| title_short | [μ-Bis(diphenylarsino)methane-1:2κ2As:As′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[triphenylstibine-3κSb]-triangulo-triruthenium(0) |
| title_sort | amp 956 bis diphenylarsino methane 1 2 amp 954 2as as amp 8242 nonacarbonyl 1 amp 954 3c 2 amp 954 3c 3 amp 954 3c triphenylstibine 3 amp 954 sb triangulo triruthenium 0 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809049927 |
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